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Abstractπ‐Conjugated polyelectrolytes (CPEs) have been studied as interlayers on top of a separate hole transport layer (HTL) to improve the wetting, interfacial defect passivation, and crystal growth of perovskites. However, very few CPE‐based HTLs have been reported without rational molecular design as ideal HTLs for perovskite solar cells (PeSCs). In this study, the authors synthesize a triphenylamine‐based anionic CPE (TPAFS‐TMA) as an HTL for p‐i‐n‐type PeSCs. TPAFS‐TMA has appropriate frontier molecular orbital (FMO) levels similar to those of the commonly used poly(bis(4‐phenyl)‐2,4,6‐trimethylphenylamine) (PTAA) HTL. The ionic and semiconducting TPAFS‐TMA shows high compatibility, high transmittance, appropriate FMO energy levels for hole extraction and electron blocking, as well as defect passivating properties, which are confirmed using various optical and electrical analyses. Thus, the PeSC with the TPAFS‐TMA HTL exhibits the best power conversion efficiency (PCE) of 20.86%, which is better than that of the PTAA‐based device (PCE of 19.97%). In addition, it exhibits negligible device‐to‐device variations in its photovoltaic performance, contrary to the device with PTAA. Finally, a large‐area PeSC (1 cm2) and mini‐module (3 cm2), showing PCEs of 19.46% and 18.41%, respectively, are successfully fabricated. The newly synthesized TPAFS‐TMA may suggest its great potential as an HTL for large‐area PeSCs.

Abstract Background Parabolic Trough Solar Collector (PTSC) is one of the most popular and an effective device that converts solar radiation into a heat or useful energy. However, it suffers from high temperature gradient and low thermal efficiency. The solution for this problem is to use new advanced coolants (hybrid nanofluids) in order to enhance PTSC's thermal efficiency. Methods A numerical analysis on the thermo-hydraulic performance of a PTSC receiver's tube equipped with conical turbulators is presented. The Navier-Stokes equations are solved using Finite Volume Method (FVM) coupled with Monte Carlo Ray Tracing (MCRT) method. The flow and thermal characteristics as well as entropy generation of the PTSC's receiver tube are investigated for three hybrid nanofluids (Ag-SWCNT, Ag-MWCNT, and Ag-MgO) having a mixing ratio of (50:50) dispersed in Syltherm oil 800, Reynolds number (5000 to 100,000) and fluid inlet temperatures (400 to 650 K). Significant findings The conical turbulators effectively augmented the thermal performance by 233.4% utilising Ag-SWCNT/Syltherm oil instead of pure Syltherm oil. The performance evaluation criterion is found to be in the range of 0.9–1.82. The thermal and exergetic efficiencies increased by 11.5% and 18.2%, respectively. The maximum decrement in the entropy generation rate and entropy generation ratio are 42.7% and 33.7%.

Abstract A new conical-cylindrical top-discharge blow tank is designed, by introducing the pulsed gas to facilitate discharging, for stable transportation for kaolin powders. A series of experimental studies on pulsed gas characteristic parameters like pulsed gas flow rate Qpulsed (5 m3/h ≤ Qpulsed ≤ 25 m3/h), pulsed interval tpulsed (1 s ≤ tpulsed ≤ 5 s) and pulsed width τpulsed (50 ms ≤ τpulsed ≤ 250 ms) are conducted with the fluidized gas flow rate of 12 m3/h. The experiments mainly test the powder mass flow rate and solid-gas ratio in the conveying process. The results indicate that the mass flow rate and solid-gas ratio range 12.6–278.04 kg/h and 0.9–19.56 kg/m3, respectively. With the increase of the pulsed gas flow rate, the mass flow rate and solid gas ratio first increase and then decrease. When the ratio of fluidized gas flow rate to pulsed gas flow rate is within 0.8–1.2, its conveying capacity reaches the maximum. Meanwhile, the increase in the pulsed interval leads to the decrease of the mass flow rate and solid-gas ratio. Moreover, the increase in the pulsed width leads to the initial increase and then the stabilization of the mass flow rate and solid gas ratio. When the pulsed width is 50 ms, the improvement of discharge would small. Conversely, increasing the pulsed width can increase the discharge, and stabilize subsequently until over 200 ms. Besides, moisture content is one of the important factors affecting kaolin powders discharge. When the moisture content is 0.83%, the pulsed gas does not improve the discharge significantly. Meanwhile, pressure distribution at different locations in the tank is also measured. The results reveal that the introduction of pulsed gas changes the pressure distribution in the tank. A pressure zone is formed on the upper part of the tank, which promotes the powder discharge.

Much of New South Wales and southern Queensland suffered from extreme drought from 2017 to 2019. This study models drought and bushfires impacts using VU‐TERM, a multi‐regional, dynamic CGE model. Prolonged drought pushed national real GDP to 0.7 per cent or more below base in 2018–2019 and 2019–2020. NSW’s real GDP fell relative to forecast by 1.1 per cent or $6.9 billion in 2018–2019 and 1.6 per cent or $10.2 billion in 2019–2020. These impacts reflect a severe diminution of farm output, given that agriculture accounts for around 1.6 per cent of NSW’s income. Bushfires exacerbated 2019–2020 losses. We assume that there is a full recovery in seasonal conditions in 2020. However, prolonged drought and bushfire destruction deplete farm capital through depressed investment and diminished herd numbers. Consequently, the income earning capacity of farms in recovery remains below that of a no drought base. The net present value of the national welfare loss is $63 billion, split between $53 billion in losses from drought and $10 billion from bushfires. The latter excludes any valuation of human lives lost, flora, fauna or forestry destruction. In the longer term, adaptation and policy responses will need to reflect the expectation of increased frequency of adverse climatic events.

Vegetated coastal ecosystems, in particular mangroves, tidal marshes and seagrasses are highly efficient at sequestering and storing carbon, making them valuable assets for climate change mitigation and adaptation. The state of Queensland, in northeastern Australia, contains almost half of the total area of these blue carbon ecosystems in the country, yet there are few detailed regional or state-wide assessments of their total sedimentary organic carbon (SOC) stocks. We compiled existing SOC data and used boosted regression tree models to evaluate the influence of environmental variables in explaining the variability in SOC stocks, and to produce spatially explicit blue carbon estimates. The final models explained 75 % (for mangroves and tidal marshes) and 65 % (for seagrasses) of the variability in SOC stocks. Total SOC stocks in the state of Queensland were estimated at 569 ± 98 Tg C (173 ± 32 Tg C, 232 ± 50 Tg C, and 164 ± 16 Tg C from mangroves, tidal marshes and seagrasses, respectively). Regional predictions for each of Queensland's eleven Natural Resource Management regions revealed that 60 % of the state's SOC stocks occurred within three regions (Cape York, Torres Strait and Southern Gulf Natural Resource Management regions) due to a combination of high values of SOC stocks and large areas of coastal wetlands. Protected areas in Queensland play an important role in conserving SOC assets in Queensland's coastal wetlands. For example, ~19 Tg C within terrestrial protected areas, ~27 Tg C within marine protected areas and ~ 40 Tg C within areas of matters of State Environmental Significance. Using multi-decadal (1987-2020) mapped distributions of mangroves in Queensland; we found that mangrove area increased by approximately 30,000 ha from 1987 to 2020, which led to temporal fluctuations in mangrove plant and SOC stocks. We estimated that plant stocks decreased from ~45 Tg C in 1987 to ~34.2 Tg C in 2020, while SOC stocks remained relatively constant from ~107.9 Tg C in 1987 to 108.0 Tg C in 2020. Considering the level of current protection, emissions from mangrove deforestation are potentially very low; therefore, representing minor opportunities for mangrove blue carbon projects in the region. Our study provides much needed information on current trends in carbon stocks and their conservation in Queensland's coastal wetlands, while also contributing to guide future management actions, including blue carbon restoration projects.

Abstract The penetration level of residential battery energy storage systems (BESSs) has been increasing in recent years. However, it is still not clear how they would impact the hosting capacity of a network. This paper presents an optimization-based framework to assess the impact of BESSs and network tariffs on the minimum photovoltaic hosting capacity (MPVHC) of distribution systems. The paper considers a rule-based as well as a mixed-integer linear programming (MILP)-based home energy management schemes to schedule the BESSs. The performance of the proposed method is compared with that of the Monte Carlo approach. It is shown that the proposed method identifies a considerably more accurate result than Monte Carlo approach. Then, the proposed methodology is applied to 128 real low voltage feeders in the U.K. The simulation results show that the effectiveness of BESSs in increasing the MPVHC depends on the penetration of BESSs in the system and the scheduling scheme of BESSs. Further, the MPVHC increases more in the cost minimization scheme compared to the self-consumption minimization. Finally, it is shown that both flat and Time-of-Use tariffs have a similar effect on the MPVHC.