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Increasing the rate of renovation for the existing building stock is a crucial challenge for EU’s energy policy. The Smart City Block (SCB) project proposes an innovative answer to this challenge. The underlying hypothesis is that introducing a collective dimension to renovation could result in increasing rates of renovation while also impacting positively the efficiency of the renovation and the social ties within urban areas. The collective dimension considered is the city block in Brussels.The first part of this paper describes the theoretical part of the project that was necessary to develop an adapted methodology. It describes the SCB offering, Brussels segmentation and some results of surveys.The SCB offering shows that many different options can be proposed to the city block dwellers, ranging from a collective insulation, efficient heating systems and shared photovoltaics to collective kitchen garden in the inner space of the block, shared vehicles or shared spaces. This is especially relevant for Brussels where city blocks often have an inner space that could be used. Besides, the segmentation of Brussels based on city block characteristics offers a typology that can be further used to target specific environmental or social deficit.However, the collective dimension introduced in the project is challenging for western individualistic minds. In order to evaluate the acceptance of households, a survey was conducted on 4 city blocks in Brussels, representing over 450 households. It shows a clear willingness to investigate the concept further but only if concrete proposals with estimations of energy and financial savings are provided. Sharing space, equipment and activities was more positively accepted than what we initially expected. Although the attitude-behaviour gap must not be underestimated, this opening can be viewed as an evolution of lifestyles in some segments of the population. Governance and institutional arrangements are expected to play a critical role in supporting this evolution.The second ...

In this thesis, I analyze the impacts of the design and implementation of different environmental policy tools from a theoretical and empirical perspective: certificates providing information on the energy performance of buildings (chapter 1); urban road pricing schemes such as congestion charges (chapter 2); quantity-based policy tools to support production with non-polluting technologies (chapter 3).In chapter 1, co-authored with Luisa Dressler, we study how energy performance certificates (EPCs) impact the residential rental market. These certificates can help solve information asymmetries between landlords and tenants about the thermal quality of dwellings for rent, which, in turn, is expected to facilitate investment aimed at improving dwellings' energy performance. However, disclosure of EPCs is often incomplete, which hampers their effectiveness in relieving such information asymmetries. Moreover, even when a certificate is available, landlords do not always disclose it. This contradicts the so-called information unraveling result, according to which all landlords should disclose quality information unless it is costly to do so: in such a setting, information eventually unravels. Using a cross-sectional dataset of residential rental advertisements from the Belgian region of Brussels, we empirically evaluate incentives to disclose energy performance ratings. We find that two fundamental assumptions underlying the unraveling result are not confirmed in our setting: firstly, tenants value energy performance of rental property only when dwellings are of very high quality; secondly, tenants do not appear to rationally adjust their expectations when faced with dwellings that withhold their energy performance rating. Finally, we formulate specific policy advice for reforming EPC mechanisms to increase disclosure rates.In chapter 2, I study how urban congestion pricing impacts the use of sustainable mobility options such as bike sharing, presenting evidence from the city of Milan, Italy.As concern for air ...

We report a measurement of the flux of cosmic rays with unprecedented precision and statistics using the Pierre Auger Observatory. Based on fluorescence observations in coincidence with at least one surface detector we derive a spectrum for energies above 1018 eV. We also update the previously published energy spectrum obtained with the surface detector array. The two spectra are combined addressing the systematic uncertainties and, in particular, the influence of the energy resolution on the spectral shape. The spectrum can be described by a broken power law E- γ with index γ = 3.3 below the ankle which is measured at log10 (Eankle / eV) = 18.6. Above the ankle the spectrum is described by a power law with index 2.6 followed by a flux suppression, above about log10 (E / eV) = 19.5, detected with high statistical significance. © 2010 Elsevier B.V. All rights reserved. ; 0 ; SCOPUS: ar.j ; info:eu-repo/semantics/published

Atmospheric plasma technology is a promising next-generation alternative for replacing thermal chemical vapor deposition or wet chemical processes for the deposition of functional coatings. In this work, TiO2 films with various morphologies and thicknesses are synthesized in a controllable way by atmospheric Dielectric Barrier Discharges (DBD) under argon/oxygen ambient conditions. This method allows varying the density of the deposited coatings, from low density powders to dense compact anatase layers simple tuning of the parameters. The surface morphology and cross section of the as-synthesized films are observed by scanning electron microscopy (SEM). It is demonstrated that the total flow rate together with the absorbed power have a significant effect on the morphology of the film, which changes from granular to compact film by increasing the total flow rate or decreasing the power. In other words, changing the energy density (Ed) in the plasma allows to control the morphology of the TiO2 films. A deposition mechanism is proposed to explain the effect of the synthesis parameters on the formed films. The chemical and phase composition of these films before and after annealing for 2 h in air at 673 K are comparatively studied. The photocatalytic activities and the reusability of the TiO2 films is investigated by degrading a methylene blue (MB) solution under Ultra-Violet (UV) light. It is compared to the activity of a P25 film, deposited by drop-casting. The photocatalytic rate of the annealed TiO2 film synthesized at a total flow rate of 2.5 slm turns out to be about 2 and 15 times higher than the one of P25 and as-synthesized TiO2 films, respectively. The annealed TiO2 film were shown to be reusable for at least three cycles, without significant loss of photocatalytic activity. ; SCOPUS: ar.j ; info:eu-repo/semantics/published

On the basis of experimental microbiological studies performed on different french distribution systems, a model of the dynamics of bacteria and biodegradable dissolved organic carbon (BDOC) in distribution networks was developed (the SANCHO model). The following processes are taken into account in the model: exoenzymatic hydrolysis of dissolved organic matter by bacteria and growth of free and fixed bacteria on the hydrolysis products; bacterial mortality which releases organic matter; reversible adsorption of bacteria and their biological attachment to inner pipe surfaces, chemical consumption of free chlorine and impact of free chlorine on the activity of free and fixed bacteria. The kinetics of these processes were all studied experimentally. The model considers the case of a water body flowing down in successive pipes of decreasing diameters and calculates the spatial variations, at steady state, of BDOC and chlorine concentration, free and fixed biomass. The SANCHO model was validated by the comparison of calculated and experimental data on various distribution systems which work over a large range of conditions. Good agreement between calculated and measured values of chlorine, BDOC, suspended and fixed bacterial biomass was found for the different distribution networks. This model can be used to define the water quality required at the outlet of a given treatment plant in order to avoid problems of bacterial growth within the distribution system fed by this plant. _____________________________________________________________________________________________________________________________ Sur la base d'études microbiologiques expérimentales réalisées sur différents réseaux de distribution d'eau potable en France, un modèle de la dynamique des bactéries et du carbone organique biodégradable (CODB) a été développé (le modèle SANCHO). Les processus suivants ont été pris en compte: - l'hydrolyse bactérienne exoenzymatique de la matière organique et la croissance des bactéries libres et fixées, à partir des ...

The Telescope Array's Middle Drum fluorescence detector was instrumented with telescopes refurbished from the High Resolution Fly's Eye's HiRes-1 site. The data observed by Middle Drum in monocular mode was analyzed via the HiRes-1 profile-constrained geometry reconstruction technique and utilized the same calibration techniques enabling a direct comparison of the energy spectra and energy scales between the two experiments. The spectrum measured using the Middle Drum telescopes is based on a three-year exposure collected between December 16, 2007 and December 16, 2010. The calculated difference between the spectrum of the Middle Drum observations and the published spectrum obtained by the data collected by the HiRes-1 site allows the HiRes-1 energy scale to be transferred to Middle Drum. The HiRes energy scale is applied to the entire Telescope Array by making a comparison between Middle Drum monocular events and hybrid events that triggered both Middle Drum and the Telescope Array's scintillator ground array. © 2012 Elsevier B.V. All rights reserved. ; 0 ; SCOPUS: ar.j ; info:eu-repo/semantics/published

Accurate ab initio intermolecular potential energy surfaces (IPES) have been obtained for the first time for the ground electronic state of the C 2H2-Kr and C2H2-Xe van der Waals complexes. Extensive tests, including complete basis set and all-electron scalar relativistic results, support their calculation at the CCSD(T) level of theory, using small-core relativistic pseudopotentials for the rare-gas atoms and aug-cc-pVQZ basis sets extended with a set of 3s3p2d1f1g mid-bond functions. All results are corrected for the basis set superposition error. The importance of the scalar relativistic and rare-gas outer-core (n.1)d correlation effects is investigated. The calculated IPES, adjusted to analytical functions, are characterized by global minima corresponding to skew T-shaped geometries, in which the Jacobi vector positioning the rare-gas atom with respect to the center of mass of the C2H2 moiety corresponds to distances of 4.064 and 4.229Å, and angles of 65.22° and 68.67° for C 2H2-Kr and C2H2-Xe, respectively. The interaction energy of both complexes is estimated to be -151.88 (1.817 kJ mol-1) and -182.76 cm-1 (2.186 kJ mol-1), respectively. The evolution of the topology of the IPES as a function of the rare-gas atom, from He to Xe, is also discussed. © 2012 Taylor and Francis. ; SCOPUS: cp.j ; info:eu-repo/semantics/published

SCOPUS: ch.b ; info:eu-repo/semantics/published