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Abstract The need to shift from a fossil fuel based economy towards a more bio-based economy has received a lot of attention in public debates and policy making in recent years. However, there seems to be some inconsistency in how a bio-based economy is defined as well as how to estimate the size of this bio-based economy. The current article shows, using a Bibliometric analysis, that the topic "bio-based economy" does not come up extensively in the literature by mid 2010. Moreover, it seems that estimating the importance of the whole of a bio-based economy (and thereby not only focusing on one type of production or product) for a region or country is quite rare, besides a few examples. Within Flanders, one such study has been executed by order of the Flemish government. The current article suggests a framework that can be used to estimate the size of the bio-based economy in other regions or countries. It is based on several steps, so called critical points related to conceptualization, disaggregation, information and valuation. The critical points depend on who has and who wants the information, what the context is, what kind of data is available and whether the research should be comparable. The authors suggest that by following their proposed steps, a reliable estimate of the size of the bio-based economy can be calculated.

Six coal samples collected from Maghara Coal Mine, North Sinai, Egypt, at different depths (52–87 m) were characterised by Mossbauer (MS) and Fourier Transform Infrared (FT-IR) spectroscopy. The moisture and ash content and the ultimate analysis are given. The iron minerals were studied by MS. Jarosite (ferric sulphate) and pyrite have been found in the sample taken at 52 m. However, ferrous sulphate and pyrite are present in the other samples. On the other hand, several structural parameters such as Har/Hal and Har/Car were calculated from FT-IR spectra as a function of depth. These parameters give a quantitative determination of the aromaticity, which was found in the range between 0.46 and 0.59, similar to that reported in the literature for subbituminous coals.

The measurement of the bulk minority carrier lifetime of semiconductors requires efficient passivation of the recombination states at the surface. While numerous recipes have been published for Si-surface passivation, no adequate passivation methods are available for Ge. This paper presents a new and straightforward passivation method, based on a solution of iodine in polyvinyl acetate and acetone. The dependence of the carrier lifetime with time after passivation and with Ge resistivity has been investigated. It is found that the lifetime in this low resistivity material is strongly governed by Auger recombination.

Abstract This contribution experimentally evaluates and compares the performance of an ORC (organic Rankine cycle) system for stationary bottoming WHR (waste heat recovery) application operating with two different working fluids, SES36 and R245fa. The test rig is a regenerative cycle equipped with a single screw expander modified from a standard compressor characterized by a nominal shaft power of 11 kW. A total of 36 and 43 steady-state points are collected for SES36 and R245fa respectively, over a wide range of operating conditions by changing the expander rotational speed, the pump frequency and the cooling condenser flow rate. The performances of the ORC components are individually evaluated. A maximum expander isentropic efficiency of 60% is reached using SES36 at 3000 rpm, and a value of 52% is reached with R245fa at 3000 rpm. However, for a given pressure ratio the expander output power is higher with R245fa than with SES36. The overall performance of the ORC unit are investigated in terms of first and second law efficiencies and net output power for the two fluids. The results experimentally demonstrate the correlation between the working fluid critical temperature and the ORC unit working characteristics for low temperature waste heat recovery applications. Open experimental data are provided for both fluids.

Abstract A linear economy approach results in many environmental challenges: resources become depleted and end up as waste and emissions. One of the key strategies to overcome these problems is using waste as a resource, i.e. evolving toward a circular economy. To monitor this transition, suitable indicators are needed that focus on sustainability issues whilst taking into account the technical reality. In this paper, we develop such an indicator to quantify the circular economy performance of different plastic waste treatment options. This indicator is based on the technical quality of the plastic waste stream and evaluates resource consumption by using the Cumulative Exergy Extraction from the Natural Environment (CEENE) method. To illustrate the use of this new indicator, it was applied in a case study on post-industrial plastic waste treatment. The results show that the indicator can be a very useful approach to guide waste streams towards their optimal valorization option, based on quality of the waste flow and the environmental benefit of the different options.

Abstract Using light alcohols in spark-ignition engines can improve energy security and offers the prospect of carbon neutral transport. The properties of these fuels enable considerable improvements in engine performance and pollutant emissions. Whereas most experimental studies have focused on ethanol, this paper provides experimental results gathered on various methanol-fuelled engines. A comparison against gasoline on two flex-fuel engines yielded relative efficiency benefits of about 10% for methanol thanks to more isochoric combustion, less pumping, cooling and dissociation losses. Lower combustion temperatures allowed to reduce engine-out NO x by 5–10 g/kWh. The CO 2 values dropped by more than 10%. Alternative load control strategies, employing mixture richness or exhaust gas recirculation (EGR) to control load while keeping the throttle wide open, were compared on a single cylinder engine. The EGR strategy seems preferable as it allows to increase part load efficiency up to 5% without sacrificing in terms of tailpipe emissions. Finally, this load control strategy of choice was applied to a turbocharged, high compression ratio engine to demonstrate that methanol can be used in dedicated engines with diesel-like efficiencies (up to 42%) and emission levels comparable to or lower than gasoline engines.

Bio-oils produced by fast pyrolysis of lignocellulosic biomass have proven to be a promising, clean, and renewable energy source. To better assess the potential of using bio-oils for the production of chemicals and fuels a new comprehensive characterization method is developed. The combination of the analyical power of GC×GC-FID and GC×GC-TOF-MS allows to obtain an unseen level of detail for both crude and hydrotreated bio-oils originated from pine wood biomass. The use of GC×GC proves to be essential to capture the compositional differences between crude and stabilized bio-oils. Our method uses a flame ionization detector to quantify the composition, while GC×GC-TOF-MS is used for the qualitative analysis. This method allows quantification of around 150 tentatively identified compounds, describing approximately 80% of total peak volume. The number of quantified compounds in bio-oils is increased with a factor five compared to the present state-of-the-arte. The necessity of using multiple internal standards (dibutyl ether and fluoranthene) and a cold-on column injector is also verified.

Given the devastating effects of global warming, the problem of human-induced climate change, and in particular carbon dioxide emissions, has been high on the global policy agenda. In this study, we examine the relationship between national culture, carbon dioxide emissions, and economic growth in the framework of the Environmental Kuznets Curve (EKC). Applying system GMM panel estimator across 69 developed and developing countries, we confirm the existence of EKC and show that culture significantly affects the income-emission relationship. Moreover, the effects of the six cultural dimensions on EKC can be collapsed into two: (i) masculinity, power distance and indulgence move the EKC upward and shift the income turning point to the left; and (ii) individualism, uncertainty, and long-term orientation move the EKC downward while shifting the income turning point to the right. The impact of culture on EKC remains also robust for alternative specifications. Future policy and global initiatives in sustainable development should incorporate the multidimensional impact of culture on national behavior towards environment and economic growth, a relationship that has been largely ignored in economic decision-making models.