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The marine environment has been in the spotlight of economic development due to the growing demand for areas to promote activities associated with the concept of Blue Economy. This is the case of the renewable energy and aquaculture sectors, whose expansion towards offshore is determined by the increase global demand for energy and food, and by exceeding of the carrying capacity of coastal and terrestrial systems. In this context, the multi-use strategy can be an alternative to minimize conflicts between activities and impacts on the surrounding social-ecological environment. This contribution presents a preliminary approach to identify opportunities for individual exploitation and the possibilities of multi-use between wind energy, wave energy and aquaculture in Brazil?s Exclusive Economic Zone. Technical, operational, and biological aspects were evaluated, through a Suitability Index validated in previous works, to identify zones with favorable conditions for energy exploitation and farming of six fish species. Additionally, overlaps between conservation areas and multi-use zones were considered to analyze possible spatial conflicts. Zones with multi-use possibilities with different combinations between these sectors were identified: i) wave energy and aquaculture presented the largest areas for multi-use, distributed in the south, southeast and northeast; ii) possibility of combining wind energy and aquaculture was identified in the northeast; and iii) multi-use possibilities in the south for marine energies. Zones with multi-use possibilities were identified in protection and conservation areas, such as the combination of wave exploitation and Greater Amberjack farming, with 63% overlap. Therefore, this case study is a guide for future local studies in the marine region of Brazil, mainly in the selection of sites for analysis. The present contribution represents a starting point for the discussion about multi-use in the country C.V.C. Weiss is grateful to the Brazilian National Council for Scientific and Technological Development (CNPq) for the PDJ (Pós-doutorado Junior) fellowship granted (151228/2020–5), and the financial support from the Universidad de Cantabria (UC) through the Agusto González de Linares and Margarita Salas Grants (POS-UC-2019-06 and RMS-04, respectively). J. Bonetti is a Research Fellow of CNPq (Grant 306633/2019–1). Raúl Guanche acknowledges the Grant RYC-2017-23260 funded by MCIN/AEI/10.13039/501100011033 and “ESF Investing in your future”. This work is framed in the project “ACUFLOT”, supported by the Biodiversity Foundation of the Ecological Transition and Demographic Challenge Ministry of Spain and the IHCantabria - Instituto de Hidráulica Ambiental de la Universidad de Cantabria

Zingiber officinale Roscoe (ginger) is a plant from the Zingiberaceae family, and its extracts have been found to contain several compounds with beneficial bioactivities. Nowadays, the use of environmentally friendly and sustainable extraction methods has attracted considerable interest. The main objective of this study was to evaluate subcritical propane (scPropane), supercritical CO2 (scCO2), and supercritical CO2 with ethanol (scCO2 + EtOH) as co-solvent methods for the extraction of high value products from ginger. In addition, the reuse/recycling of the secondary biomass in a second extraction as a part of the circular economy was evaluated. Both the primary and the secondary biomass led to high yield percentages, ranging from 1.23% to 6.42%. The highest yield was observed in the scCO2 + EtOH, with biomass prior used to scCO2 extraction. All extracts presented with high similarities as far as their total phenolic contents, antioxidant capacity, and chemical composition. The most abundant compounds, identified by the two different gas chromatography-mass spectrometry (GC-MS) systems present, were a-zingiberene, β- sesquiphellandrene, a-farnesene, β-bisabolene, zingerone, gingerol, a-curcumene, and γ-muurolene. Interestingly, the reuse/recycling of the secondary biomass was found to be promising, as the extracts showed high antioxidant capacity and consisted of significant amounts of compounds with beneficial properties.

In recent years novel applications of bioelectrochemical systems are exemplified by phototrophic biocathodes, biocompatible enzymatic fuel cells and biodegradable microbial fuel cells (MFCs). Herein, transparent silk fibroin membranes (SFM) with various fibroin content (2%, 4% and 8%) were synthesised and employed as separators in MFCs and compared with standard cation exchange membranes (CEM) as a control. The highest real-time power performance of thin-film SFM was reached by 2%-SFM separators: 25.7 ± 7.4 μW, which corresponds to 68% of the performance of the CEM separators (37.7 ± 3.1 μW). Similarly, 2%-SFM revealed the highest coulombic efficiency of 6.65 ± 1.90%, 74% of the CEM efficiency. Current for 2%-SFM reached 0.25 ± 0.03 mA (86% of CEM control). Decrease of power output was observed after 23 days for 8% and 4% and was a consequence of deterioration of SFMs, determined by physical, chemical and biological studies. This is the first time that economical and transparent silk fibroin polymers were successfully employed in MFCs.

Abstract. Wind farm control is one of the solutions recently proposed to increase the overall energy production of a wind power plant. A generic wind farm control is typically synthesized so as to optimize the energy production of the entire wind farm by reducing the detrimental effects due to wake–turbine interactions. As a matter of fact, the performance of a farm control is typically measured by looking at the increase in the power production, properly weighted through the wind statistics. Sometimes, fatigue loads are also considered in the control optimization problem. However, an aspect which is rather overlooked in the literature on this subject is the evaluation of the impact that a farm control law has on the individual wind turbine in terms of maximum loads and dynamic response under extreme conditions. In this work, two promising wind farm controls, based on wake redirection (WR) and dynamic induction control (DIC) strategy, are evaluated at the level of a single front-row wind turbine. To do so, a two-pronged analysis is performed. Firstly, the control techniques are evaluated in terms of the related impact on some specific key performance indicators, with special emphasis on ultimate loads and maximum blade deflection. Secondarily, an optimal blade redesign process is performed with the goal of quantifying the modification in the structure of the blade entailed by a possible increase in ultimate values due to the presence of wind farm control. Such an analysis provides for an important piece of information for assessing the impact of the farm control on the cost-of-energy model.

Centaurus A (Cen A) is the nearest radio galaxy discovered as a very-high-energy (VHE; 100 GeV–100 TeV) γ-ray source by the High Energy Stereoscopic System (H.E.S.S.). It is a faint VHE γ-ray emitter, though its VHE flux exceeds both the extrapolation from early Fermi-LAT observations as well as expectations from a (misaligned) single-zone synchrotron-self Compton (SSC) description. The latter satisfactorily reproduces the emission from Cen A at lower energies up to a few GeV. New observations with H.E.S.S., comparable in exposure time to those previously reported, were performed and eight years of Fermi-LAT data were accumulated to clarify the spectral characteristics of the γ-ray emission from the core of Cen A. The results allow us for the first time to achieve the goal of constructing a representative, contemporaneous γ-ray core spectrum of Cen A over almost five orders of magnitude in energy. Advanced analysis methods, including the template fitting method, allow detection in the VHE range of the core with a statistical significance of 12σ on the basis of 213 hours of total exposure time. The spectrum in the energy range of 250 GeV–6 TeV is compatible with a power-law function with a photon index Γ = 2.52 ± 0.13stat ± 0.20sys. An updated Fermi-LAT analysis provides evidence for spectral hardening by ΔΓ ≃ 0.4 ± 0.1 at γ-ray energies above 2.8+1.0−0.6 GeV at a level of 4.0σ. The fact that the spectrum hardens at GeV energies and extends into the VHE regime disfavour a single-zone SSC interpretation for the overall spectral energy distribution (SED) of the core and is suggestive of a new γ-ray emitting component connecting the high-energy emission above the break energy to the one observed at VHE energies. The absence of significant variability at both GeV and TeV energies does not yet allow disentanglement of the physical nature of this component, though a jet-related origin is possible and a simple two-zone SED model fit is provided to this end.

AbstractThe study reports on the effect of anaerobic digestate derived composts on the metabolite composition and thermal behaviour of rosemary (Rosmarinus officinalis L.). Plants were cultivated in semiarid soil under four different fertiliser treatments (composts of anaerobic digested cattle (C) or pig slurry (P) at 30t/ha and 60 t/ha, and two control treatments (inorganic fertiliser and no fertiliser application). Samples of leaves and stems were analysed to investigate the effect of treatment on chemical composition and thermochemical properties. Three orthogonal analytical approaches were used, namely: Fourier transform mid infrared spectroscopy (FTIR), gas chromatography/mass spectrometry (GC/MS) and thermochemical gravimetric analysis (TGA). FTIR and GC/MS showed fertiliser treatment resulted in tissue specific changes in sample metabolite composition. Fertiliser treatment was detected to change the thermogravimetric properties of the leaf samples and from inorganic and composted pig slurry digestate treatments had greater ash content and lower proportions of fixed carbon compared with samples from the unfertilised control treatment. This study provides information on how the composition of rosemary might be altered by fertiliser application in regions of poor soil, and has implications for biomass quality when rosemary is grown on semi-wild sites for the purpose of soil improvement.

A priority of the industrial applications of microalgae is the reduction of production costs while maximizing algae biomass productivity. The purpose of this study was to carry out a comprehensive evaluation of the effects of pH control on the production of Nannochloropsis gaditana in tubular photobioreactors under external conditions while considering the environmental, biological, and operational parameters of the process. Experiments were carried out in 3.0 m3 tubular photobioreactors under outdoor conditions. The pH values evaluated were 6.0, 7.0, 8.0, 9.0, and 10.0, which were controlled by injecting pure CO2 on-demand. The results have shown that the ideal pH for microalgal growth was 8.0, with higher values of biomass productivity (Pb) (0.16 g L-1 d-1), and CO2 use efficiency ([Formula: see text]) (74.6% w w-1); [Formula: see text]/biomass value obtained at this pH (2.42 [Formula: see text] gbiomass-1) was close to the theoretical value, indicating an adequate CO2 supply. At this pH, the system was more stable and required a lower number of CO2 injections than the other treatments. At pH 6.0, there was a decrease in the Pb and [Formula: see text]; cultures at pH 10.0 exhibited a lower Pb and photosynthetic efficiency as well. These results imply that controlling the pH at an optimum value allows higher CO2 conversions in biomass to be achieved and contributes to the reduction in costs of the microalgae production process.