Filters
Clear All
David N. Stephens; David N. Stephens
Harvested from ORCID Public Data FileDavid N. Stephens in OpenAIRE Robert K. Szilagyi; Robert K. Szilagyi
Harvested from ORCID Public Data FileRobert K. Szilagyi in OpenAIRE Paige N. Roehling; Paige N. Roehling
Harvested from ORCID Public Data FilePaige N. Roehling in OpenAIRE Navamoney Arulsamy; +1 AuthorsNavamoney Arulsamy
Harvested from ORCID Public Data FileNavamoney Arulsamy in OpenAIRE David N. Stephens; David N. Stephens
Harvested from ORCID Public Data FileDavid N. Stephens in OpenAIRE Robert K. Szilagyi; Robert K. Szilagyi
Harvested from ORCID Public Data FileRobert K. Szilagyi in OpenAIRE Paige N. Roehling; Paige N. Roehling
Harvested from ORCID Public Data FilePaige N. Roehling in OpenAIRE Navamoney Arulsamy; Navamoney Arulsamy
Harvested from ORCID Public Data FileNavamoney Arulsamy in OpenAIRE
Michael T. Mock; Michael T. Mock
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesMichael T. Mock in OpenAIREAbstractWe report a nickel complex for catalytic oxidation of ammonia to dinitrogen under ambient conditions. Using the aryloxyl radical 2,4,6‐tri‐tert‐butylphenoxyl (tBu3ArO⋅) as a H atom acceptor to cleave the N−H bond of a coordinated NH3 ligand up to 56 equiv of N2 per Ni center can be generated. Employing the N‐oxyl radical 2,2,6,6‐(tetramethylpiperidin‐1‐yl)oxyl (TEMPO⋅) as the H‐atom acceptor, up to 15 equiv of N2 per Ni center are formed. A bridging Ni‐hydrazine product identified by isotopic nitrogen (15N) studies and supported by computational models indicates the N−N bond forming step occurs by bimetallic homocoupling of two paramagnetic [Ni]−NH2 fragments. Ni‐mediated hydrazine disproportionation to N2 and NH3 completes the catalytic cycle.
Access RoutesGreen bronze add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1002/anie.202213462&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu
