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Editorial Complex Optimization and Simulation in Power Systems

Abstract To achieve the EU climate and energy objectives, a transition towards a future sustainable energy system is needed. The integration of the huge potential for industrial waste heat recovery into smart energy system represents a main opportunity to accomplish these goals. To successfully implement this strategy, all the several stakeholders' conflicting objectives should be considered. In this paper an evolutionary multi-objective optimization model is developed to perform a sustainability evaluation of an energy system involving an industrial facility as the waste heat source and the neighbourhood as district heating network end users. An Italian case study of heat recovery from a steel casting facility shows how the model allows to properly select the district heating network set of users to fully exploit the available waste energy. Design directions such as the thermal energy storage capacity can be also provided. Moreover, the model enables the analysis of the trade-off between the stakeholders’ different perspectives, allowing to identify possible win-win solutions for both the industrial sector and the citizenship.

Production of biodiesel from yellow grease (waste cooking oil and waste animal fats) is fast emerging as a promising alternative to address the twin challenges before the biodiesel industry today-fluctuation in prices of vegetable oil and the food versus fuel debate. Yellow grease has a high percentage of free fatty acids (FFA) and proves to be an unsuitable feedstock for biodiesel production from commercially viable alkali-catalyzed production systems due to saponification problems.“Green” methodologies based on heterogeneous solid acid catalyzed reactions have the potential to simultaneously promote esterification and transesterification reactions of yellow grease to produce biodiesel without soap formation and offer easy catalyst separation without generation of toxic streams. This paper presents kinetic studies for the conversion of model yellow grease feeds to biodiesel using a heteropolyacid supported on alumina (HSiW/Al2O3) using a batch autoclave. Three model yellow grease feeds were prepared using canola oil with added FFA such as palmitic, oleic and linoleic acid. A pseudo homogeneous kinetic model for the parallel esterification and transesterification was developed. The rate constants and activation parameters for esterification and transesterification reactions for the model yellow grease feeds were determined. The rate constants for esterification are higher than the transesterification rate constants. The kinetic model was validated using the experimental biodiesel data obtained from processing a commercial yellow grease feed. The kinetic model could be used to design novel processes to convert various low-value waste oils, fats and non-food grade oils to sustainable biodiesel. Keywords: Yellow grease, Canola oil, Free fatty acids, Heteropolyacid, Kinetics for esterification and transesterification

Abstract In this study, crude cellulose derived from cornstalk, after bleaching, was used as raw material for the synthesis of sodium carboxymethyl cellulose (CMC) by reacting with the cellulose with NaOH and chloroacetic acid at 75 °C for 1.5 h. Effects of alkali dosage, concentration of chloroacetic acid on the physical and chemical properties of the CMC products were investigated. It was revealed that the reactants alkali reagent/chloroacetic acid/cellulose at the molar ratio of 4.6:2.8:1and 4:2.5:1, or at the molar ratio of NaOH/ClCH 2 COOH ≈1.6–1.64, resulted in CMC products of relatively high water solubility. The viscosity-average molecular weight M v of these two CMC products obtained at molar ratios of 4.0:2.5:1 and 4.6:2.8:1 is in the range of 1.94 × 10 4 –2.48 × 10 4 g mol −1 , and the average DS of the two products are 0.57 and 0.85, respectively. As the solute concentration is above 2 wt%, the viscosity of the CMC-water solution exhibits nonlinear (exponential) increasing with increasing the solute concentration (typical of non-Newton fluids).

Laboratory corrosion and scaling testing of metallic materials exposed in high temperature and pressure environments generally involves complex, multi-instrument measurement setups. Here, we present a setup including an autoclave that is instrumented for in-situ electrochemical testing and that contains a ZrO2-based solid-state pH electrode and devices for temperature control and solution stirring. We show results highlighting the importance of adequate pre-calibration of the pH measurement, due to the hysteresis depending on temperature sweep. Additionally, we illustrate how interfacing the autoclave and the electrochemical cell to measuring and controlling instruments, using different data communication interfaces, can create ground loops. These ground loop interferences can introduce significant errors in the measurement, such as a potential shift of >100 mV. In complex, multi-instrument setups, a complete understanding of ground loops may often be difficult. Thus, we recommend systematic checks to identify the ground loops and we propose measures to avoid them. Measurement, 155 ISSN:0263-2241 ISSN:1873-412X

UV/visible light is a promising radiation source for biomass pretreatment, but very little knowledge is available on the effect of UV on the thermal behavior of lignocellulose in comparison with more classical, physical pretreatment methods. In this paper, we investigate the effects of ball-milling and UV irradiation on two species of softwood and two species of hardwood, using X-ray diffractometry (XRD), evolved gas analysis-mass spectrometry (EGA-MS), and pyrolysis-gas chromatography coupled to mass spectrometry (Py-GC/MS). The XRD data showed that the crystalline fraction of cellulose was destroyed by milling, but not by irradiation. The EGA-MS data and isoconversional kinetic analysis showed that both milling and irradiation can reduce the thermal stability of wood up to a limit value. The Py-GC/MS data showed that irradiation caused the most significant changes in the pyrolytic behavior of the wood species, increasing the ratio of holocellulose to lignin pyrolysis products and the reactivity of cellulose toward the derivatizing agent. Softwoods were more affected by irradiation than hardwoods. This paper shows that UV irradiation can decrease the recalcitrance of biomass toward pyrolysis, but its efficiency is highly dependent on the type of lignocellulosic substrate.

Abstract Bio-based polyurethane (BPU) foams were successfully prepared using hydrothermally liquefied wheat straw (WS) to substitute a mass fraction of up to 50% of polyols. Response surface methodology (RSM) based on central composite design (CCD) was employed to optimize four process parameters: NCO/OH molar ratio, loading of crosslinking agent (glycerol), loading of catalyst (a mixture of triethylene diamine, stannous octoate, and triethanolamine), and loading of blowing agent (water) for the maximum compression strength of the rigid BPU foams. With the quadratic orthogonal regression model, verified by experimentation, the maximum compression strength of approximately 180 kPa was obtained at the following optimal conditions: NCO/OH molar ratio of 1.24:1, glycerol addition of 12.11%, catalyst loading of 0.76%, and blowing agent addition of 1.31% in relation to the total mass of polyols. The BPU foam prepared at the optimal conditions exhibits good thermal conductivity (0.045 Wm−1K−1) and thermal stability, comparable to those of a reference foam prepared with 100% PPG400.

The assessment of voltage stability margins is a promising direction for wide-area monitoring systems. Accurate monitoring architectures for long-term voltage instability are typically centralized and lack scalability, while completely decentralized approaches relying on local measurements tend towards inaccuracy. Here we present distributed linear algorithms for the online computation of voltage collapse sensitivity indices. The computations are collectively performed by processors embedded at each bus in the smart grid, using synchronized phasor measurements and communication of voltage phasors between neighboring buses. Our algorithms provably converge to the proper index values, as would be calculated using centralized information, but but do not require any central decision maker for coordination. Modifications of the algorithms to account for generator reactive power limits are discussed. We illustrate the effectiveness of our designs with a case study of the New England 39 bus system. 10 pages, submitted for publication