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Harmful algal blooms (HABs) have wide-ranging environmental impacts, including on aquatic species of social and commercial importance. In New Zealand (NZ), strategic growth of the aquaculture industry could be adversely affected by the occurrence of HABs. This review examines HAB species which are known to bloom both globally and in NZ and their effects on commercially important shellfish and fish species. Blooms of Karenia spp. have frequently been associated with mortalities of both fish and shellfish in NZ and the sub-lethal effects of other genera, notably Alexandrium spp., on shellfish (which includes paralysis, a lack of byssus production, and reduced growth) are also of concern. Climate change and anthropogenic impacts may alter HAB population structure and dynamics, as well as the physiological responses of fish and shellfish, potentially further compromising aquatic species. Those HAB species which have been detected in NZ and have the potential to bloom and harm marine life in the future are also discussed. The use of environmental DNA (eDNA) and relevant bioassays are practical tools which enable early detection of novel, problem HAB species and rapid toxin/HAB screening, and new data from HAB monitoring of aquaculture production sites using eDNA are presented. As aquaculture grows to supply a sizable proportion of the world’s protein, the effects of HABs in reducing productivity is of increasing significance. Research into the multiple stressor effects of climate change and HABs on cultured species and using local, recent, HAB strains is needed to accurately assess effects and inform stock management strategies.

Wind characteristics (e.g., mean wind speed, gust factor, turbulence intensity and integral scale, etc.) are quite scattered in different measurement conditions, especially during typhoon and/or hurricane processes, which results in the structural engineer ambiguously determining the wind parameters in wind-resistant design of buildings and structures in cyclone-prone regions. In tropical cyclones (including typhoons and hurricanes), the inconsistent wind characteristics may be in part ascribed to the complex flow structure with the coexistence of both mechanical and convective turbulence in the boundary layer of tropical cyclones. Another significant contribution to the scattered wind characteristics is due to various measurement conditions (e.g., terrain exposure and height) and data processing schemes (e.g., averaging time). The removal of the inconsistency in the field-measurement system may offer a more rational comparison of measured wind data from various observation platforms, and hence facilitates a better identification scheme of the wind characteristics to guide the urban planning design and wind-resistant design of buildings and structures. In this study, an analytical framework was firstly proposed to eliminate the potential observation-related effects in wind characteristics and then the wind characteristics of seven field measured tropical cyclones (four typhoons and three hurricanes) were comparatively investigated. Specifically, field measurements of wind characteristics were converted to a standard reference station with a roughness length of 0.03 m, observation duration of 10 min for mean wind and averaging time of 3 s for gusty wind at a 10 m height. The differences of the measured wind characteristics between the typhoons and hurricanes were highlighted. The standardized turbulent wind characteristics under the analytical framework for typhoons and hurricanes were compared with the corresponding recommendations in standard of American Society of Civil Engineers (ASCE 7-10) and Architectural Institute of Japan Recommendations for Loads on Buildings (AIJ-RLB-2004).

A new environmental ban has forced the restructure of open dumps in China since 1 July 2011. A technical process was established in this study that is feasible for the upgrade of open dumps through restructuring. The feasibility of restructuring and the benefit of greenhouse gas emission reductions were assessed according to field surveys of five landfills and four dumps in Nanjing. The results showed that the daily processing capacities of the existing landfills have been unable to meet the growth of municipal solid waste (MSW), making restructuring of the landfills imperative. According to an assessment of the technical process, only four sites in Nanjing were suitable for upgrading. Restructuring the Jiaozishan landfill effectively reduced the leachate generation rate by 5.84% under its scale when expanded by 60.7% in 2015. CO2 emissions were reduced by approximately 55,000–86,000 tons per year, in which biogas power generation replaced fossil fuels Fossil fuels accounted for the largest proportion, up to 45,000–60,000 tons. Photovoltaic power generation on the overlying land has not only reduced CO2 emissions to 26,000–30,000 tons per year but has also brought in continuing income from the sale of electricity. The funds are essential for developing countries such as China, which lack long-term financial support for landfill management after closure.

Production of biodiesel from yellow grease (waste cooking oil and waste animal fats) is fast emerging as a promising alternative to address the twin challenges before the biodiesel industry today-fluctuation in prices of vegetable oil and the food versus fuel debate. Yellow grease has a high percentage of free fatty acids (FFA) and proves to be an unsuitable feedstock for biodiesel production from commercially viable alkali-catalyzed production systems due to saponification problems.“Green” methodologies based on heterogeneous solid acid catalyzed reactions have the potential to simultaneously promote esterification and transesterification reactions of yellow grease to produce biodiesel without soap formation and offer easy catalyst separation without generation of toxic streams. This paper presents kinetic studies for the conversion of model yellow grease feeds to biodiesel using a heteropolyacid supported on alumina (HSiW/Al2O3) using a batch autoclave. Three model yellow grease feeds were prepared using canola oil with added FFA such as palmitic, oleic and linoleic acid. A pseudo homogeneous kinetic model for the parallel esterification and transesterification was developed. The rate constants and activation parameters for esterification and transesterification reactions for the model yellow grease feeds were determined. The rate constants for esterification are higher than the transesterification rate constants. The kinetic model was validated using the experimental biodiesel data obtained from processing a commercial yellow grease feed. The kinetic model could be used to design novel processes to convert various low-value waste oils, fats and non-food grade oils to sustainable biodiesel. Keywords: Yellow grease, Canola oil, Free fatty acids, Heteropolyacid, Kinetics for esterification and transesterification

Abstract In this study, crude cellulose derived from cornstalk, after bleaching, was used as raw material for the synthesis of sodium carboxymethyl cellulose (CMC) by reacting with the cellulose with NaOH and chloroacetic acid at 75 °C for 1.5 h. Effects of alkali dosage, concentration of chloroacetic acid on the physical and chemical properties of the CMC products were investigated. It was revealed that the reactants alkali reagent/chloroacetic acid/cellulose at the molar ratio of 4.6:2.8:1and 4:2.5:1, or at the molar ratio of NaOH/ClCH 2 COOH ≈1.6–1.64, resulted in CMC products of relatively high water solubility. The viscosity-average molecular weight M v of these two CMC products obtained at molar ratios of 4.0:2.5:1 and 4.6:2.8:1 is in the range of 1.94 × 10 4 –2.48 × 10 4 g mol −1 , and the average DS of the two products are 0.57 and 0.85, respectively. As the solute concentration is above 2 wt%, the viscosity of the CMC-water solution exhibits nonlinear (exponential) increasing with increasing the solute concentration (typical of non-Newton fluids).

Wide‐bandgap (WBG) perovskite solar cells (PSCs) are acknowledged as promising candidates for tandem solar cells and building photovoltaics. It is well known that cesium‐based all‐inorganic halide WBG perovskites possess the comparable optoelectronic properties as the organic–inorganic counterparts, but exhibit superior thermal stability. Among them, CsPbIBr2 is considered a feasible material for tandem solar cells after balancing the bandgap and stability of the inorganic perovskite. However, CsPbIBr2 PSCs are often subjected to drastic interfacial charge recombination especially in carbon‐based device structure derived from the chemical bonding defects (i.e., uncoordinated Pb2+) naked on CsPbIBr2 soft lattice, which dramatically limits overall efficiency of CsPbIBr2 WBG PSCs. Herein, a trimethyl ammonium salt hexyltrimethylammonium bromide is presented for CsPbIBr2/carbon interfacial modification. Benefiting from the −N+(CH3)3 passivation effect and −C6H13 hydrophobic alkyl chain, the optimal device with highly smooth morphology and sufficient charge extraction exhibits a champion power conversion efficiency of 11.24% and improved long‐term stability with 99.7% and 79.7% efficiency retention under dry air atmosphere and continuous 85 °C thermal stress, indicating the valuable potential application of the lattice solidified CsPbIBr2 WBG PSCs.

To meet the increasing demands of precision agricultural and environmental management, more abundant and accurate information is needed to describe soil organic carbon (SOC) vertical variation. Based on 923 soil profiles (collected at the depths of 0–15, 15–30, 30–60, 60–90, 90–120, and 120–150 cm) in the central area of Changhua County, Taiwan, the distribution curve of the SOC content of each profile was fitted by the equal-area spline model, and it was possible to obtain the SOC content at all depths. Taking the 0–5 cm (L1), 5–10 cm (L2), and 10–15 cm (L3) sub-layers as examples, their SOC contents and stocks were compared to the mean values of the average 5-cm-thick sub-layers (Lm) derived from the value of the 0–15 cm layer. The results indicated that the SOC contents and stocks both reduced with increasing soil depths. The mean SOC contents of L1, L2, and L3 were 22.1, 21.0, and 18.7 g·kg−1, respectively, with significant variation, and the values of L2 and L3 were 5.0% and 15.4% lower than that of L1. Similarly, the mean SOC stocks were 1.29, 1.25, and 1.16 kg·m−2 of the L1, L2, and L3 layers, also with significant variation, and the values of L2 and L3 were 4.0% and 10.1% lower than that of L1. Meanwhile, it was found that the SOC content and stock of Lm were both close to the corresponding values in L2, but were significantly different to that of L1 and L3. Furthermore, the interpolation contours of the SOC contents and stocks in L1, L2, and L3 by digital soil mapping also presented regular variation with increasing soil depths, while the contours of Lm had nearly identical patterns to that of L2. The results demonstrate that the typically used mean SOC contents with certain thicknesses calculated from the sampling layer can only approximately inflect the SOC situation at intermediate depths, but the SOC content in the upper and lower parts within the sampling layer varies greatly. Therefore, the actual distribution of SOC varies gradually depending on the soil depth. This study indicates that the combination of the equal-area spline model and digital soil mapping can greatly enrich the current soil SOC database and provide more abundant and accurate SOC content and stock information for precision agricultural and environmental management based on legacy soil database.

The microbial electrolysis desalination and chemical-production cell (MEDCC) is a device to desalinate seawater, and produce acid and alkali. The objective of this study was to enhance the desalination and chemical-production performance of the MEDCC using two types of stack structure. Experiments were conducted with different membrane spacings, numbers of desalination chambers and applied voltages. Results showed that the stack construction in the MEDCC enhanced the desalination and chemical-production rates. The maximal desalination rate of 0.58 ± 0.02 mmol/h, which was 43% higher than that in the MEDCC, was achieved in the four-desalination-chamber MEDCC with the AEM-CEM stack structure and the membrane spacing of 1.5mm. The maximal acid- and alkali-production rates of 0.079 ± 0.006 and 0.13 ± 0.02 mmol/h, which were 46% and 8% higher than that in the MEDCC, respectively, were achieved in the two-desalination-chamber MEDCC with the BPM-AEM-CEM stack structure and the membrane spacing of 3mm.