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Microwave-assisted alkali pre-treatment of wheat straw and its enzymatic hydrolysis were investigated and compared with the conventional alkali pre-treatment process. First, the effect of microwave power and pre-treatment time on the weight loss and composition of wheat straw was examined. The results show that the higher microwave power with shorter pre-treatment time and the lower microwave power with longer pre-treatment time had the same effect on the weight loss and composition at the same energy consumption. The comparison was then made between the effect of the microwave-assisted alkali pre-treatment and the conventional alkali one on the weight loss and composition of wheat straw. The wheat straw had a weight loss of 48·4% and a composition of cellulose 79·6%, lignin 5·7% and hemicellulose 7·8% after 25 min microwave-assisted alkali pre-treatment at 700 W, compared with a weight loss of 44·7% and a composition of cellulose 73·5%, lignin 7·2% and hemicellulose 11·2% after 60 min conventional alkali pre-treatment. The microwave-assisted alkali pre-treatment removed more lignin and hemicellulose from wheat straw with shorter pre-treatment time compared with the conventional alkali one. Finally, the enzymatic hydrolysis of pre-treated wheat straw (substrate concentration 50 g l−1, enzyme loading 20 mg g−1 substrate) was also investigated and the results indicate that the microwave-assisted alkali pre-treated wheat straw had higher hydrolysis rate, reducing sugar concentration and glucose content in the hydrolysate than the conventional alkali pre-treated one. Microwave-assisted alkali pre-treatment is a potential alternative of wheat straw pre-treatment for its enzymatic hydrolysis.

In the water-rich karst regions, high water and mud outbursts are common geological disasters in tunnel construction. To ensure the safe and smooth construction of tunnel projects, it is necessary to consider anti-water pressure, water inrush prevention and geological disasters during the design of tunnels. Based on the Yongfutun Tunnel Project, this paper studies the application and effect of radial grouting and curtain grouting, which involves those in high-water-pressure tunnels under double-layer support conditions. To obtain the effects and parameters of radial grouting and curtain grouting, the influences of different grouting ranges on the tunnel’s surrounding rocks and supporting structures were analyzed and the finite difference method was adopted. The results show that the radial grouting of the surrounding rock can notably improve the initial support of the tunnel, but the impact is less obvious when the grouting range exceeds 4 m. The design of radial grouting is recommended to be 4.0 m to 4.5 m. Curtain grouting can effectively reduce the external water pressure of the tunnel lining. The external water pressure of the grouting area is 23% greater than that without curtain grouting. Curtain grouting can slow down the infiltration of external water pressure. This is beneficial to the stress of the tunnel lining structure, but the improvement in initial support force is slight. Moreover, curtain grouting improves the safety reserve of the secondary lining by strengthening the self-stability ability of the surrounding rock. Meanwhile, the double-layer primary support can effectively share the external water pressure and surrounding rock pressure. This study provides a certain reference for the lining design of high-water-pressure tunnels.

Abstract Transportation de-carbonization is a complex problem involving the economy, population, technology and environment. Implementing the pathway simulation based on systematic methods will help to optimize the transportation sustainability plan. This study’s key motivation is that earlier research ignored the relationship between driving factors and the transmission process. To quantitatively identify the path and process of emission reduction, a hybrid system dynamics STIRPAT-SD model is proposed to explore the transportation optimization’s de-carbonization ability. This study fully considers the composition of elements and subsystems based on the STIRPAT theoretical model and visually shows the system’s feedback relationship. Transportation structural and technical optimization scenarios are set to identify the threshold reduction paths. It is found these optimization strategies have significant de-carbonization effects. And transportation structure policy has the highest de-carbonization efficiency, the emission intensity decreased by 9.1% under the TSS2 scenario (Transportation structure scenario). This study proposes a novelty model combining dynamic simulating processes with a significantly theoretical model to improve simulation and factor composition accuracy. And the joint scenario setting identifies the most effective de-carbonization pathway and clarifies the threshold of all possible pathways. Research findings can effectively track, test, predict the achievement of policy goals, and provide policy optimization references for the sustainable development related to the transportation system in practice.

Abstract In this paper, coupled governing equations were proposed to simulate three-dimensional heat conduction and moisture transport in the nuclear waste repository. Because there will be a large temperature gradient near inner and outer boundaries of the bentonite buffer layer, and the heat driven moisture transport is introduced in the governing equation of moisture transport. By applying the Fourier and Laplace transforms, the governing equations were converted to the Bessel equations, and the Laplace-domain solutions to temperature and moisture distributions were derived through the inverse Fourier transform. The reliability of the proposed solutions was verified through comparative analysis with the line heat source model. These analytical solutions were applied to obtain the evolutions of temperature field and moisture distribution near the waste canister. Finally, a sensitivity study was performed to analyze the effects of relevant parameters on the heat driven moisture transport.

This study aims to explore the application of fractional order chaotic system (FOCS), based on the T-S fuzzy model, in the design of secure communication (SC) and this SC system’s role in the construction of efficiency evaluation system for dispatching operation of energy saving and power generation under a low carbon economy (LCE). First, the definition of fractional order differential equations and the stability theory of FOCS are discussed. T-S fuzzy control is introduced to analyse the stability of FOCS. Then, based on the adaptive synchronisation theory, the combined FOCS is designed for SC, and the performance of the system constructed here is analysed in a MATLAB environment. Next, an evaluation index system of the dispatching operation effect of energy saving and power generation under LCE is constructed. The confidential communication system constructed here is used to transmit the index data. The particle swarm optimisation (PSO) algorithm is then used to optimise the back propagation neural network (BPNN) model. The BPNN algorithm based on PSO (PSO-BPNN) is obtained, and the evaluation model is constructed. After training this model, it is applied to the evaluation of the dispatching operation effect for energy saving and power generation in 10 provinces in China. The simulation results show that the FOCS based on the T-S fuzzy model can acquire the criterion of system stability. Furthermore, the constructed SC system can effectively undertake the secure transmission of square and sine waves. The performance of the PSO-BPNN model seems to be better than other algorithms. After analysing the data on energy saving and power generation from 10 provinces in China using this model, the comprehensive evaluation value of province 5 is found to be the highest and good (0.802), while that of province 4 is the lowest and general (0.600). Summarising, the FOCS based on T-S fuzzy model constructed here is applied to the design of SC. This can improve the confidentiality of data transmission and reduce the transmission error. Moreover, the BPNN evaluation model based on PSO can effectively achieve the evaluation of the dispatching operation effect of energy saving and power generation under LCE.

Energy is consumed at every stage of the cycle of water production, distribution, end use, and recycled water treatment. Understanding the nexus of energy and water may help to minimize energy and water consumption and reduce environmental emissions. However, the interlinkages between water and energy have not received adequate attention. To address this gap, this paper disaggregates and quantifies the energy consumption of the entire water cycle process in Beijing. The results of this study show that total energy consumption by water production, treatment and distribution, end use, and recycled water reuse amounts to 55.6 billion kWh of electricity in 2015, or about 33% of the total urban energy usage. While water supply amount increased by only 10% from 2005 to 2015, the related energy consumption increased by 215% due to water supply structural change. The Beijing municipal government plans to implement many water saving measures in the area from 2016 to 2020, however, these policies will increase energy consumption by 74 million kWh in Beijing. This study responds to the urgent need for research on the synergies between energy and water. In order to achieve the goal of low-energy water utilization in the future, water and energy should be integrated in planning and management.

Abstract The Chinese government has taken measures to realize energy-savings and emission reductions, such as promoting innovations, adjusting the industrial structure, balancing regional development, and reforming markets. The aim of this paper is to assess the effects of these measures on China's CO2 emissions by using a newly proposed decomposition approach, which identified eight new factors related to the above realistic measures, i.e., energy saving and production technologies, industrial energy and production efficiencies, regional energy and production efficiencies, and pure energy and production efficiencies. The main findings indicate benefits from considerable technological progress in energy-saving and production during 2000–2016 period, and two technological factors contributed the most to emissions abatement and cumulatively reduced 5372.43 Mt and 1291.72 Mt CO2 emissions. The efforts of industrial restructuring promoted energy and production efficiency improvement, which further facilitated emission reduction. In contrast, the pure energy and production efficiency changes cumulatively led to 1080.26 Mt and 1135.85 Mt CO2 emissions growth during the whole sample period, suggesting that severe resource misallocation problems may exist in both the energy market and output market. Additionally, the Chinese government failed to narrow the technology gap between developed regions and underdeveloped regions, further restricting emission reduction.

Abstract CBM reservoirs are extremely vulnerable to damage due to their complex pore structure. So, changing pore structures in CBM reservoirs is of vital importance for reducing reservoirs damage. Organic solvents have been considered as additives into fracturing fluids to enhance production because they can enhance the pore connectivity and loosening macromolecular network structure. It is thus of great interests to investigate how organic solvents (ethanol and ethylene glycol ether) change micropore structures and fluid distribution. In this study, samples were selected from different wells completed in No. 3 coal seam, Zhaozhuang minefield. Low-pressure nitrogen adsorption (LP-N2GA) experiments were conducted on coal samples to evaluate the changes in pore-structure parameters including specific surface area (SSA), pore diameter, and pore volume. NMR experiments were conducted on coal samples to evaluate the changes in fluid distribution. Analyzing the LP-N2GA results suggests ethylene glycol ether and ethanol can effectively increase SSA, pore diameter, and opening degree of pores in coal samples. Comparative analysis of NMR results indicates that ethylene glycol ether consistently reduces the irreducible water saturation (Swir) in samples. The average value of Swir of raw samples is 0.8670 and the average value of Swir of samples treated with ethylene glycol ether value is 0.7644. Considering the pore-structure alterations, this study demonstrates that ethylene glycol ether is more preferable for enhancing recovery from CBM reservoirs compared with ethanol.

As a porous medium with rich pore structure, activated carbon (AC) was once considered the best carrier for hydrate storage and transportation. However, the harsh conditions of the hydrate reaction in the wet carbon environment have always limited the sufficient and rapid formation of hydrate. Therefore, the influences of particle size (4–8, 8–16, 20–40 and 100 mesh) and liquid phase saturation (fully/partially saturated) in the sodium dodecyl sulfate system on hydrate reaction were investigated. The results showed that small particle in the fully saturated liquid phase system led to the increase in hydrate generation rate, with the highest hydrate reaction rate of 3.16 mmol/min in the 100 mesh AC layer, which was 1.7–2.9 times higher than other AC layers. The gas storage capability of the 4–8 mesh AC layer with a water saturation of 70% was the highest among all systems, reaching 0.198 mol/mol. The saturation of the liquid phase induced the nucleation and growth of hydrates. Adherently growing hydrates of fully saturated liquid phase systems and mushroom-like hydrates of partially saturated liquid phase systems were found in turn. This research facilitates the commercialization of AC-based hydrate technology.