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Green ammonia is gaining momentum as a globally significant technology for deep decarbonisation. In this thesis, several models are developed across chemical, techno-economic, and energy system modelling disciplines to explore the future role of green ammonia. First, standalone models of production (i.e., power-to-ammonia) and re-electrification (i.e., ammonia-to-power) are developed and compared to competing technologies. Second, these models are integrated into a planning and dispatch energy system model (ESM) of India to 2050. The ESM has several novel additions including the sector coupling of hydrogen and ammonia, multiple years of granular weather data, and learning-curve-based technology cost forecasts. India is chosen as an ideal case study given its globally unmatched demand growth in all three relevant sectors: electricity, green hydrogen, and green ammonia. The projected electricity demands for green hydrogen and ammonia production account for 25% of the total Indian electricity demand in 2050, underscoring the transformational potential that green hydrogen and ammonia sector coupling can have on the Indian energy system. The results of the state-of-the-art ESM highlight synergistic effects of hydrogen and ammonia sector coupling with the power system. The least-cost system employs seasonal green ammonia production paired with up to 40 million tonnes (i.e., 200 TWh) of ammonia storage, as well as some re-electrification via gas turbines. Sector coupling reduces system curtailment, addresses challenges of long-duration storage, and improves system resilience to interannual weather variations. While India is a crucial case study from a global decarbonisation perspective, the methodology and findings are generally applicable, and it is the aim of this work to motivate and accelerate the wider research community into considering the potential impacts of green ammonia sector coupling on electricity grid design. Finally, this work highlights strategic technology development direction for ammonia producers and gas turbine manufacturers, as well as implications for policymakers.

Voluntary environmental management programs for firms have become an increasingly popular instrument of environmental policy. However, the literature’s conclusion on the effectiveness of suchprograms is ambiguous, and for the European region there is a lack of evidence based on a large control group. We seek to fill this gap with an evaluation of the Eco-Management and Audit Scheme (EMAS), introduced in 1995 by the European Union as a premium certification of continuous pro-environmental efforts above regulatory minimum standards. It is more demanding than other voluntary programsdue to annual public reports of the environmental performance and targets for improvements. We use official firm-level production census data on the German manufacturing sector, a major energy consumer and emitter in Europe. To account for the self-selection of firms, we combine the Coarsened Exact Matching approach with a Difference-in-Differences estimation. Our results do not suggest reductions of firms’ CO2 intensity and energy intensity neither before nor after certification. Moreover, program participants do not increase renewable energy consumption or investments into the protection of the environment and climate. Our results are robust to a variety of checks and call into question the effectiveness of the EMAS program concerning these particular outcome variables.

Abstract In many cases, hazardous wastes are subject to thermal treatment at elevated temperatures. Some types of wastes do not have a sufficient calorific value to cover the heat demand of the high temperature process. For thermal treatment of e.g. filter residues, dusts, sulfuric acid, aluminium dross, foundry sand, or waste water, supplementary energy supply is needed. The specific energy demand ranges from 0.5 to 2.5 kWh/kg (2–10 MJ/kg). An important aim of process optimisation is the reduction of (fossil) energy consumption and exhaust gas flow. Concentrated solar energy promises advantages when applied to high energy consuming waste treatment processes with regard to substitute fossil or electric energy consumption, to reduce CO2 emissions, and exhaust gas flow. In parallel to conceptional studies, a solar-heated rotary kiln mini-plant has been designed and constructed for tests in the DLR solar furnace. The tests will give indications of boundary conditions for solar thermal treatment or conversion of selected hazardous materials.

The global community has set intensive targets in Sustainable Development Goals (SDGs) to better people’s lives after closing the Millennium Development Goals (MDGs). It corresponds to the 2030 aspirations of the United Nations to enhance and promote the sustainable development of human society. The current paper explores the impact of fiscal hedging and R&D in energy Using a green-energy system in SDGs. To do this, we used TOPSIS and QARDL methodologies on a 21-year dataset of South and Southeast Asian economies from 2000 to 2020. The study results show that fiscal hedging contributes favourably to the environmental degradation of the underlying economy. Research and development (R&D) in renewables has contributed negatively to ecological degradation and SDGs in the economies of South & Southeast Asia. This study suggests policy guidelines for advanced and developing economies based on fiscal stability and technical innovation through R&D to meet SDG.

Abstract Solid-solid phase change materials (SSPCMs) with small volume change and leak-proof characteristic during the whole process of phase change play a vital role in development of PCM for thermal energy storage (TES). However, the non-recyclability of the materials due to their permanent cross-linking networks limited their practical application. Herein, a dynamic urethane bond cross linked SSPCM with PEG as phase change functional segments was successfully fabricated which was in solid state even at 130°C.Meantime, it exhibited excellent solid-state plasticity, resulting from dynamic urethane bond exchange. Moreover, the dynamic behavior of urethane bond in SSPCMs was firstly investigated. The topology freezing transition temperature (Tv) is about 113°C and the relaxation activation energy of SSPCM is calculated to be about 90 kJ/mol. The crystalline PEG endows SSPCM with high enthalpy value (reached up to 85 J/g), meantime, the cross-linked structure endows SSPCMs with remarkable mechanical flexibility (possess ultra-stretchability of 600%), thermal reliability and chemical stability. The combined thermal storage ability, appealing recyclability and flexibility endow the SSPCM promising application in the field of TES.

Oil sludge (OS) is a typical hazardous waste from the petrochemical industry. Currently, the increasing ratio of high-sulfur crude oil worldwide that results in the growth production of OS with hig...

Abstract China's carbon emissions have been ranking first in the world. This study filled in the gaps in research, decomposed carbon intensity from the perspective of time, space and industry. A decoupling effort model based on factor decomposition models was constructed to analyze the driving factors of carbon emissions and economic decoupling, which builded a foundation for achieving sustainable economic development. Using the Logarithmic Mean Divisia Index method (LMDI), the paper measured the carbon emission intensity of 29 provinces and cities in China from 1998 to 2019, and decomposed the decoupling effect between GDP and carbon emission on the basis of factor decomposition by tapio. The results showed that: (1) Carbon intensity declined first, then rise lightly, and finally declined steadily. For the primary industry and the tertiary industry, the carbon intensity declined steadily, while the carbon intensity increased accordingly to the overall carbon intensity. In terms of spatial evolution, the regional differences between different provinces decreased correspondingly. (2) The cumulative contribution rates of these three effects, i.e., technological progress, industrial structure and regional scale were 106.3299%, −15.1486% and 8.8188%, respectively. There were obvious differences of these cumulative contribution rates of carbon intensity among different provinces. (3) From the perspective of industrial, technological progress effect is the largest contribution for carbon intensity in the secondary industry. The Industrial structure effect mainly affects the primary and tertiary industries; and no significant difference in regional scale effect. (4) The decoupling effect gradually improved, and technological progress has played an absolute leading role in promoting the decoupling effect. Based on the research results, the key policy recommendation are put forward as follows: (1) Further improve the technological level and support clean technology enterprises. (2) Promote industrial upgrading in backward industrial provinces (3) Promote regional assistance and the introduction of high-quality foreign investment.

With rapid progress in the corporate social responsibility (CSR) theories and the up-gradation of the global market information disclosure system, enterprises have increased their attention toward relevant stakeholders and social responsibility. CSR exerts a substantial impact on the sustainable development of enterprises and markets in the economic and social fields. On the one hand, the increasingly perfect supporting facilities promote the financial growth of the entire society. While on the other hand, the profit-seeking trend of capital is also on the rise. The incongruity between the rapid progress of enterprises and the lack of social responsibility limits the benign development of the market. This study discusses the antecedents of CSR from the variable combination perspective using the fuzzy-set qualitative comparative analysis. It also investigates which combination of characteristics has better CSR performance. After the configuration analysis, it is identified that four paths lead to high CSR performance. These include the market-developed type, political link type, financial performance type, and state-owned enterprise subsidy type, and the level of each type is explained in-depth. Finally, this study provides management inspiration for the government and enterprises to formulate a sound social responsibility strategy and improve CSR performance by optimizing the matching of CSR activities and business objectives.