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Abstract In the present study, Loblolly pine biomass residue was converted to bio-oil in a two-step process, consisting of 1) fast pyrolysis in the presence of zeolite ZSM-5 as a catalyst to produce pyrolysis oil, 2) hydrogenation of pyrolysis oil using formic acid as the hydrogen source in presence of Ru/activated carbon catalyst. Pyrolysis oils were analyzed by 13C, 31P and HSQC-NMR and the results revealed that the zeolite-induced catalytic fast pyrolysis process led to effective demethoxylation, producing more catechol and p-hydroxy-phenyl hydroxyl groups in the bio-oils, resulting in a decrease in the methoxyl group content by about 85 % and rich aromatic structures in the pyrolysis oils. The properties of pyrolysis oil with and without zeolite were in the bio-oil range. Hydrogenated pyrolysis oil showed that 79 % of the aromatic protons are eliminated and 87 % of protons are aliphatic in nature, with no oxygen attached to the α-carbon.

Cattail-grass-derived porous carbon as high-capacity anode materials were prepared via high-temperature carbonization and activation with KOH. The samples exhibited different structures and morphologies with increasing treatment time. It was found that the cattail grass with activation treatment—1 (CGA-1) sample obtained at 800 °C for 1 h presented excellent electrochemical performance. As an anode material for lithium-ion batteries, CGA-1 showed a high charge–discharge capacity of 814.7 mAh g−1 at the current density of 0.1 A g−1 after 400 cycles, which suggests that it has a great potential for energy storage.

The ‘4 per mille Soils for Food Security and Climate’ was launched at the COP21 with an aspiration to increase global soil organic matter stocks by 4 per 1000 (or 0.4 %) per year as a compensation for the global emissions of greenhouse gases by anthropogenic sources. This paper surveyed the soil organic carbon (SOC) stock estimates and sequestration potentials from 20 regions in the world (New Zealand, Chile, South Africa, Australia, Tanzania, Indonesia, Kenya, Nigeria, India, China Taiwan, South Korea, China Mainland, United States of America, France, Canada, Belgium, England & Wales, Ireland, Scotland, and Russia). We asked whether the 4 per mille initiative is feasible for the region. The outcomes highlight region specific efforts and scopes for soil carbon sequestration. Reported soil C sequestration rates globally show that under best management practices, 4 per mille or even higher sequestration rates can be accomplished. High C sequestration rates (up to 10 per mille) can be achieved for soils with low initial SOC stock (topsoil less than 30 t C ha− 1), and at the first twenty years after implementation of best management practices. In addition, areas which have reached equilibrium will not be able to further increase their sequestration. We found that most studies on SOC sequestration only consider topsoil (up to 0.3 m depth), as it is considered to be most affected by management techniques. The 4 per mille number was based on a blanket calculation of the whole global soil profile C stock, however the potential to increase SOC is mostly on managed agricultural lands. If we consider 4 per mille in the top 1m of global agricultural soils, SOC sequestration is between 2-3 Gt C year− 1, which effectively offset 20–35% of global anthropogenic greenhouse gas emissions. As a strategy for climate change mitigation, soil carbon sequestration buys time over the next ten to twenty years while other effective sequestration and low carbon technologies become viable. The challenge for cropping farmers is to find disruptive technologies that will further improve soil condition and deliver increased soil carbon. Progress in 4 per mille requires collaboration and communication between scientists, farmers, policy makers, and marketeers.

The present study is motivated by the need to decouple economic growth from environmental degradation given the new wave of chase for higher economic growth trajectories comes with its environmental cost implications, especially among developing blocs like the Emerging 7 (E7) countries. There is a consistent trade-off between economic growth versus environmental quality. Government apparatus are perpetually on the chase for low-carbon emission policies via the pursuit for green economy. To this end, this present study extends the conventional environmental Kuznets curve (EKC) argument by incorporating the role of institution in emerging industrialized economies (E7) and using second-generation panel analysis methods like mean group (MG), augmented mean group (AMG), common correlated effects mean group (CCEMG), and the Dumitrescu and Hurlin causality test for more robust estimates and inferences. To this end, we explore the long-run and causality relationship between economic growth, quadratic form of economic growth, institutional quality, trade flow, investment in energy sector, and financial development in an EKC environment. Empirical analysis established a long-run equilibrium relationship among the outlined variables over the study period. The long-run regression shows the presence of EKC in the E7. Thus, suggesting the preference for GDP growth over environmental quality at the earlier stage of growth curve. Interestingly, investment in energy, trade flow dynamics across the blocs, and financial development dampens the detrimental effect of environmental pollution as we observed negative relationship with the ecological footprint. On the contrary, quality of institution is weak as institutional quality increase (worsen) the quality of environment in the E7 economies. From a policy perspective, this current study proposed the need for more stringent environmental treaties and regulations and promotion of green economy without compromising economic growth. In the conclusion part of the study, more details and specifics about the policy blueprint are presented.

Abstract Gold nanoparticles (Au-NPs) seeded plasmonic nanofluids (PNFs) have shown promising results in overall performance enhancement of direct absorption solar collector (DASC) due to localized surface plasmon resonance (LSPR) effect. For the work presented here, Au-NPs were synthesized by the wet chemical method and were utilized to prepare plasmonic nanofluid. The surface plasmon resonance peak of Au-NPs was observed at 531 nm using UV–Visible spectrophotometer study. The testing for performance enhancement of gold plasmonic nanofluid (GPNF) laden DASC so far is limited to laboratory scale setups or simulation studies. Considering the dearth of outdoor experimental studies, an attempt has been made in the present study to evaluate the thermal performance of Au-NPs (∼40 nm) based nanofluid (∼0.0002 wt%) in full scale DASC. The experiments have been performed at different flow rates under clear sky outdoor conditions in winter season at Jalandhar, India. The maximum collector outlet temperature was measured to be 55 °C with GPNF which is about 7 °C higher than the maximum outlet temperature obtained with de-ionized water as working fluid. Thermal efficiency with GPNF is about 33% higher than de-ionized water at the optimal flow rate of 0.030 kg/s.

LoRA stands for Long Range communication. Lo-RAwan is the specification used for the battery operated and wireless systems. The main aim of the LoRA is to target the Internet Of Things requirement and also Bidirectional communication. In order to prove the proof of concept, here we are creating a smart prepaid electric meter which will consist of lora module along with it. All the data related to the meters i.e voltage, energy power etc will be send to a gateway. Gateway is the central unit or router which collects all the data from all the meters and it is connected with the local storage device or PC which will create the database for all the data, Now this data is again uploaded to the cloud by this pc to the public network, which can be accessed from any of the place. The most important part of this is that this concept of communication can be extended to other application in which the data transmitted bits is less. As a result of this we can overcome the disadvantage of the 3G/4G GSM modules and low power WAN i.e. LORA can be used for communication.

In this paper, we investigate the energy harvesting (EH) technique and accordingly design transceivers for a $K$ link multiple-input multiple-output interference channel. Each link consists of two full-duplex (FD) Internet of Things (IoT) nodes exchanging information simultaneously in a bi-directional communication channel. All the nodes suffer from interference, in particular strong self-interference and inter-node interference, due to operating in FD mode and simultaneous transmission at each link, respectively. Further, we divide the received signal at each node into two parts. While one part of the signal is used for information decoding, the other part is used for EH. We jointly design the transmit and receive beamforming vectors and receiver power splitting ratios by minimizing the total transmission power of the system, subject to both signal-to-interference-plus-noise ratio and EH threshold constraints. Furthermore, the case of multiple-input single-output interference channel is also included for the sake of comparison. We also revisit the above problems for the case when the available channel state information (CSI) at the transmitters is imperfect, where the errors of the CSI are assumed to be norm bounded. Simulation results show that the EH technique can harvest enough energy to support power consumption limited IoT devices by aiding in recharging their respective batteries.