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In the current situation with the unprecedented deployment of clean technologies for electricity generation, it is natural to expect that storage will play an important role in electricity networks. This paper provides a qualitative methodology to select the appropriate technology or mix of technologies for different applications. The multiple comparisons according to different characteristics distinguish this paper from others about energy storage systems. Firstly, the different technologies available for energy storage, as discussed in the literature, are described and compared. The characteristics of the technologies are explained, including their current availability. In order to gain a better perspective, availability is cross-compared with maturity level. Moreover, information such as ratings, energy density, durability and costs is provided in table and graphic format for a straightforward comparison. Additionally, the different electric grid applications of energy storage technologies are described and categorised. For each of the categories, we describe the available technologies, both mature and potential. Finally, methods for connecting storage technologies are discussed.

Considerable interest is being shown in using biochar production from waste biomass with a variety of disciplines to address the most pressing environmental challenges. Biochar produced by the thermal decomposition of biomass under oxygen-limited conditions is gaining popularity as a low-cost amendment for agro-ecosystems. The efficiency of biochar formation is affected by temperature, heating rate, feedstock type, particle size and reactor conditions. Properties such as pH, surface area and ash content of produced biochar increases with increasing temperatures. Biochar produced at lower heating rates may have high porosity and be beneficial for morphological changes in the soil. Biochar can help to enhance soil health and fertility as well as improve agricultural yield. As a result, biochar can assist in increasing food security by promoting sustainable agricultural systems and preserving an eco-friendly environment. Biochar is also widely being used as a sorbent for organic and inorganic pollutants, owing to its large surface area, allowing it to be immobilized from soil with ease. The functional groups and charges present on the surface of biochar play an important role in pollutants removal. This review focuses on the mechanisms of biochar production using different waste materials as a feed stock, factors that influence biochar quality as well as application of biochar in agricultural soil and their reclamation as well. This article also discusses knowledge gaps and future perspectives in the field of biochar-based toxic-pollution remediation.

Massive adoptions of combined heat and power (CHP) units necessitate the coordinated operation of power system and district heating system (DHS). Exploiting the reconfigurable property of district heating networks (DHNs) provides a cost-effective solution to enhance the flexibility of the power system by redistributing heat loads in DHS. In this paper, a unit commitment considering combined electricity and reconfigurable heating network (UC-CERHN) is proposed to coordinate the day-ahead scheduling of power system and DHS. The DHS is formulated as a nonlinear and mixed-integer model with considering the reconfigurable DHN. Also, an auxiliary energy flow variable is introduced in the formed DHS model to make the commitment problem tractable, where the computational burdens are significantly reduced. Extensive case studies are presented to validate the effectiveness of the approximated model and illustrate the potential benefits of the proposed method with respect to congestion management and wind power accommodation. (Corresponding author:Hongbin Sun)

Robust mitigation options will play significant role in achieving the target of limiting global change to below 1.5 °C above pre-industrial levels by 2100. To support cooperation for mitigation development, we establish a real options-based model to evaluate the rational decisions of exercising the abandon option for carbon capture and storage-enhanced oil recovery (CCS-EOR) projects under oil market and geological uncertainties. Three possible cooperative mechanisms (fixed carbon dioxide (CO2) price, oil-indexed CO2 price, and joint venture contracts) among CO2-EOR stakeholders are evaluated. The results show that the conflicts in profit maximization targets for different stakeholders in cooperative mitigation are to a great extent unable to be avoided. A joint venture business model is preferred in cooperative mitigation as it can effectively weaken such conflicts. And it is more reasonable to provide incentives to the downstream of the CO2-EOR chain than compensating the adoption cost of carbon capture technologies in the upstream. From a global perspective, the inefficient cooperation can be a main barrier that hinders the development of deep-cutting options. Global mitigation strategies should not only focus on promoting technology progress but also the design of innovative business models to balance the benefits among stakeholders. A joint venture business model is recommended in both the developed and developing countries for seizing the early mitigation opportunities.

For the first time, we here propose a green methodology to modify a low bandgap polymer for highly efficient solar cells using atmospheric pressure plasma jet or soft plasma operating on different feeding gases (air, Ar and N2). The physical properties of the modified polymer were investigated using conductivity measurements, UV-visible spectroscopy, photoluminescence spectroscopy, X-ray photoelectron spectroscopy, cyclic voltammograms, atomic force microscopy, cathodoluminescence and confocal Raman spectroscopy. Further, we examined the variation of the work function of the polymer before and after plasma treatment using a γ-focused ion beam. Additionally, photovoltaic cells based on the plasma-modified polymer having ITO/PEDOT:PSS/PHVTT (with or without plasma modification):PC71BM/LiF/Al configuration were fabricated and then characterized. We found that the power conversion efficiency (PCE) of the plasma-modified polymer increased dramatically as compared to the control polymer (without plasma treatment). PCE of the control polymer was found to be 4.11%, while after air, Ar and N2 gas plasma treatment the polymer showed PCEs of 4.85%, 4.87% and 5.14% respectively. Thus, plasma treatment not only alters the surface properties, but also modifies the bulk properties (changes in HOMO and LUMO bandgap level). Hence, this work provides new dimensions to explore more about plasma and polymer chemistry.

The growing population and increasing urbanization have led to a surge in domestic wastewater generation, posing significant challenges for effective and sustainable treatment. The present study demonstrates a novel and sustainable approach for the onsite treatment of domestic wastewater using an integrated settler-based biofilm reactor (ISBR) with efficient biogas generation. The ISBR provides an optimized environment for the growth of biofilm, facilitating the removal of organic pollutants and pathogens. Moreover, the ISBR enables the recovery of a valuable resource in the form of biogas, thus enhancing the overall utility of the treatment process. The performance of the ISBR was comprehensively evaluated at laboratory scale through treating the actual domestic wastewater generated from the hostel of Manipal University Jaipur. The ISBR system was operated under an ambient environment at a hydraulic retention time (HRT) of 24 h. The results demonstrated remarkable efficiency in terms of chemical oxygen demand (COD), total suspended solids (TSS), and coliforms removal, with average removal efficiency being more than 90%. According to the COD mass balance analysis, 48.2% of the influent COD was recovered as bioenergy. The chromatogram revealed a high percentage of methane gas in the collected biogas sample. The field emission scanning electron microscope (FESEM) analysis of the accumulated sludge in the ISBR system depicted the morphology of methanogenic bacteria. Both the experimental and theoretical results confirmed the feasibility and sustainability of the ISBR system at the onsite level.

A thermoelectric generator with zero internal resistance, vanishing heat leakage and negligible production of Thomson heat is considered. It is shown that such a generator behaves as an ideal Carnot engine or an endoreversible Carnot engine depending upon whether the heat transfer mechanism at the junctions is reversible or a finite rate. Furthermore, the optimized power of the generator is found to be greater than that of the endoreversible Carnot engine.

Abstract The potential of using high metals containing coal gangue and lignite to prepare high-activity coal char-based catalysts is investigated for effective biomass tar decomposition. Loose structure and rough surface are formed for these char-based catalysts with heterogeneous distribution of a large number of inorganic particles. In the biomass tar decomposition, the performance of the coal char-based catalysts is significantly influenced by the content of the metals in the raw materials and coal gangue char (GC) with the ash content as high as 50.80% exhibits the highest activity in this work. A high biomass tar conversion efficiency of 93.5% is achieved at 800 °C along with a significant increase in the fuel gas product. During the five-time consecutive tests, the catalytic performance of GC increases a little at the second or third times reuse and remains relatively stable, showing the remarkable stability of the catalyst in biomass tar decomposition applications.