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Abstract The aim of this study was to explore the utilization of Pennisetum sinese as cellulose source for the preparation of cellulose nanocrystals (CNC). The cellulose was extracted from P. sinese by chemical treatment and bleaching, and obtained cellulose nanocrystals by acid hydrolysis. Transmission electron microscopy (TEM) showed that CNC were rod-like with the diameter of 20–30 nm and the length of 200–300 nm. Fourier transform infrared (FTIR) showed that chemical treatment removed most of the lignin and hemicellulose from P. sinese , and CNC had similar structure to that of native cellulose. The crystallinity indexes calculated from X-ray diffraction (XRD) for P. sinese and CNC were 40.6% and 77.3%, respectively. The zeta-potential analysis showed that CNC had higher stability than P. sinese had. The thermal stability was investigated by thermogravimetric analysis (TGA), and the result showed that P. sinese had higher thermal stability than that of prepared CNC.

Renewable energy has become more popular since it is cost-effective and more efficient than conventional energy sources. Biomass-based renewable energy is primarily used in emerging economies to ensure environmental sustainability. This study examines the asymmetric correlation between biomass energy consumption and CO2 emissions in the top-10 biomass energy consumer countries (Brazil, Canada, Thailand, China, Italy, India, Germany, USA, UK, and Japan). A new approach "Quantile-onQuantile (QQ)" is employed by utilizing the data from 1991 to 2018. Biomass energy consumption, with the exception of Thailand, significantly mitigates CO2 emissions at various quantiles in selected countries. As a robustness check, we used the quantile regression test, whose findings are consistent with the outcomes from the quantile-on-quantile method. However, the degree of asymmetry in the biomass energy-CO2 nexus varies by country, necessitating extra attention and government vigilance when developing biomass energy and environmental policies.

It's not only the carbon in the trees Forest loss affects climate not just because of the impacts it has on the carbon cycle, but also because of how it affects the fluxes of energy and water between the land and the atmosphere. Evaluating global impact is complicated because deforestation can produce different results in different climate zones, making it hard to determine large-scale trends rather than more local ones. Alkama and Cescatti conducted a global assessment of the biophysical effects of forest cover change. Forest loss amplifies diurnal temperature variations, increases mean and maximum air temperatures, and causes a significant amount of warming when compared to CO 2 emission from land-use change. Science , this issue p. 600

Abstract Metallic solid-liquid phase change materials (SLPCMs) are crucial for the thermal energy storage technology of various industrial systems. However, the encapsulation of metallic SLPCMs is still technically difficult. In this pursuit, the present research envisaged the development of a novel technology to successfully prepare the core(=Al-Si/Bi)/void/shell(=Al2O3) composite SLPCMs by using Al/Bi immiscible alloy powders as starting material and tetraethoxysilane as SiO2 source. The Al-Si alloy and Al2O3 shell were in-situ synthesized by the displacement reaction between SiO2 and molten Al. Interestingly, most of the Bi distributed in the shell of Al/Bi immiscible alloy powders could not only improve the activity of alloy powders and promote the formation of precursor shell, but also be recycled by evaporation to form the void layer during the calcination process of composite SLPCMs. The produced void layer provided a space buffer to alleviate the volume expansion of the core SLPCM, and thereby improving the thermal cycling stability of the prepared composite SLPCMs. The thermal cycling test results showed that after 300 thermal cycles, the melting latent heat reduction of the core(=Al-Si/Bi)/void/shell(=Al2O3) composite SLPCMs (24.3–31.7 J/g) was much less than that of the core(=Al-Si)/shell(=Al2O3) composite SLPCM (58.1 J/g). Moreover, the prepared Al-Si/Bi/Al2O3 exhibited an adjustable melting temperature (571.9 °C to 631.9 °C) and average particle diameter (39.3 μm to 112.6 μm), relatively high thermal conductivity [2.068 W(mK)−1 to 2.966 W(mK)−1], and excellent thermal energy storage capacity (209.5 J/g to 278.2 J/g). Thus, the prepared Al-Si/Bi/Al2O3 composite SLPCMs are potential thermal energy storage materials, which can be used to improve the energy efficiency of various industrial systems.

With the large-scale integration of distributed generators (DGs), the coupling relations between transmission network (TN) and distribution networks (DNs) are getting closer. Coordinating the black-start processes of TN and DNs is beneficial to improving restoration efficiency. Therefore, a distributed black-start optimization method for global transmission and distribution (T&D) network is proposed in this paper. Firstly, a black-start optimization model of global T&D network is established to minimize the outage costs. Then, it is decomposed into the TN black-start optimization sub-problem and several DN black-start optimization sub-problems based on the analytical target cascading (ATC). The mixed integer quadratic programming (MIQP) is used for sub-problem modeling. The models take into account the restoration operations of different grid components at each black-start time step. The transmission control center (TCC) and distribution control centers (DCCs) only need to exchange partial information including the boundary power at each time step for distributed coordination, to obtain the coordinated black-start scheme for T&D network. Finally, the effectiveness of the proposed model and method is validated using a global T&D network case.

This study highlights how Chinese economic development detrimentally impacted water quality in recent decades and how this has been improved by enormous investment in environmental remediation funded by the Chinese government. To our knowledge, this study is the first to describe the variability of surface water quality in inland waters in China, the affecting drivers behind the changes, and how the government-financed conservation actions have impacted water quality. Water quality was found to be poorest in the North and the Northeast China Plain where there is greater coverage of developed land (cities + cropland), a higher gross domestic product (GDP), and higher population density. There are significant positive relationships between the concentration of the annual mean chemical oxygen demand (COD) and the percentage of developed land use (cities + cropland), GDP, and population density in the individual watersheds (p < 0.001). During the past decade, following Chinese government-financed investments in environmental restoration and reforestation, the water quality of Chinese inland waters has improved markedly, which is particularly evident from the significant and exponentially decreasing GDP-normalized COD and ammonium (NH4+-N) concentrations. It is evident that the increasing GDP in China over the past decade did not occur at the continued expense of its inland water ecosystems. This offers hope for the future, also for other industrializing countries, that with appropriate environmental investments a high GDP can be reached and maintained, while simultaneously preserving inland aquatic ecosystems, particularly through management of sewage discharge.