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  • Authors: Zhang Peng-jun; Dai Shi-xun; Cao Ying; Peng Bo; +3 Authors

    series of chalcohalide glasses based on the composition 0. 9 (Ge-25 Ga-5 S-70)-0. 1CsI doped with the different Tm3+/Dy3+ ions ratio were synthesized by melt-quenching technique. The absorption spectra, and mid-infrared fluorescence of different glass samples under 800 nm laser excitation were measured. The results prove that, Tm3+ is an efficient sensitizer, which can enhance the Dy3+ : 2.9 mu m fluorescence intensity significantly. A decrease in the intensity of 1. 8 mu m fluorescence and lifetimes of the Tm3+ : F-3(4) level occurred with increasihg the concentration of Dy3+ ions from 0 to 1 Wt% where Tm3+ concentration was fixed to 0. 5 Wt%. Also a wide spectral oveflap between Tm3+ : 1. 8 mu m emission and the absorption of Dy3+ : H-6(15/2)-> H-6(11/2) level.

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  • 随着微器件的商业化,非常态工作环境成了影响器件高精度与可靠性获得的重要因素。作为这些微结构的核心元件,微谐振器在非常态环境下的谐振特性研究变得越来越重要。本论文以微谐振器为研究对象,设计温度敏感与阻尼敏感两类谐振器结构,从理论推导、建模仿真与实验验证三方面研究微谐振器谐振频率的温度变化规律,以及系统阻尼与真空关系。主要研究内容和成果如下: 1)简述典型支撑梁固有频率的温度系数模型,梳理支撑梁温度敏感参数,分析温度影响支撑梁固有频率的规律性机制,并以此作为设计目标,对典型支撑梁进行结构参数化仿真。仿真结果表明:在温度环境作用下,直脚梁、蟹脚梁与折叠梁支撑结构的谐振频率都随温度增高而线性减小;梁. ; With the commercialization of micro devices, abnormal working condition becomes key factor that affects the acquisition of high precision and reliability of micro devices. Since the microresonator is the core component of these microstructures, research on its resonant characteristics in abnormal working condition becomes increasingly important. Therefore with micro resonator as the research objec. ; 学位:工程硕士 ; 院系专业:物理与机电工程学院_机械工程 ; 学号:19920111152780

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  • 一直以来,煤炭都是中国能源市场最重要的能源品种。从资源禀赋的构成以及成本的角度来看,未来相当长一段时期内,煤炭在中国一次能源消费结构中仍将占据主导地位。因此,煤炭价格问题已经成为关系到国计民生的深层次问题,研究分析中国的煤炭价格,探索建立符合中国煤炭市场发展要求的煤炭价格形成机制,不仅直接影响煤炭产业的结构和煤炭工业的可持续发展,而且还关系到国民经济能否又好又快地发展。 本文首先分析研究了中国的煤炭价格形成机制,然后总结比较了世界煤炭市场的几种定价方法,接着对美、俄、印三个主要产煤国的煤炭价格形成机制进行了系统地阐述,从中总结出一定的经验和启示。最后,从规制经济学的角度,探索了中国煤炭价格形. ; Coal has always been the most important energy variety in China. From the perspective of resource endowment and cost, coal will continue to be the most important energy in primary energy consumption structure of China far into the future. Therefore, the coal price has a profound impact on the development of national economy and the life of people. Research on China's coal price and coal price form. ; 学位:经济学硕士 ; 院系专业:经济学院中国能源经济研究中心_能源经济学 ; 学号:31320081152249

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  • 【中文文摘】从体形、室内布局、玻璃和 遮阳等几个方面,提出夏热冬冷地 区住宅的节能设计方法。 【英文文摘】This paper puts forward the design methods for residential buildings energy conservation in hot in summer and cold in winner zone, based on the shape、interior space planning、glass and shading. ; 东南大学科技资金(XJ000101)资助项目

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  • [中文文摘]以化学电源为着重点,介绍了2008年5月18-22日在美国亚利桑那州凤凰城举行的美国电化学会第213次会议的情况。本次会议有关化学电源的内容占主导地位,重点集中在高能量密度、高安全性的锂离子电池;还介绍了生物质燃料电池等新兴领域的发展状态,同时也注意到了室温燃料电池和氧化物燃料电池、超级电容量等的最新研究进展。[英文文摘]With emphasizing on battery,the development of electrochemical power sources in the 213th Electrochemical Society Meeting was introduced,which was held in Phoenix City,AZ,U.S.from May 18 to 22,2008.In this meeting,the chemical power sources session in which lithium batteries with the focus on high energy density and improving safety were still dominating part.The new area of biological fuel cell was introduced.The progress in room temperature and metal oxide fuel cells and supercapacitors was also released.

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  • 印尼蕴藏丰富的能源资源,能源产业获得巨大发展,是东南亚能源生产与消费大国。近些年中国与印尼在油气、煤炭、电力等传统能源领域的合作卓有成效,在新能源、可再生能源的合作也已经起步。中国和印尼在能源领域存在着诸多共同利益,能源合作是中印尼经贸合作新的增长点。两国政府应在鼓励能源发展合作方面制定相关的配套政策,对能源合作所需要的信息、人才、资金、管理、技术等方面建立起有效的技术创新服务体系,为促进双方合作提供政策法规和激励机制,包括法律法规、发展规划、财政支持政策、产业发展政策、税收优惠等,进一步加强在能源领域上的合作。 ; Indonesia has rich energy resources and is a major country of energy production and consumption.Its energy industry has achieved great development.In recent years, China has conducted very fruitful cooperation with Indonesia in the areas of oil and gas, coal, electric power and other traditional energy and has started to cooperate in new energy and renewable energy.China and Indonesia have many common interests in the energy area, and energy cooperation is a new point for growth in economic and trade cooperation between China and Indonesia.The two governments should formulate relevant supporting policies to encourage energy development and cooperation, establish an effective technological innovation and service system to provide information, personnel, capital, management, and technology as needed by energy cooperation, and provide policies, regulations and incentive mechanisms to promote cooperation between the two sides, including laws and regulations, development planning, fi nancial support, industrial development policy, and tax breaks, so as to further strengthen cooperation in the energy fi eld. ; 教育部人文社会科学重点研究基地重大项目“印度尼西亚经济崛起及其与中国战略伙伴关系研究”的阶段性成果;项目编号:13JJD810010; 福建省社会科学规划项目“福建省发展海洋经济打造蓝色产业带对策研究”的阶段性成果;项目编号:2013A027)

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  • 在戏剧治疗的发展历程中,角色扮演作为戏剧治疗的重要技术手段,可以说从一开始就受到了某些心理咨询师们的关注,而对戏剧治疗角色应用的探讨一直以来也成为这一领域的焦点话题,与此同时,戏剧治疗的角色理论部分则被相对忽视。本文立足于角色扮演的实操运用,试图对其理论架构进行深入的解读与探讨。 本文分为导言、正文、小结三个部分。导言部分简要概述本文的研究现状、研究目的、研究意义和研究方法。正文部分则分为三章: 第一章将从社会心理学、剧场理论和戏剧治疗等学科背景出发,分别对角色理论进行不同的观点解读,在分析三者异同的基础上,寻求其内在的紧密联系。从规范、途径和转化的立体交织结构中,揭开戏剧治疗中角色理论的. ; In the development of drama therapy, role playing as an important technical means of drama therapy, has attracted the attention of many psychological consultants. While the practical part of role theory has always been the focus of this field, its theory is relatively ignored. In this paper, based on the role playing in practical application, it tries to carry on the thorough theoretical interpret. ; 学位:艺术学硕士 ; 院系专业:人文学院_戏剧与影视学 ; 学号:10220121152243

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  • 应用密度泛函理论,在B3LYP/6-31G*水平上优化得到了线性簇合物BC2B(n=1~12,D∞h)的平衡几何构型,并n计算了它们的谐振动频率.在优化平衡几何构型下,通过TD-B3LYP/cc-pvDZ和TD-B3LYP/cc-pvTZ计算,分别得到了n=1~12和n=1~7的X1Σg→11Σ+u电子跃迁的垂直激发能和对应的振子强度.在B3LYP/6-311+G*水平上计算得到+了簇合物BC2B(n=1~12,D∞h)的电离能.基于计算结果,导出了BC2B体系X1Σg→11Σ+u电子跃迁能以及第一电离能+nn与体系大小n的解析表达式. ; Using density functional theory, the geometries and the vibrational frequencies of linear chain BC2 B (n=1~12, D∞h) have been investigated at the B3LYP/6-31G* level. Time-dependent density func- n tional theory (TD-DFT) has been used to calculate the vertical transition energies and oscillator strengths for X1Σg →11Σ+u transitions of BC2 B with the cc-pvTZ and cc-pvDZ basis sets. At the B3LYP/6-311+G* + n level, the single-point energies of the clusters have been calculated in order to determine the first ionization energies. On the basis of present calculations, the explicit expressions for the size dependence of the excita- tion energy, the first adiabatic ionization energies (AIE) and vertical ionization energies (VIE) in linear car- bon chains were suggested. ; 厦门大学固体表面物理化学国家重点实验室开放课题基金;; 国家自然科学基金;; 河南省自然科学基金(Nos. 20173042; 20233020; 20021002;0311011200)资助项目.

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  • 福建在发展中同样面临着能源、“三农”和环境的困扰,更因缺油少煤及矿产资源不丰和丘陵山地过多而倍感艰难。但在生物时代本省丰富的林业产品成了价值颇高的可再生资源,可提供制作生物柴油的原料和用于造气,其市场广阔。因而只要调整思路,扬长避短,就能战胜上述困扰,把海峡西岸经济区建设得更好。 ; Fujian has also encountered some troubles such as energy issurse,agriculture,countryside and farmer problem,and environment pollution during developmental process,these troubles have become stronger when there is not enough fossil fuel and too much hilly land.But in biological era,the abundant forestry products in Fujian show much more potential value,for their regeneration features.They can produce biodiesel and biogas.So,if we turn these renewable resources to advantage,then we will achieve the jump-over development in West-strait area. ; “生物柴油的固碱催化合成法”和“水基防锈金属切削液的研制”课题得到固体表面物理化学国家重点实验室的资助

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  • 利用线性扫描电沉积的方法在玻碳电极或多壁碳纳米管表面制备出铂纳米立方体,扫描电子显微镜(SEM)和透射电子显微镜(TEM)结果表明,铂立方体的尺度约为38 nM,由PT(111)择优取向的小粒子围成.运用电化学循环伏安和电位阶跃技术研究了所合成的2种催化剂和商用碳载铂对乙醇氧化的电催化活性,发现在2种铂纳米立方体上乙醇氧化的电催化活性和稳定性均高于商用碳载铂,其起峰电位较商业碳载铂降低168 MV.采用电化学原位红外光谱对比研究了铂纳米立方体和商用碳载铂对乙醇氧化的电催化过程,发现铂纳米立方体起始氧化电位提前,催化活性增强.乙醇在该催化剂上更易转化为乙酸,且表现出较强的CO吸附能力. ; Platinum nanocubes deposited on glassy carbon(Ptcube/GC) or multi-walled carbon nanotubes(MWCNTs)(Ptcube/MWCNTs) were prepared with electrochemical deposition using linear sweep voltammetry.SEM and TEM results show that the average particle size of Ptcube/GC is 38 nm,which is composed of small particles surrounded by the Pt(111) preferred orientation.Electrochemical investigations including cyclic voltammetry and current-time curves,show that these two kinds of Pt cubes exhibit a higher catalytic activity and better stability for the oxidation of ethanol than commercial Pt/C.It is worth to note that Pt nanocubes show an onset potential shifted negatively by 168 mV than commercial Pt/C sample.Electrochemical in-situ FTIR spectroscopy was also used to study the adsorption and oxidation behavior of ethanol oxidation in acidic media on Ptcube/MWCNTs and commercial Pt/C.The results show that negative shift of oxidation potential and increase of catalytic activity on Ptcube/MWCNTs are mainly due to direct oxidation of ethanol to acetic acid at low potentials.In addition,the nanocubes also exhibit stronger CO adsorption. ; 国家自然科学基金(批准号:20833005;20873116;60936003)资助

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606 Research products
  • Authors: Zhang Peng-jun; Dai Shi-xun; Cao Ying; Peng Bo; +3 Authors

    series of chalcohalide glasses based on the composition 0. 9 (Ge-25 Ga-5 S-70)-0. 1CsI doped with the different Tm3+/Dy3+ ions ratio were synthesized by melt-quenching technique. The absorption spectra, and mid-infrared fluorescence of different glass samples under 800 nm laser excitation were measured. The results prove that, Tm3+ is an efficient sensitizer, which can enhance the Dy3+ : 2.9 mu m fluorescence intensity significantly. A decrease in the intensity of 1. 8 mu m fluorescence and lifetimes of the Tm3+ : F-3(4) level occurred with increasihg the concentration of Dy3+ ions from 0 to 1 Wt% where Tm3+ concentration was fixed to 0. 5 Wt%. Also a wide spectral oveflap between Tm3+ : 1. 8 mu m emission and the absorption of Dy3+ : H-6(15/2)-> H-6(11/2) level.

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  • 随着微器件的商业化,非常态工作环境成了影响器件高精度与可靠性获得的重要因素。作为这些微结构的核心元件,微谐振器在非常态环境下的谐振特性研究变得越来越重要。本论文以微谐振器为研究对象,设计温度敏感与阻尼敏感两类谐振器结构,从理论推导、建模仿真与实验验证三方面研究微谐振器谐振频率的温度变化规律,以及系统阻尼与真空关系。主要研究内容和成果如下: 1)简述典型支撑梁固有频率的温度系数模型,梳理支撑梁温度敏感参数,分析温度影响支撑梁固有频率的规律性机制,并以此作为设计目标,对典型支撑梁进行结构参数化仿真。仿真结果表明:在温度环境作用下,直脚梁、蟹脚梁与折叠梁支撑结构的谐振频率都随温度增高而线性减小;梁. ; With the commercialization of micro devices, abnormal working condition becomes key factor that affects the acquisition of high precision and reliability of micro devices. Since the microresonator is the core component of these microstructures, research on its resonant characteristics in abnormal working condition becomes increasingly important. Therefore with micro resonator as the research objec. ; 学位:工程硕士 ; 院系专业:物理与机电工程学院_机械工程 ; 学号:19920111152780

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  • 一直以来,煤炭都是中国能源市场最重要的能源品种。从资源禀赋的构成以及成本的角度来看,未来相当长一段时期内,煤炭在中国一次能源消费结构中仍将占据主导地位。因此,煤炭价格问题已经成为关系到国计民生的深层次问题,研究分析中国的煤炭价格,探索建立符合中国煤炭市场发展要求的煤炭价格形成机制,不仅直接影响煤炭产业的结构和煤炭工业的可持续发展,而且还关系到国民经济能否又好又快地发展。 本文首先分析研究了中国的煤炭价格形成机制,然后总结比较了世界煤炭市场的几种定价方法,接着对美、俄、印三个主要产煤国的煤炭价格形成机制进行了系统地阐述,从中总结出一定的经验和启示。最后,从规制经济学的角度,探索了中国煤炭价格形. ; Coal has always been the most important energy variety in China. From the perspective of resource endowment and cost, coal will continue to be the most important energy in primary energy consumption structure of China far into the future. Therefore, the coal price has a profound impact on the development of national economy and the life of people. Research on China's coal price and coal price form. ; 学位:经济学硕士 ; 院系专业:经济学院中国能源经济研究中心_能源经济学 ; 学号:31320081152249

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  • 【中文文摘】从体形、室内布局、玻璃和 遮阳等几个方面,提出夏热冬冷地 区住宅的节能设计方法。 【英文文摘】This paper puts forward the design methods for residential buildings energy conservation in hot in summer and cold in winner zone, based on the shape、interior space planning、glass and shading. ; 东南大学科技资金(XJ000101)资助项目

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  • [中文文摘]以化学电源为着重点,介绍了2008年5月18-22日在美国亚利桑那州凤凰城举行的美国电化学会第213次会议的情况。本次会议有关化学电源的内容占主导地位,重点集中在高能量密度、高安全性的锂离子电池;还介绍了生物质燃料电池等新兴领域的发展状态,同时也注意到了室温燃料电池和氧化物燃料电池、超级电容量等的最新研究进展。[英文文摘]With emphasizing on battery,the development of electrochemical power sources in the 213th Electrochemical Society Meeting was introduced,which was held in Phoenix City,AZ,U.S.from May 18 to 22,2008.In this meeting,the chemical power sources session in which lithium batteries with the focus on high energy density and improving safety were still dominating part.The new area of biological fuel cell was introduced.The progress in room temperature and metal oxide fuel cells and supercapacitors was also released.

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  • 印尼蕴藏丰富的能源资源,能源产业获得巨大发展,是东南亚能源生产与消费大国。近些年中国与印尼在油气、煤炭、电力等传统能源领域的合作卓有成效,在新能源、可再生能源的合作也已经起步。中国和印尼在能源领域存在着诸多共同利益,能源合作是中印尼经贸合作新的增长点。两国政府应在鼓励能源发展合作方面制定相关的配套政策,对能源合作所需要的信息、人才、资金、管理、技术等方面建立起有效的技术创新服务体系,为促进双方合作提供政策法规和激励机制,包括法律法规、发展规划、财政支持政策、产业发展政策、税收优惠等,进一步加强在能源领域上的合作。 ; Indonesia has rich energy resources and is a major country of energy production and consumption.Its energy industry has achieved great development.In recent years, China has conducted very fruitful cooperation with Indonesia in the areas of oil and gas, coal, electric power and other traditional energy and has started to cooperate in new energy and renewable energy.China and Indonesia have many common interests in the energy area, and energy cooperation is a new point for growth in economic and trade cooperation between China and Indonesia.The two governments should formulate relevant supporting policies to encourage energy development and cooperation, establish an effective technological innovation and service system to provide information, personnel, capital, management, and technology as needed by energy cooperation, and provide policies, regulations and incentive mechanisms to promote cooperation between the two sides, including laws and regulations, development planning, fi nancial support, industrial development policy, and tax breaks, so as to further strengthen cooperation in the energy fi eld. ; 教育部人文社会科学重点研究基地重大项目“印度尼西亚经济崛起及其与中国战略伙伴关系研究”的阶段性成果;项目编号:13JJD810010; 福建省社会科学规划项目“福建省发展海洋经济打造蓝色产业带对策研究”的阶段性成果;项目编号:2013A027)

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  • 在戏剧治疗的发展历程中,角色扮演作为戏剧治疗的重要技术手段,可以说从一开始就受到了某些心理咨询师们的关注,而对戏剧治疗角色应用的探讨一直以来也成为这一领域的焦点话题,与此同时,戏剧治疗的角色理论部分则被相对忽视。本文立足于角色扮演的实操运用,试图对其理论架构进行深入的解读与探讨。 本文分为导言、正文、小结三个部分。导言部分简要概述本文的研究现状、研究目的、研究意义和研究方法。正文部分则分为三章: 第一章将从社会心理学、剧场理论和戏剧治疗等学科背景出发,分别对角色理论进行不同的观点解读,在分析三者异同的基础上,寻求其内在的紧密联系。从规范、途径和转化的立体交织结构中,揭开戏剧治疗中角色理论的. ; In the development of drama therapy, role playing as an important technical means of drama therapy, has attracted the attention of many psychological consultants. While the practical part of role theory has always been the focus of this field, its theory is relatively ignored. In this paper, based on the role playing in practical application, it tries to carry on the thorough theoretical interpret. ; 学位:艺术学硕士 ; 院系专业:人文学院_戏剧与影视学 ; 学号:10220121152243

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  • 应用密度泛函理论,在B3LYP/6-31G*水平上优化得到了线性簇合物BC2B(n=1~12,D∞h)的平衡几何构型,并n计算了它们的谐振动频率.在优化平衡几何构型下,通过TD-B3LYP/cc-pvDZ和TD-B3LYP/cc-pvTZ计算,分别得到了n=1~12和n=1~7的X1Σg→11Σ+u电子跃迁的垂直激发能和对应的振子强度.在B3LYP/6-311+G*水平上计算得到+了簇合物BC2B(n=1~12,D∞h)的电离能.基于计算结果,导出了BC2B体系X1Σg→11Σ+u电子跃迁能以及第一电离能+nn与体系大小n的解析表达式. ; Using density functional theory, the geometries and the vibrational frequencies of linear chain BC2 B (n=1~12, D∞h) have been investigated at the B3LYP/6-31G* level. Time-dependent density func- n tional theory (TD-DFT) has been used to calculate the vertical transition energies and oscillator strengths for X1Σg →11Σ+u transitions of BC2 B with the cc-pvTZ and cc-pvDZ basis sets. At the B3LYP/6-311+G* + n level, the single-point energies of the clusters have been calculated in order to determine the first ionization energies. On the basis of present calculations, the explicit expressions for the size dependence of the excita- tion energy, the first adiabatic ionization energies (AIE) and vertical ionization energies (VIE) in linear car- bon chains were suggested. ; 厦门大学固体表面物理化学国家重点实验室开放课题基金;; 国家自然科学基金;; 河南省自然科学基金(Nos. 20173042; 20233020; 20021002;0311011200)资助项目.

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  • 福建在发展中同样面临着能源、“三农”和环境的困扰,更因缺油少煤及矿产资源不丰和丘陵山地过多而倍感艰难。但在生物时代本省丰富的林业产品成了价值颇高的可再生资源,可提供制作生物柴油的原料和用于造气,其市场广阔。因而只要调整思路,扬长避短,就能战胜上述困扰,把海峡西岸经济区建设得更好。 ; Fujian has also encountered some troubles such as energy issurse,agriculture,countryside and farmer problem,and environment pollution during developmental process,these troubles have become stronger when there is not enough fossil fuel and too much hilly land.But in biological era,the abundant forestry products in Fujian show much more potential value,for their regeneration features.They can produce biodiesel and biogas.So,if we turn these renewable resources to advantage,then we will achieve the jump-over development in West-strait area. ; “生物柴油的固碱催化合成法”和“水基防锈金属切削液的研制”课题得到固体表面物理化学国家重点实验室的资助

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  • 利用线性扫描电沉积的方法在玻碳电极或多壁碳纳米管表面制备出铂纳米立方体,扫描电子显微镜(SEM)和透射电子显微镜(TEM)结果表明,铂立方体的尺度约为38 nM,由PT(111)择优取向的小粒子围成.运用电化学循环伏安和电位阶跃技术研究了所合成的2种催化剂和商用碳载铂对乙醇氧化的电催化活性,发现在2种铂纳米立方体上乙醇氧化的电催化活性和稳定性均高于商用碳载铂,其起峰电位较商业碳载铂降低168 MV.采用电化学原位红外光谱对比研究了铂纳米立方体和商用碳载铂对乙醇氧化的电催化过程,发现铂纳米立方体起始氧化电位提前,催化活性增强.乙醇在该催化剂上更易转化为乙酸,且表现出较强的CO吸附能力. ; Platinum nanocubes deposited on glassy carbon(Ptcube/GC) or multi-walled carbon nanotubes(MWCNTs)(Ptcube/MWCNTs) were prepared with electrochemical deposition using linear sweep voltammetry.SEM and TEM results show that the average particle size of Ptcube/GC is 38 nm,which is composed of small particles surrounded by the Pt(111) preferred orientation.Electrochemical investigations including cyclic voltammetry and current-time curves,show that these two kinds of Pt cubes exhibit a higher catalytic activity and better stability for the oxidation of ethanol than commercial Pt/C.It is worth to note that Pt nanocubes show an onset potential shifted negatively by 168 mV than commercial Pt/C sample.Electrochemical in-situ FTIR spectroscopy was also used to study the adsorption and oxidation behavior of ethanol oxidation in acidic media on Ptcube/MWCNTs and commercial Pt/C.The results show that negative shift of oxidation potential and increase of catalytic activity on Ptcube/MWCNTs are mainly due to direct oxidation of ethanol to acetic acid at low potentials.In addition,the nanocubes also exhibit stronger CO adsorption. ; 国家自然科学基金(批准号:20833005;20873116;60936003)资助

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