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Project: Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets - These data have been generated as part of the internationally-coordinated Coupled Model Intercomparison Project Phase 6 (CMIP6; see also GMD Special Issue: http://www.geosci-model-dev.net/special_issue590.html). The simulation data provides a basis for climate research designed to answer fundamental science questions and serves as resource for authors of the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR6). CMIP6 is a project coordinated by the Working Group on Coupled Modelling (WGCM) as part of the World Climate Research Programme (WCRP). Phase 6 builds on previous phases executed under the leadership of the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and relies on the Earth System Grid Federation (ESGF) and the Centre for Environmental Data Analysis (CEDA) along with numerous related activities for implementation. The original data is hosted and partially replicated on a federated collection of data nodes, and most of the data relied on by the IPCC is being archived for long-term preservation at the IPCC Data Distribution Centre (IPCC DDC) hosted by the German Climate Computing Center (DKRZ). The project includes simulations from about 120 global climate models and around 45 institutions and organizations worldwide. Summary: These data include the subset used by IPCC AR6 WGI authors of the datasets originally published in ESGF for 'CMIP6.ScenarioMIP.DWD.MPI-ESM1-2-HR' with the full Data Reference Syntax following the template 'mip_era.activity_id.institution_id.source_id.experiment_id.member_id.table_id.variable_id.grid_label.version'. The MPI-ESM1.2-HR climate model, released in 2017, includes the following components: aerosol: none, prescribed MACv2-SP, atmos: ECHAM6.3 (spectral T127; 384 x 192 longitude/latitude; 95 levels; top level 0.01 hPa), land: JSBACH3.20, landIce: none/prescribed, ocean: MPIOM1.63 (tripolar TP04, approximately 0.4deg; 802 x 404 longitude/latitude; 40 levels; top grid cell 0-12 m), ocnBgchem: HAMOCC6, seaIce: unnamed (thermodynamic (Semtner zero-layer) dynamic (Hibler 79) sea ice model). The model was run by the Deutscher Wetterdienst, Offenbach am Main 63067, Germany (DWD) in native nominal resolutions: aerosol: 100 km, atmos: 100 km, land: 100 km, landIce: none, ocean: 50 km, ocnBgchem: 50 km, seaIce: 50 km.

Project: Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets - These data have been generated as part of the internationally-coordinated Coupled Model Intercomparison Project Phase 6 (CMIP6; see also GMD Special Issue: http://www.geosci-model-dev.net/special_issue590.html). The simulation data provides a basis for climate research designed to answer fundamental science questions and serves as resource for authors of the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR6). CMIP6 is a project coordinated by the Working Group on Coupled Modelling (WGCM) as part of the World Climate Research Programme (WCRP). Phase 6 builds on previous phases executed under the leadership of the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and relies on the Earth System Grid Federation (ESGF) and the Centre for Environmental Data Analysis (CEDA) along with numerous related activities for implementation. The original data is hosted and partially replicated on a federated collection of data nodes, and most of the data relied on by the IPCC is being archived for long-term preservation at the IPCC Data Distribution Centre (IPCC DDC) hosted by the German Climate Computing Center (DKRZ). The project includes simulations from about 120 global climate models and around 45 institutions and organizations worldwide. Summary: These data include the subset used by IPCC AR6 WGI authors of the datasets originally published in ESGF for 'CMIP6.CMIP.HAMMOZ-Consortium.MPI-ESM-1-2-HAM.historical' with the full Data Reference Syntax following the template 'mip_era.activity_id.institution_id.source_id.experiment_id.member_id.table_id.variable_id.grid_label.version'. The MPI-ESM1.2-HAM climate model, released in 2017, includes the following components: aerosol: HAM2.3, atmos: ECHAM6.3 (spectral T63; 192 x 96 longitude/latitude; 47 levels; top level 0.01 hPa), atmosChem: sulfur chemistry (unnamed), land: JSBACH 3.20, ocean: MPIOM1.63 (bipolar GR1.5, approximately 1.5deg; 256 x 220 longitude/latitude; 40 levels; top grid cell 0-12 m), ocnBgchem: HAMOCC6, seaIce: unnamed (thermodynamic (Semtner zero-layer) dynamic (Hibler 79) sea ice model). The model was run by the ETH Zurich, Switzerland; Max Planck Institut fur Meteorologie, Germany; Forschungszentrum Julich, Germany; University of Oxford, UK; Finnish Meteorological Institute, Finland; Leibniz Institute for Tropospheric Research, Germany; Center for Climate Systems Modeling (C2SM) at ETH Zurich, Switzerland (HAMMOZ-Consortium) in native nominal resolutions: aerosol: 250 km, atmos: 250 km, atmosChem: 250 km, land: 250 km, ocean: 250 km, ocnBgchem: 250 km, seaIce: 250 km.

Microbial electrochemical technologies (METs) constitute the core of a number of emerging technologies with a high potential for treating urban wastewater due to a fascinating reaction mechanism—the electron transfer between bacteria and electrodes to transform metabolism into electrical current. In the current work, we focus on the model electroactive microorganism Geobacter sulfurreducens to explore both the design of new start-up procedures and electrochemical operations. Our chemostat-grown plug and play cells, were able to reduce the start-up period by 20-fold while enhancing chemical oxygen demand (COD) removal by more than 6-fold during this period. Moreover, a filter-press based bioreactor was successfully tested for both acetate-supplemented synthetic wastewater and real urban wastewater. This proof-of-concept pre-pilot treatment included a microbial electrolysis cell (MEC) followed in time by a microbial fuel cell (MFC) to finally generate electrical current of ca. 20 A·m−2 with a power of 10 W·m−2 while removing 42 g COD day−1·m−2. The effective removal of acetate suggests a potential use of this modular technology for treating acetogenic wastewater where Geobacter sulfurreducens outcompetes other organisms.

Abstract In an effort to minimise electricity consumption and greenhouse gases emissions, the heating, ventilation and air-conditioning sector has focused its attention on developing alternative solutions to electrically-driven vapour-compression cooling. Liquid desiccant air-conditioning systems represent an energy-efficient and more environmentally friendly alternative technology for dehumidification and cooling, particularly in those cases with high latent loads to maintain indoor air quality and comfort conditions. This technology is considered particularly efficient in hot and humid climates. As a matter of fact, the choice of the desiccant solution influences the overall performance of the system. The current paper reviews the working principle of liquid desiccant systems, focusing on the thermodynamic properties of the desiccant solutions and describes an evaluation of the reference thermodynamic properties of different desiccant solutions to identify which thermodynamic, physical, transport property influences the liquid desiccant process and to what extent. The comparison of these thermodynamic properties for the commonly used desiccants is conducted to estimate which fluid could perform most favourably in the system. The economic factors and the effect of different applications and climatic conditions on the system performance are also described. The paper is intended to be the first step in the evaluation of alternative desiccant fluids able to overcome the problems related to the use of the common desiccant solutions, such as crystallization and corrosion to metals. Ionic liquids seem a promising alternative working fluid in liquid desiccant air-conditioning systems and their characteristics and cost are discussed.

Project: Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets - These data have been generated as part of the internationally-coordinated Coupled Model Intercomparison Project Phase 6 (CMIP6; see also GMD Special Issue: http://www.geosci-model-dev.net/special_issue590.html). The simulation data provides a basis for climate research designed to answer fundamental science questions and serves as resource for authors of the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR6). CMIP6 is a project coordinated by the Working Group on Coupled Modelling (WGCM) as part of the World Climate Research Programme (WCRP). Phase 6 builds on previous phases executed under the leadership of the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and relies on the Earth System Grid Federation (ESGF) and the Centre for Environmental Data Analysis (CEDA) along with numerous related activities for implementation. The original data is hosted and partially replicated on a federated collection of data nodes, and most of the data relied on by the IPCC is being archived for long-term preservation at the IPCC Data Distribution Centre (IPCC DDC) hosted by the German Climate Computing Center (DKRZ). The project includes simulations from about 120 global climate models and around 45 institutions and organizations worldwide. Summary: These data include the subset used by IPCC AR6 WGI authors of the datasets originally published in ESGF for 'CMIP6.CMIP.MPI-M.MPI-ESM1-2-LR.historical' with the full Data Reference Syntax following the template 'mip_era.activity_id.institution_id.source_id.experiment_id.member_id.table_id.variable_id.grid_label.version'. The MPI-ESM1.2-LR climate model, released in 2017, includes the following components: aerosol: none, prescribed MACv2-SP, atmos: ECHAM6.3 (spectral T63; 192 x 96 longitude/latitude; 47 levels; top level 0.01 hPa), land: JSBACH3.20, landIce: none/prescribed, ocean: MPIOM1.63 (bipolar GR1.5, approximately 1.5deg; 256 x 220 longitude/latitude; 40 levels; top grid cell 0-12 m), ocnBgchem: HAMOCC6, seaIce: unnamed (thermodynamic (Semtner zero-layer) dynamic (Hibler 79) sea ice model). The model was run by the Max Planck Institute for Meteorology, Hamburg 20146, Germany (MPI-M) in native nominal resolutions: aerosol: 250 km, atmos: 250 km, land: 250 km, landIce: none, ocean: 250 km, ocnBgchem: 250 km, seaIce: 250 km.

Project: Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets - These data have been generated as part of the internationally-coordinated Coupled Model Intercomparison Project Phase 6 (CMIP6; see also GMD Special Issue: http://www.geosci-model-dev.net/special_issue590.html). The simulation data provides a basis for climate research designed to answer fundamental science questions and serves as resource for authors of the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR6). CMIP6 is a project coordinated by the Working Group on Coupled Modelling (WGCM) as part of the World Climate Research Programme (WCRP). Phase 6 builds on previous phases executed under the leadership of the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and relies on the Earth System Grid Federation (ESGF) and the Centre for Environmental Data Analysis (CEDA) along with numerous related activities for implementation. The original data is hosted and partially replicated on a federated collection of data nodes, and most of the data relied on by the IPCC is being archived for long-term preservation at the IPCC Data Distribution Centre (IPCC DDC) hosted by the German Climate Computing Center (DKRZ). The project includes simulations from about 120 global climate models and around 45 institutions and organizations worldwide. Summary: These data include the subset used by IPCC AR6 WGI authors of the datasets originally published in ESGF for 'CMIP6.ScenarioMIP.DWD.MPI-ESM1-2-HR.ssp585' with the full Data Reference Syntax following the template 'mip_era.activity_id.institution_id.source_id.experiment_id.member_id.table_id.variable_id.grid_label.version'. The MPI-ESM1.2-HR climate model, released in 2017, includes the following components: aerosol: none, prescribed MACv2-SP, atmos: ECHAM6.3 (spectral T127; 384 x 192 longitude/latitude; 95 levels; top level 0.01 hPa), land: JSBACH3.20, landIce: none/prescribed, ocean: MPIOM1.63 (tripolar TP04, approximately 0.4deg; 802 x 404 longitude/latitude; 40 levels; top grid cell 0-12 m), ocnBgchem: HAMOCC6, seaIce: unnamed (thermodynamic (Semtner zero-layer) dynamic (Hibler 79) sea ice model). The model was run by the Deutscher Wetterdienst, Offenbach am Main 63067, Germany (DWD) in native nominal resolutions: aerosol: 100 km, atmos: 100 km, land: 100 km, landIce: none, ocean: 50 km, ocnBgchem: 50 km, seaIce: 50 km.

Natural potentials for future cropland expansion The potential for the expansion of cropland is restricted by the availability of land resources and given local natural conditions. As a result, area that is highly suitable for agriculture according to the prevailing local biophysical conditions but is not under cultivation today has a high natural potential for expansion. Policy regulations can further restrict the availability of land for expansion by designating protected areas, although they may be suitable for agriculture. Conversely, by applying e.g. irrigation practices, land can be brought under cultivation, although it may naturally not be suitable. Here, we investigate the potentials for agricultural expansion for near future climate scenario conditions to identify the suitability of non-cropland areas for expansion according to their local natural conditions. We determine the available energy, water and nutrient supply for agricultural suitability from climate, soil and topography data, by using a fuzzy logic approach according to Zabel et al. (2014). It considers the 16 globally most important staple and energy crops. These are: barley, cassava, groundnut, maize, millet, oil palm, potato, rapeseed, rice, rye, sorghum, soy, sugarcane, sunflower, summer wheat, winter wheat. The parameterization of the membership functions that describe each of the crops’ specific natural requirements is taken from Sys et al. (1993). The considered natural conditions are: climate (temperature, precipitation, solar radiation), soil properties (texture, proportion of coarse fragments and gypsum, base saturation, pH content, organic carbon content, salinity, sodicity), and topography (elevation, slope). As a result of the fuzzy logic approach, values in a range between 0 and 1 describe the suitability of a crop for each of the prevailing natural conditions at a certain location. The smallest suitability value over all parameters finally determines the suitability of a crop. The daily climate data is provided by simulation results from the global climate model ECHAM5 (Jungclaus et al. 2006) for near future (2011-2040) SRES A1B climate scenario conditions. Soil data is taken from the Harmonized World Soil Database (HWSD) (FAO et al. 2012), and topography data is applied from the Shuttle Radar Topography Mission (SRTM) (Farr et al. 2007). In order to gather a general crop suitability, which does not refer to one specific crop, the most suitable crop with the highest suitability value is chosen at each pixel. In addition the natural biophysical conditions, we consider today’s irrigated areas according to (Siebert et al. 2013). We assume that irrigated areas globally remain constant until 2040, since adequate data on the development of irrigated areas do not exist, although it is likely that freshwater availability for irrigation could be limited in some regions, while in other regions surplus water supply could be used to expand irrigation practices (Elliott et al. 2014). However, it is difficult to project where irrigation practices will evolve, since it is driven by economic investment costs that are required to establish irrigation infrastructure. In principle, all agriculturally suitable land that is not used as cropland today has the natural potential to be converted into cropland. We assume that only urban and built-up areas are not available for conversion, although more than 80% of global urban areas are agriculturally suitable (Avellan et al. 2012). However, it seems unlikely that urban areas will be cleared at the large scale due to high investment costs, growing cities and growing demand for settlements. Concepts of urban and vertical farming usually are discussed under the aspects of cultivating fresh vegetables and salads for urban population. They are not designed to extensively grow staple crops such as wheat or maize for feeding the world in the near future. Urban farming would require one third of the total global urban area to meet only the global vegetable consumption of urban dwellers (Martellozzo et al. 2015). Thus, urban agriculture cannot substantially contribute to global agricultural production of staple crops. Protected areas or dense forested areas are not excluded from the calculation, in order not to lose any information in the further combination with the biodiversity patterns (see chapter 2.3). We use data on current cropland distribution by Ramankutty et al. (2008) and urban and built-up area according to the ESA-CCI land use/cover dataset (ESA 2014). From this data, we calculate the ‘natural expansion potential index’ (Iexp) that expresses the natural potential for an area to be converted into cropland as follows: Iexp = S * Aav The index is determined by the quality of agricultural suitability (S) (values between 0 and 1) multiplied with the amount of available area (Aav) for conversion (in percentage of pixel area). The available area includes all suitable area that is not cultivated today, and not classified as urban or artificial area. The index ranges between 0 and 100 and indicates where the conditions for cropland expansion are more or less favorable, when taking only natural conditions into account, disregarding socio-economic factors, policies and regulations that drive or inhibit cropland expansion. The index is a helpful indicator for identifying areas where cropland expansion could take place in the near future. Further information Detailled information are available in the following publication: Delzeit, R., F. Zabel, C. Meyer and T. Václavík (2017). Addressing future trade-offs between biodiversity and cropland expansion to improve food security. Regional Environmental Change 17(5): 1429-1441. DOI: 10.1007/s10113-016-0927-1 Contact Please contact: Dr. Florian Zabel, f.zabel@lmu.de, Department für Geographie, LMU München (www.geografie.uni-muenchen.de) This research was carried out within the framework of the GLUES (Global Assessment of Land Use Dynamics, Greenhouse Gas Emissions and Ecosystem Services) Project, which has been supported by the German Ministry of Education and Research (BMBF) program on sustainable land management (grant number: 01LL0901E).

Project: Convective and Orographically-induced Precipitation Study - Weather forecast models have not been successful in improving the Quantitative Precipitation Forecast during the last 16 years. One reason for this stagnation is the lack of comprehensive, high-quality data sets usable for model validation as well as for data assimilation, thus leading to improved initial fields in numerical models. Theoretical analyses have identified the requirements measured data have to meet in order to close the gaps in process understanding. In field campaigns, it has been shown that the newest generation of remote sensing systems has the potential to yield data sets of the required quality. It is therefore time to combine the most powerful remote sensing instruments with proven ground-based and airborne measurement techniques in an Intensive Observations Period (IOP). Its goal is to serve as a backbone for the Priority Program SPP 1167 by producing the demanded data sets of unachieved accuracy and resolution. This requires a sophisticated scientific preparation and a careful coordination between the efforts of the institutions involved. For the first time, the pre-convective environment, the formation of clouds and the onset and development of precipitation as well as its intensity will be observed in four dimensions simultaneously in a region of sufficient size. This shall be achieved by combining the IOP with international programs and by collaboration between leading scientists in Europe, US, and other countries. Thus, the IOP, which we call Convective and Orographically-induced Precipitation Study (COPS), is a unique opportunity for an international field campaign featuring the newest generation of measurement systems such as scanning radar and lidar and leading to outstanding advances in atmospheric sciences. Please be aware of the common COPS/GOP/D-PHASE data policy, which you please find at http://cops.wdc-climate.de/ Summary: The energy balance stations run by University of Bayreuth continuously measured radiation and soil parameters over different land types with a sampling frequency of 1 Hz averaged to 1 min values within the data logger. After a check for plausibility the 1 min values have been averaged to 30 min intervals, which are provided in this data set. The instrumentation was different on each location. The following was measured depending on the station: - soil heat flux - soil temperature - volumetric soil water content - longwave radiation components - shortwave radiation components - tipping bucket rain gauge measurements The ground heat flux including the heat storage in the upper soil layer was determined from the measured soil heat flux, soil temperatures and volumetric soil water contents according to the 'simple measurement' (SM) method according to Liebethal and Foken (2007).

1. Aphids are abundant in natural and managed vegetation, supporting a diverse community of organisms and causing damage to agricultural crops. Due to a changing climate, periods of drought are anticipated to increase, and the potential consequences of this for aphid-plant interactions are unclear. 2. Using a meta-analysis and synthesis approach, we aimed to advance understanding of how increased drought incidence will affect this ecologically and economically important insect group, and to characterise any potential underlying mechanisms. We used qualitative and quantitative synthesis techniques to determine whether drought stress has a negative, positive, or null effect on aphid fitness and examined these effects in relation to 1) aphid biology, 2) geographical region, 3) host plant biology. 3. Across all studies, aphid fitness is typically reduced under drought. Subgroup analysis detected no difference in relation to aphid biology, geographical region, or the aphid-plant combination, indicating the negative effect of drought on aphids is potentially universal. Furthermore, drought stress had a negative impact on plant vigour and increased plant concentrations of defensive chemicals, suggesting the observed response of aphids is associated with reduced plant vigour and increased chemical defence in drought-stressed plants. 4. We propose a conceptual model to predict drought effects on aphid fitness in relation to plant vigour and defence to stimulate further research. Please check the ReadMe for an explanation of the values included in the dataset. Please note that n/a values are included in the Global_Dataset tab for plant meta-analysis data (_Plant_Vigour, _Plant_Defence, and _Plant_Nutrition), these indicate studies that did not report these parameters. Data was collected and curated using standard systematic literature synthesis approaches. The effect size (Hedges' g) reported in the dataset was calculated from extracted means and standard deviations.

Anthropogenic greenhouse gases contribute to global warming. Among those gases, perfluorocarbons (PFCs) are thousands to tens of thousands times more harmful to the environment than comparable amounts of carbon dioxide. Till date, materials that selectively adsorb perfluorocarbons in favor to other less harmful gases have not been reported. Here a series of porous organic cage compounds with alkyl-, fluoroalkyl, and partially fluorinated alkyl groups are presented. Their isomorphic crystalline states allowed us to study the property-relationship of the degree of fluorination of the alkyl chains on gas sorption properties for PFCs and their selective uptakes in comparison to other, non-fluorinated gases. By this approach, one compound was identified, having superior selectivities of PFCs vs N2 or CO2 under ambient conditions.