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A full understanding of the elementary processes taking place in dye-sensitised solar cells requires an accurate description of the electronic structure of the dyes, the semiconductor surface, the electrolyte and their interactions. This review describes how electronic structure calculations have contributed to the field since its first steps and what methodologies have been adopted to study the charge transfer processes at the interface. Not all properties are equally predictable with electronic structure methods, and this work highlights the main success areas (e.g. the rationalization of the optical properties of the dyes), the recent developments (e.g. the improved description of the dye–semiconductor interaction) and the key challenges for the future (e.g. the calculation of charge recombination rate).

In the present paper design, realization and testing of a novel small scale adsorption refrigerator prototype based on activated carbon/ethanol working pair is described. Firstly, experimental activity has been carried out for identification of the best performing activated carbon available on the market, through the evaluation of the achievable thermodynamic performance both under air conditioning and refrigeration conditions. Once identified the best performing activated carbon, the design of the adsorber was developed by experimental dynamic performance analysis, carried out by means of the Gravimetric-Large Temperature Jump (G-LTJ) apparatus available at CNR ITAE lab. Finally, the whole 0.5 kW refrigerator prototype was designed and built. First experimental results both under reference air conditioning and refrigeration cycles have been reported, to check the achievable performance. High Specific Cooling Powers (SCPs), 95 W/kg and 50 W/kg, for air conditioning and refrigeration respectively, were obtained, while the COP ranged between 0.09 and 0.11, thus showing an improvement of the current state of the art.

This paper illustrates a formulation of a continuous state space model in dq frame of the Thyristor Controlled Reactor (TCR), which can be used for stability studies by eigenvalue analysis. Differently from the previous approaches, this model is just addressed to reproduce the operation of the non-linear part of the TCR system, without considering shunted capacitor or control system, thus obtaining a characterization of the TCR independent from the application. A typical problem of the continuous models in dq frame of the TCR system is the presence of an un-damped homogenous current component in the solution, which is inconsistent with the real operation; the proposed model solves this problem improving the accuracy. The model performance has been also evaluated in the frequency domain comparing the obtained results with a numerical simulation of the TCR implemented by PSIM program.

The correlations between skeletal parameters (bulk density, micro-density and porosity), coral age and sea surface temperature were assessed along a latitudinal gradient in the zooxanthellate coral Balanophyllia europaea and in the azooxanthellate coral Leptopsammia pruvoti. In both coral species, the variation of bulk density was more influenced by the variation of porosity than of micro-density. With increasing polyp age, B. europaea formed denser and less porous skeletons while L. pruvoti showed the opposite trend, becoming less dense and more porous. B. europaea skeletons were generally less porous (more dense) than those of L. pruvoti, probably as a consequence of the different habitats colonized by the two species. Increasing temperature had a negative impact on the zooxanthellate species, leading to an increase of porosity. In contrast, micro-density increased with temperature in the azooxanthellate species. It is hypothesized that the increase in porosity with increasing temperatures observed in B. europaea could depend on an attenuation of calcification due to an inhibition of the photosynthetic process at elevated temperatures, while the azooxanthellate species appears more resistant to variations of temperature, highlighting possible differences in the sensitivity/tolerance of these two coral species to temperature changes in face of global climate change.

We report the properties of a shape-persistent tetra-terpyridine ligand whose coordination to transition metal ions guides its three-dimensional self-assembly in two steps: at first, nanoscale objects form, which with time, self-assemble into micrometer structures. This work highlights the potential for control of the molecular self-assembly of molecules on the nanoscale, and the successive self-assembly of the formed supramolecular nanosystems to yield mesoscopic objects.

A numerical study of heat transfer to supercritical water in vertical tubes is carried out using the ANSYS-CFX code and employing the k-omega SST turbulence model. The numerical results on wall tem ...

Latent thermal energy storage systems represent a promising alternative to traditional sensible storages, but their exploitation requires a careful design of the system. The present paper reports a mathematical model for the simulation of thermal energy storage systems with phase change materials (PCMs). The model is suitable for the description of a latent heat storage using a fin-and-tube heat exchanger. Accuracy and computational effort are both taken into consideration, by coupling a 1D model for the tubes of the heat exchanger and a reduced 3D model for the material and fin domains. The developed model has been validated for two systems, realised at ITAE and ISE, differing for the PCM employed and the constructive characteristics of the heat exchanger. Results show that the model has a good accuracy and could predict the behaviour of the storages within 40 W error in case of powers and 1 K in case of heat transfer fluid temperatures. When a stable PCM was used, the average deviation between the PCM temperature in experiments and simulation was lower than 0.6 K.

The Indian Ocean Experiment (INDOEX) was an international, multiplatform field campaign to measure long-range transport of air pollution from South and Southeast Asia toward the Indian Ocean during the dry monsoon season in January to March 1999. Surprisingly high pollution levels were observed over the entire northern Indian Ocean toward the Intertropical Convergence Zone at about 6°S. We show that agricultural burning and especially biofuel use enhance carbon monoxide concentrations. Fossil fuel combustion and biomass burning cause a high aerosol loading. The growing pollution in this region gives rise to extensive air quality degradation with local, regional, and global implications, including a reduction of the oxidizing power of the atmosphere.