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Chemical looping combustion allows a simple separation of CO2 during the combustion of fossil fuels, thanks to the use of regenerable oxygen carriers. In this work, novel materials containing manganese and iron/manganese oxides have been developed via geopolymerization, and characterized in thermogravimetric apparatus and fixed bed reactor. The materials demonstrated suitable characteristics for chemical looping combustion (CLC). The tests conducted in the temperature range 800-900 °C revealed the good performance of the developed oxygen carriers, which also exhibited the ability to release O2 in inert conditions. Efficiencies in CO conversion up to 99% were achieved, as well as some synergies between Fe and Mn oxides gave a beneficial effect toward the oxygen yield. X-ray diffraction analyses of the samples confirmed the effective reduction/oxidation behavior of the materials, as well as the morphological characterization did not reveal dramatic changes of the internal microstructure up to 900 °C

Capítulos en libros The importance of the natural gas sector in the electric power industry has increased substantially over the last decades, reaching 21% generation capacity in Europe in 2016. Generation companies that own gas fired units (GFUs), such us combined cycle gas turbines, have to take into account not only the fuel and the operation and maintenance costs, but also the costs related to the third-party access (TPA) tariffs to the gas network as any other gas consumer. This paper highlights the importance of modeling these TPA tariffs in a proper manner as they represent a significant share of the total operation cost of GFU. In addition, the fact that TPA final costs depend on the daily gas consumption for the whole month, makes traditional short-term unit-commitment (UC) models unable to capture the impact of the new complicating constraints. This paper presents the mathematical formulation of a UC model that models the TPA tariffs to the gas network in a more realistic manner where a joint assessment is formulated for all the units that withdraw gas from the same node of the gas network. The paper includes an example case that illustrates the impact on the optimal hourly scheduling of such detailed modeling, and it compares the results with the standard formulation based on individual cost functions of each thermal unit. info:eu-repo/semantics/publishedVersion

The most widely used process for hydrogen production is steam methane reforming. It can be carried out using a membrane reactor in which simultaneous hydrogen production and purification occur. Mathematical modeling of these reactors plays a key role in the selection of the design and operating parameters that yield high performance for the reactor. This review study discusses, synthesizes, and compares different mathematical modeling studies on the packed bed membrane reactors for hydrogen production from methane found in the literature. Different approaches used in these modeling studies for the hydrogen permeation steps, reaction kinetic expressions, phases involved (pseudo-homogeneous and heterogeneous), and spatial dimensions (one, two, and three dimensional) are given.

The reversible dissociation/carbonation of metal carbonates, performed in fluidized bed reactors, is one of the most promising technological solution for thermochemical energy storage (TCES) in concentrating solar power plants (CSP). In this framework, the SrCO3/SrO system is receiving increasing interest due to its high energy density (4 GJ/m3) and working temperatures (up to 1200 ?C). As the more investigated CaCO3/CaO couple, also SrO undergoes a dramatic drop of reactivity over multiple carbonation/calcina- tion cycles due to sintering. Even though the potentiality of this system has already been proved by thermo-gravimetric analyses, its actual reaction performances in a fluidized bed are strongly dependent on the gas-solid contact efficiency and heat/mass transfer between the gaseous and solid phase. In this work, the cyclic carbonation/calcination of the SrO/SrCO3 system for TCES-CSP has been investigated by thermo-gravimetric analysis and, for the first time, in a lab-scale fluidized bed rig, thus providing useful applicative insights. A new Al2O3-stabilized composite has been synthesized, i.e. Al2O3 has been added to SrO/SrCO3 system as both sintering inhibitor and flow conditioner. In particular, composite materials with different Al2O3/SrO composition have been synthesized to investigate the ef- fect of the inhibitor amount on both the fluidizability and energy storage performances.

Lysophosphatidic acid species (LPA) are lipid bioactive signaling molecules that have been recently implicated in the modulation of emotional and motivational behaviors. The present study investigates the consequences of either genetic deletion or pharmacological blockade of lysophosphatidic acid receptor-1 (LPA1) in alcohol consumption.The experiments were performed in alcohol-drinking animals by using LPA1-null mice and administering the LPA1 receptor antagonist Ki16425 in both mice and rats.In the two-bottle free choice paradigm, the LPA1-null mice preferred the alcohol more than their wild-type counterparts. Whereas the male LPA1-null mice displayed this higher preference at all doses tested, the female LPA1-null mice only consumed more alcohol at 6% concentration. The male LPA1-null mice were then further characterized, showing a notably increased ethanol drinking after a deprivation period and a reduced sleep time after acute ethanol administration. In addition, LPA1-null mice were more anxious than the wild-type mice in the elevated plus maze test. For the pharmacological experiments, the acute administration of the antagonist Ki16425 consistently increased ethanol consumption in both wild-type mice and rats; while it did not modulate alcohol drinking in the LPA1-null mice and lacked intrinsic rewarding properties and locomotor effects in a conditioned place preference paradigm. In addition, LPA1-null mice exhibited a marked reduction on the expression of glutamate-transmission-related genes in the prefrontal cortex similar to those described in alcohol-exposed rodents.Results suggest a relevant role for the LPA/LPA1 signaling system in alcoholism. In addition, the LPA1-null mice emerge as a new model for genetic vulnerability to excessive alcohol drinking. The pharmacological manipulation of LPA1 receptor arises as a new target for the study and treatment of alcoholism.

Intention of this work is to investigate the opportunity and feasibility of energy efficient networking in Home and Building automation protocols. Wired HBAS have traditionally devoted a relatively little attention to this point, especially if compared to wireless networks. This paper will try to address the issue by evaluating the introduction of power state switching in a real scenario and proposing the concept of functional and spatial adjacency among packets.

Il volume contiene gli abstract dei lavori accettati per i contributi orali e i poster presentati a HYPOTHESIS XII

Castor (Ricinus communis L.) is an oilseed species, which in southern Italy is cultivated as annual during the spring-summer period under irrigation, but in most temperate areas such as those of eastern coast of Sicily, it could be grown as semiperennial with no irrigation, by the adoption of autumnal sowings. A field experiment was conducted in southeastern Sicily with the aim of assessing plant surviving, seed yield and oil quality of four castor genotypes originating from different geographical areas (two Sicilian, one Tunisian and one Brazilian). The favorable climatic conditions allowed the plant to survive during the fall-winter period. Seed yield reached 3.45 t ha-1 on average of the two years and seed oil content ranged from 45% (Tunisian cultivar) to 48% ('Local RG 2' Sicilian genotype). Oil yield reflected the variation in seed yield. Genetic diversity for fatty acid composition and saponification number, iodine value and cetane number was evidenced. When ricinoleic acid is not taken into account, the oil of all genotypes satisfied the E.U. standards for biodiesel. The ricinoleic acid was the lowest (79%) in the Sicilian 'Local RG 2' and the highest (89%) in the Tunisian one, revealing a greater suitability of oil of the first genotype for biodiesel. In turn, the oil of Tunisian genotype could be exploited in other bio-based industrial sectors. The study also demonstrated that in the southeastern coast of Sicily autumnal sowings might be advantageous for castor grown as semi-perennial crop, mainly since they allow saving irrigation water.