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AbstractCurrently, Sb2Se3 thin films receive considerable research interest as a solar cell absorber material. When completed into a device stack, the major bottleneck for further device improvement is the open‐circuit voltage, which is the focus of the work presented here. Polycrystalline thin‐film Sb2Se3 absorbers and solar cells are prepared in substrate configuration and the dominant recombination path is studied using photoluminescence spectroscopy and temperature‐dependent current–voltage characteristics. It is found that a post‐deposition annealing after the CdS buffer layer deposition can effectively remove interface recombination since the activation energy of the dominant recombination path becomes equal to the bandgap of the Sb2Se3 absorber. The increased activation energy is accompanied by an increased photoluminescence yield, that is, reduced non‐radiative recombination. Finished Sb2Se3 solar cell devices reach open‐circuit voltages as high as 485 mV. Contrarily, the short‐circuit current density of these devices is limiting the efficiency after the post‐deposition annealing. It is shown that atomic layer‐deposited intermediate buffer layers such as TiO2 or Sb2S3 can pave the way for overcoming this limitation.

Abstract This research, entitled “Eco-development in the light of the euro mediterranean partnership: application to the coastal territories of Algeria and Morocco” wants to focus on the economic and policy causes which conduct to move to the alternative of eco-development as a new growth policy for these southern countries, to preserve their natural resources and enhance a sustainable way for growth. Both Algeria and Morocco, despite their human, material and natural resources, have failed during the last years to attain significant results in their fight against underdevelopment and poverty. More than that, development policies applied by each of these countries are based on, in a major part, the exploitation of their coastal territories and natural resources, which are both limited. The growth level yearly attained during the last decade, have not been more than 3% to 3.5% for each of them, less than estimated growth level of 7%, considered by many researchers as necessary to stabilize poverty and satisfy job demands. The intensive exploitation of natural resources added to the growing pressures on coastal territories has conduct to the rise of environmental damages, which enhance the costs of growth. We can observe that claimed objectives to help these South Mediterranean countries to push growth level, fixed previously by the partnership agreements with E.U., are not in their way to be realized at the level where it have been announced. How can be thinked a global economic model, to enhance growth, preserve environment and coastal territories, in a renewed and more equitable partnership agreement with E.U.? Is it possible to clear such model, which tries to embrace all aspects of this problematic, which is not only economic, but also social, environmental and including also spatial planning? To analyze these aspects, common to the cited growth policy experiences, this work have been conducted simultaneously, in spite of different levels of intensity in research works, at three cities (Annaba, Algiers and ...

We introduce a novel simulation tool capable of calculating the energy yield of a PV system based on its fundamental material properties and using self-consistent models. Thus, our simulation model can operate without measurements of a PV device. It combines wave and ray optics and a dedicated semiconductor simulation to model the optoelectronic PV device properties resulting in the IV-curve. The system surroundings are described via spectrally resolved ray tracing resulting in a cell resolved irradiance distribution, and via the fluid dynamics-based thermal model, in the individual cell temperatures. A lumped-element model is used to calculate the IV-curves of each solar cell for every hour of the year. These are combined factoring in the interconnection to obtain the PV module IV-curves, which connect to the inverter for calculating the AC energy yield. In our case study, we compare two types of 2 terminal perovskite/silicon tandem modules with STC PV module efficiencies of 27.7% and 28.6% with a reference c-Si module with STC PV module efficiency of 20.9%. In four different climates, we show that tandem PV modules operate at 1–1.9 °C lower yearly irradiance weighted average temperatures compared to c-Si. We find that the effect of current mismatch is significantly overestimated in pure optical studies, as they do not account for fill factor gains. The specific yields in kWh/kWp of the tandem PV systems are between −2.7% and +0.4% compared to the reference c-Si system in all four simulated climates. Thus, we find that the lab performance of the simulated tandem PV system translates from the laboratory to outdoors comparable to c-Si systems. Photovoltaic Materials and Devices Electrical Sustainable Energy Energie and Industrie

The electrical grid is changing from a centralized system with predictable and controllable power generation to a system integrating large numbers of distributed energy resources including weather-dependent renewables. As a consequence, the future retail energy market for electrical energy will have many more participants and see more volatile prices than today, creating the need for new communication and trading infrastructures facilitating. In this paper, we briefly review PowerMatcher as a possible approach for such an infrastructure, and analytically evaluate its communication characteristics. PowerMatcher is a multiagent based smart grid communication framework developed by TNO which enables market integration of distributed energy resources and automatic demand supply matching. While the trading side of the framework is well understood, there is no study that considers the communication side. Our results show that PowerMatcher enables scalable retail energy transactions with millions of participants requiring only moderate resources on the communication's side.

Materials and design 254, 114021 (2025). doi:10.1016/j.matdes.2025.114021 Published by Elsevier Science, Amsterdam [u.a.]

Red blood cell folate is measured for folate deficiency diagnosis, because it reflects the long-term folate level in tissues, whereas serum folate only represents the dietary intake. Direct homogeneous assay from whole blood would be ideal but conventional fluorescence techniques in blood suffer from high background and strong absorption of light at ultraviolet and visible wavelengths. In this study, a new photon upconversion-based homogeneous assay for whole blood folate is introduced based on resonance energy transfer from upconverting nanophosphor donor coated with folate binding protein to a near-infrared fluorescent acceptor dye conjugated to folate analogue. The sensitized acceptor emission is measured at 740 nm upon 980 nm excitation. Thus, optically transparent wavelengths are utilized for both donor excitation and sensitized acceptor emission to minimize the sample absorption, and anti-Stokes detection completely eliminates the Stokes-shifted autofluorescence. The IC50 value of the assay was 6.0 nM and the limit of detection (LOD) was 1 nM. The measurable concentration range was 2 orders of magnitude between 1.0-100 nM, corresponding to 40-4000 nM folate in the whole blood sample. Recoveries of added folic acid were 112%-114%. A good correlation was found when compared to a competitive heterogeneous assay based on the DELFIA-technology. The introduced assay provides a simple and fast method for whole blood folate measurement.

AbstractThe susceptibility of porphyrin derivatives to light‐harvesting and charge‐transport operations have enabled these materials to be employed in solar cell applications. The potential of porphyrin derivatives as hole‐transporting materials (HTMs) for perovskite solar cells (PSCs) has recently been demonstrated, but knowledge of the relationships between the porphyrin structure and device performance remains insufficient. In this work, a series of novel zinc porphyrin (PZn) derivatives has been developed and employed as HTMs for low‐temperature processed PSCs. Key to the design strategy is the incorporation of an electron‐deficient pyridine moiety to down‐shift the HOMO levels of porphyrin HTMs. The porphyrin HTMs incorporating diphenyl‐2‐pyridylamine (DPPA) have HOMO levels that are in good agreement with the perovskite active layers, thus facilitating hole transfers from the perovskite to the HTMs. The DPPA‐containing zinc porphyrin‐based PSCs gave the best performance, with efficiency levels comparable to those of PSCs using spiro‐OMeTAD, a current state‐of‐the‐art HTM. In particular, PZn–DPPA‐based PSCs show superior air stability, in both doped and undoped forms, to spiro‐OMeTAD based devices.

The working pair zeolite-water has very good characteristics for the heat pump application. It is non-poisonous, non-flammable and low-corrosive so that the use of a zeolite-water heat pump in the large field of domestic heating is very promising.

This paper explores the ability of European refineries to pass-through costs associated with the introduction of the EU Emissions Trading Scheme (EU ETS). We estimated a sequence of vector error correction models (VECM) within a multi-national setting which covers 14 EU member states. Using weekly data at the country level, this paper finds a significant influence of prices for European Union Allowances (EUAs) on unleaded petrol retail prices during the trial phase of the EU ETS from 2005 to 2007. Petrol prices are found to be elastic with respect to crude oil prices and exchange rates but rather inelastic with respect to carbon costs. The long-run elasticity of petrol prices with respect to the EUA prices typically ranges between 0.01% and 0.09%. Furthermore, by computing the variance decomposition our analysis shows that a significant fraction of petrol price changes in Austria, Germany, France and Spain can be explained by changes in allowances prices (between 10% and 20%).