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AbstractTransition to a bio‐based economy will create new demand for biomass, e.g. the increasing use of bioenergy, but the impacts on existing markets are unclear. Furthermore, there is a growing public concern on the sustainability of biomass. This study proposes a methodological framework for mapping national biomass flows based on domestic production‐consumption and cross‐border trade, and respective share of sustainably‐certified biomass. A case study was performed on the Netherlands for 2010‐2011, focusing on three categories: (i) woody biomass, (ii) oils and fats, and (iii) carbohydrates. Between 2010‐2011 few major shifts were found, besides the increasing biofuel production. The share of sustainably‐certified feedstock is growing in many categories. Woody biomass used for energy amounted to 3.45 MT, including 1.3 MT imported wood pellets ( >85% certified). About 0.6 MT of oils and fats and 1.2 MT (estimation) of carbohydrates were used for biofuel production. It is assumed that only certified materials were used for biofuel production. For non‐energy purpose, more than 50% of woody biomass used was either certified or derived from recycled streams. Certified oils has entered the Dutch food sector since 2011, accounted for 7% of total vegetable oils consumption. It is expected that carbohydrates will also be certified in the near future. Methodological challenges encountered are: inconsistency in data definitions, lack of coherent cross‐sectorial reporting systems, low reliability of bilateral trade statistics, lack of transparency in biomass supply chains, and disparity in sustainability requirements. The methodology may be expanded for future projection in different scenarios. © 2013 Society of Chemical Industry and John Wiley & Sons, Ltd

Extreme summer droughts are expected to occur more often in the future in NW Europe due to climate change. These droughts might accelerate the rate of peat oxidation in drained peat areas, with impacts on soil subsidence, GHG emission and water quality. This study aimed at providing more insight in the oxidation of deep peat layers that had not previously been exposed to air, the so-called secondary decomposition. We incubated two types of peat (eutrophic and oligotrophic), sampled from permanently anoxic peat layers from nature reserves and agricultural peat meadows. Peat samples were incubated for thirteen weeks under anoxic conditions, but were exposed to air for one to eight weeks. The production of CO2 and CH4 was quantified as a proxy for decomposition; concentrations of soluble nutrients and phenolic compounds were also measured. The results showed that oxygenation led to a steep increase in the rate of decomposition, indicated by higher carbon loss rates during and after oxygenation compared to non-oxygenated samples. Carbon loss rates increased more for eutrophic peat (agricultural area: 352%, nature reserve: 182%) than for oligotrophic peat (83% and 159% respectively). Most peat samples investigated showed higher post-oxygenation CO2 and/or CH4 production compared to the anoxic pre-oxygenation period. This indicates that oxygenation stimulates decomposition, even after anoxic conditions have returned. Contrary to the enzymic latch theory, no effects of oxygenation on the concentrations of soluble or condensed phenolic compounds were detected. Soluble nutrient concentrations did not change due to oxygenation either. Noteworthy is the occurrence of pyrite mineralization and associated acidification in eutrophic peat. Thus, low summer water levels, for example due to climate change, should be avoided in order to limit exceptionally high decomposition rates and associated problems such as increasing subsidence rates, greenhouse gas emission, sulfate release and acidification.

In industrialized countries, large amounts of mineral wastes are produced. They are re-used in various ways, particularly in road and earth constructions, substituting primary resources such as gravel. However, they may also contain pollutants, such as heavy metals, which may be leached to the groundwater. The toxic impacts of these emissions are so far often neglected within Life Cycle Assessments (LCA) of products or waste treatment services and thus, potentially large environmental impacts are currently missed. This study aims at closing this gap by assessing the ecotoxic impacts of heavy metal leaching from industrial mineral wastes in road and earth constructions. The flows of metals such as Sb, As, Pb, Cd, Cr, Cu, Mo, Ni, V and Zn originating from three typical constructions to the environment are quantified, their fate in the environment is assessed and potential ecotoxic effects evaluated. For our reference country, Germany, the industrial wastes that are applied as Granular Secondary Construction Material (GSCM) carry more than 45,000 t of diverse heavy metals per year. Depending on the material quality and construction type applied, up to 150 t of heavy metals may leach to the environment within the first 100 years after construction. Heavy metal retardation in subsoil can potentially reduce the fate to groundwater by up to 100%. One major challenge of integrating leaching from constructions into macro-scale LCA frameworks is the high variability in micro-scale technical and geographical factors, such as material qualities, construction types and soil types. In our work, we consider a broad range of parameter values in the modeling of leaching and fate. This allows distinguishing between the impacts of various road constructions, as well as sites with different soil properties. The findings of this study promote the quantitative consideration of environmental impacts of long-term leaching in Life Cycle Assessment, complementing site-specific risk assessment, for the design of waste management strategies, particularly in the construction sector.

Abstract As main contributors to greenhouse gas emissions, power and transportation are crucial sectors for energy system decarbonization. Their interaction is expected to increase significantly: plug-in electric vehicles add a new electric load, increasing grid demand and potentially requiring substantial grid upgrade; hydrogen production for fuel cell electric vehicles or for clean fuels synthesis could exploit the projected massive power overgeneration by intermittent and seasonally-dependent renewable sources via Power-to-Hydrogen. This work investigates the infrastructural needs involved with a broad diffusion of clean mobility, adopting a sector integration perspective at the national scale. The analysis combines a multi-node energy system balance simulation and a techno-economic assessment of the infrastructure to deliver energy vectors for mobility. The article explores the long-term case of Italy, considering a massive increase of renewable power generation capacity and investigating different mobility scenarios, where low-emission vehicles account for 50% of the stock. First, the model solves the energy balances, integrating the consumption related to mobility energy vectors and taking into account power grid constraints. Then, an optimal infrastructure is identified, composed of both a hydrogen delivery network and a widespread installation of charging points. Results show that the infrastructural requirements bring about investment costs in the range of 43–63 G€. Lower specific costs are associated with the exclusive presence of FCEVs, whereas the full reliance on BEVs leads to the most significant costs. Scenarios that combine FCEVs and BEVs lie in between, suggesting that the overall power + mobility system benefits from the presence of both drivetrain options.

AbstractThis study compared the economic and environmental impacts of torrefaction on bioenergy supply chains against conventional pellets for scenarios where biomass is produced in Mozambique, and undergoes pre‐processing before shipment to Rotterdam for conversion to power and Fischer‐Tropsch (FT) fuels. We also compared the impacts of using different land quality (productive and marginal) for feedstock production, feedstocks (eucalyptus and switchgrass), final conversion technologies (XtY and CXtY) and markets (the Netherlands and Mozambique). At current conditions, the torrefied pellets (TOPs) are delivered in Rotterdam at higher cost (7.3–7.5 $/GJ) than pellets (5.1–5.3 $/GJ). In the long term, TOPs costs could decline (4.7–5.8 $/GJ) and converge with pellets. TOPs supply chains also incur 20% lower greenhouse gas (GHG) emissions than pellets. Due to improved logistics and lower conversion investment, fuel production costs from TOPs are lower (12.8–16.9 $/GJFT) than from pellets (12.9–18.7 $/GJFT). Co‐firing scenarios (CXtY) result in lower cost fuel (but a higher environmental penalty) than 100% biomass fired scenarios (XtY). In most cases, switchgrass and the productive region of Nampula provide the lowest fuel production cost compared to eucalyptus and the marginally productive Gaza region. Both FT and ion in Mozambique are more costly than in Rotterdam. For the Netherlands, both FT and power production are competitive against average energy costs in Western Europe. The analysis shows that large‐scale bioenergy production can become competitive against fossil fuels. While the benefits of TOPs are apparent in logistics and conversion, the current higher torrefaction costs contribute to higher biofuel costs. Improvements in torrefaction technology can result in significant performance improvements over the future chain. © 2013 Society of Chemical Industry and John Wiley & Sons, Ltd

This paper analyzes the ability of water utilities to contribute to sustainability transition processes. More specifically, we compare the capacity of utilities, embedded in purely public, mixed and largely private governance modes, to innovate. We employ dynamic capabilities as core indicators for innovativeness and therefore as major enabling factors for sustainable sector transitions. We assess the relationship between governance modes and innovation by conducting an in-depth comparative analysis of three water utilities, each within a differing governance mode along the public-to-private continuum: Zurich, Berlin and Leeds. While we find that the private and mixed governance modes have an increased degree of innovativeness, they perform lower in terms of static sustainability criteria than the public mode. We therefore conclude that the impact of privatization on sustainability transitions in the water sector involves multi-dimensional trade-offs between static and dynamic sustainability criteria.

Fossil fuel substitution with biomass is one of the measures to reduce carbon dioxide (CO2) emissions. This paper estimates the cost-effectiveness of raising industrial steam and producing materials (i.e. chemicals, polymers) from biomass. We quantify their long-term global potentials in terms of energy saving, CO2 emission reduction, cost and resource availability. Technically, biomass can replace all fossil fuels used for the production of materials and for generating low and medium temperature steam. Cost-effective opportunities exist for steam production from biomass residues and by substitution of high value petrochemicals which would together require more than 20 exajoules (EJ) of biomass worldwide in addition to baseline by 2030. Potentials could double in 2050 and reach 38-45 EJ (25% of the total industrial energy use), with most demand in Asia, other developing countries and economies in transition. The economic potential of using biomass as chemical feedstock is nearly as high as for steam production, indicating its importance. The exploitation of these potentials depends on energy prices and industry's access to biomass supply. Given the increasing competition for biomass from several economic sectors, more resource efficient materials need to be developed while steam production is already attractive due to its high effectiveness for reducing CO2 emissions per unit of biomass.

National net zero emission targets could, if fully implemented, reduce best estimates of projected global average temperature increase to 2.0–2.4 °C by 2100, bringing the Paris Agreement temperature goal within reach. A total of 131 countries are discussing, have announced or have adopted net zero targets, covering 72% of global emissions. These targets could substantially lower projected warming as compared to currently implemented policies (2.9–3.2 °C) or pledges submitted to the Paris Agreement (2.4–2.9 °C). Current pledges for emissions cuts are insufficient to meet the Paris Agreement temperature goal. The wave of net zero targets being discussed and adopted could make the Paris goal possible if further countries follow suit.