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Flexible butyl interconnection segments are synthetically incorporated into an electronically conductive poly(pyrene methacrylate) homopolymer and its copolymer. The insertion of butyl segment makes the pyrene polymer more flexible, and can better accommodate deformation. This new class of flexible and conductive polymers can be used as a polymer binder and adhesive to facilitate the electrochemical performance of a silicon/graphene composite anode material for lithium ion battery application. They act like a “spring” to maintain the electrode mechanical and electrical integrity. High mass loading and high areal capacity, which are critical design requirements of high energy batteries, have been achieved in the electrodes composed of the novel binders and silicon/graphene composite material. A remarkable area capacity of over 5 mAh/cm2 and volumetric capacity of over 1700 Ah/L have been reached at a high current rate of 333 mA/g.

Abstract In this paper, we analyze the rationale for an energy policy mix when the European Emissions Trading Scheme (ETS) is considered from a public choice perspective. That is, we argue that the economic textbook model of the ETS implausibly assumes (1) efficient policy design and (2) climate protection as the single objective of policy intervention. Contrary to these assumptions, we propose that the ETS originates from a political bargaining game within a context of multiple policy objectives. In particular, the emissions cap is negotiated between regulators and emitters with the emitters' abatement costs as crucial bargaining variable. This public choice view yields striking implications for an optimal policy mix comprising RES supporting policies. Whereas the textbook model implies that the ETS alone provides sufficient climate protection, our analysis suggests that support for renewable energies (1) contributes to a more effective ETS-design and (2) may even increase the overall efficiency of climate and energy policy if other externalities and policy objectives besides climate protection are considered. Thus, our analysis also shows that a public choice view not necessarily entails negative evaluations concerning efficiency and effectiveness of a policy mix.

The passivation of iron and steel (DIN 1623) was studied by integral and depth selective conversion electron Mossbauer spectroscopy and Auger electron spectroscopy. Thickness and phase composition of the passive layer formed in sulphate solution and in a phosphate buffer were determined in dependence on the anodic potential and the duration of the passivating procedure. The experimental results lead to the conclusion that not the whole oxidic layer is responsible for the passivity but only a very thin intermediate layer formed between the cubic substrate and the rhombic oxide (γ-FeOOH) cover.

In the context of rapid climate change, phenological advance is a key adaptation for which evidence is accumulating across taxa. Among vertebrates, phenotypic plasticity is known to underlie most of this phenological change, while evidence for micro-evolution is very limited and challenging to obtain. In this study, we quantified phenotypic and genetic trends in timing of spring migration using 8032 dates of arrival at the breeding grounds obtained from observations on 1715 individual common terns (Sterna hirundo) monitored across 27 years, and tested whether these trends were consistent with predictions of a micro-evolutionary response to selection. We observed a strong phenotypic advance of 9.3 days in arrival date, of which c. 5% was accounted for by an advance in breeding values. The Breeder’s equation and Robertson’s Secondary Theorem of Selection predicted qualitatively similar evolutionary responses to selection, and these theoretical predictions were largely consistent with our estimated genetic pattern. Overall, our study provides rare evidence for micro-evolution underlying (part of) an adaptive response to climate change in the wild and illustrates how a combination of adaptive micro-evolution and phenotypic plasticity facilitated a shift towards earlier spring migration in this free-living population of common terns. Data used for models presented in: Micro-evolutionary response of spring migration timing in a wild seabird by Moiron M, Teplitsky C, Haest B, Charmantier A†, Bouwhuis S† († = shared last authors) published in Evolution Letters. for information regarding the analyses, please contact mariamoironc@gmail.com for information regarding the data, please contact sandra.bouwhuis@ifv-vogelwarte.de if you'd like to use the data, please also contact sandra.bouwhuis@ifv-vogelwarte.de These data are part of those collected in an ongoing individual-based longitudinal population study additional data are likely to be available, and we are often very happy to collaborate provided that none of our own staff or students is working on a conflicting project.

Avoiding irreversible climate change as effectively as possible is one of the most pressing challenges of society. Carbon pricing that is uniformly valid on a global and cross-sectoral basis represents a cost-efficient policy tool to meet this challenge. Carbon pricing allows external costs to be allocated or internalized on a polluter-pays principle. It is shown that a global emissions cap-and-trade system is the most suitable market-based instrument for reducing global emissions levels, in line with the temperature goal set by the Paris Agreement. A proposal for its design is presented in this paper. This instrument encourages worldwide measures, with the lowest marginal abatement cost, according to a pre-defined reduction path. Thereby, it ensures compliance with a specified remaining carbon budget to meet a certain temperature limit in a cost-efficient manner. Possible reduction paths are presented in this paper. Weaknesses in the design of existing emissions trading systems (ETS), such as the EU ETS, are identified and avoided in the proposed instrument. The framework solves several problems of today’s climate change policies, like the free rider problem, carbon leakage, rebound effects or the green paradox. The introduction of a global uniform carbon pricing instrument and its concrete design should be the subject of policy, especially at the United Nations climate change conferences, as soon as possible in order to allow for rapid implementation. If a global ETS with a uniform carbon price could be introduced, additional governmental regulations with regard to carbon emissions would become obsolete.

Abstract. Reliable quantification of the sources and sinks of greenhouse gases, together with trends and uncertainties, is essential to monitoring the progress in mitigating anthropogenic emissions under the Paris Agreement. This study provides a consolidated synthesis of CH4 and N2O emissions with consistently derived state-of-the-art bottom-up (BU) and top-down (TD) data sources for the European Union and UK (EU27+UK). We integrate recent emission inventory data, ecosystem process-based model results, and inverse modelling estimates over the period 1990–2018. BU and TD products are compared with European National GHG Inventories (NGHGI) reported to the UN climate convention secretariat UNFCCC in 2019. For uncertainties, we used for NGHGI the standard deviation obtained by varying parameters of inventory calculations, reported by the Member States following the IPCC guidelines recommendations. For atmospheric inversion models (TD) or other inventory datasets (BU), we defined uncertainties from the spread between different model estimates or model specific uncertainties when reported. In comparing NGHGI with other approaches, a key source of bias is the activities included, e.g. anthropogenic versus anthropogenic plus natural fluxes. In inversions, the separation between anthropogenic and natural emissions is sensitive to the geospatial prior distribution of emissions. Over the 2011–2015 period, which is the common denominator of data availability between all sources, the anthropogenic BU approaches are directly comparable, reporting mean emissions of 20.8 Tg CH4 yr−1 (EDGAR v5.0) and 19.0 Tg CH4 yr−1 (GAINS), consistent with the NGHGI estimates of 18.9 ± 1.7 Tg CH4 yr−1. TD total inversions estimates give higher emission estimates, as they also include natural emissions. Over the same period regional TD inversions with higher resolution atmospheric transport models give a mean emission of 28.8 Tg CH4 yr−1. Coarser resolution global TD inversions are consistent with regional TD inversions, for global inversions with GOSAT satellite data (23.3 Tg CH4yr−1) and surface network (24.4 Tg CH4 yr−1). The magnitude of natural peatland emissions from the JSBACH-HIMMELI model, natural rivers and lakes emissions and geological sources together account for the gap between NGHGI and inversions and account for 5.2 Tg CH4 yr−1. For N2O emissions, over the 2011–2015 period, both BU approaches (EDGAR v5.0 and GAINS) give a mean value of anthropogenic emissions of 0.8 and 0.9 Tg N2O yr−1 respectively, agreeing with the NGHGI data (0.9 ± 0.6 Tg N2O yr−1). Over the same period, the average of the three total TD global and regional inversions was 1.3 ± 0.4 and 1.3 ± 0.1 Tg N2O yr−1 respectively, compared to 0.9 Tg N2O yr−1 from the BU data. The TU and BU comparison method defined in this study can be operationalized for future yearly updates for the calculation of CH4 and N2O budgets both at EU+UK scale and at national scale. The referenced datasets related to figures are visualized at https://doi.org/10.5281/zenodo.4288969 (Petrescu et al., 2020).

AbstractWe devise a methodology to predict failures in wind turbine drive‐train components and quantify its utility. The methodology consists of two main steps. The first step is the set up of a predictive model for shutdown events, which is able to raise an alarm in advance of the fault‐induced shutdown. The model is trained on data for shutdown events retrieved from the alarm log of an offshore wind farm. Here, it is assumed that the timely prediction of low‐severity events, typically caused by abnormal component operation, allows for an intervention that can prevent premature component failures. The prediction models are based on statistical classification using only supervisory control and data acquisition (SCADA) data. In the second step, the shutdown prediction model is combined with a cost model to provide an estimate of the benefits associated with implementing the predictive maintenance system. This is achieved by computing the maximum net utility attainable as a function of the model performance and efficiency of intervention carried out by the user. Results show that the system can be expected to be cost‐effective under specific conditions. A discussion about potential improvements of the approach is provided, along with suggestions for further research in this area.

In this study, feasibility of selected nutrient sequestration during hydrothermal carbonization (HTC) was tested for three different HTC temperatures (180, 230, and 300 °C). To study the nutrient sequestration in solid from liquid solution, sugar and salt solutions were chosen as HTC feedstock. Glucose was used as carbohydrate source and various salts e.g., ammonium hydrophosphate, potassium chloride, potassium sulfate, and anhydrous ferric chloride were used as source of nitrogen and phosphorus, potassium, and iron, respectively. Solid hydrochar was extensively characterized by means of elemental, ICP-OES, SEM-EDX, surface area, pore volume and size, and ATR-FTIR to determine nutrients’ sequestration as well as hydrochar quality variation with HTC temperatures. The spherical mesoporous hydrochars produced during HTC have low surface area in the range of 1.0–3.5 m2 g?1. Hydrochar yield was increased about 10% with the increase of temperature from 180 °C to 300 °C. Nutrient sequestration was also increased with HTC temperature. In fact, around 71, 31, and 23 wt% nitrogen, iron, and phosphorus were sequestered at 300 °C, respectively. Potassium sequestration was very low throughout the HTC and maximum 5.2% was observed in solid during HTC.