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Five years after the efficiency tests of the European COST ES0601 project (known as “HOME”) new tests are planned with the use of a new benchmark dataset. New tests are needed for three reasons: i) Several homogenization methods have newer versions since HOME, while some other methods were not tested by HOME; ii) The HOME benchmark represented only one climatic region (i.e. the central-western European climate) and a not very large selection of inhomogeneity problems; and iii) The number of networks in the HOME benchmark was small, and thus certain kinds of results with them have large statistical uncertainty. For all these reasons the representativeness of HOME results is limited. The new tests will be performed by researchers of the Centre for Climate Change of the University Rovira i Virgili and those of the Spanish Meteorological Agency (AEMET) with the support of a Spanish national project. We will develop and use a much larger benchmark dataset than the HOME benchmark, but we will test automatic methods only, thus the amount of the required work remains feasible. Primarily, the openly accessible automatic methods will be tested, which do not need the direct collaboration of the method developers. However, we intend to keep contact with the developers in order to test the best versions of the methods with the best possible parameterizations . Until the autumn of 2016 we will be accepting newly developed methods and versions for testing. In the development of the new benchmark, we will build on the knowledge gathered before the creation of HOME benchmark, but we aim to create an even more realistic benchmark including various segments representing particular climatic regions and inhomogeneity problems. For instance, the new benchmark will consider that a) The frequency of breaks of detectable size is generally much higher for temperature series than for precipitation series; b) The annual cycle of biases depends both on the examined variable and the geographical region; c) The frequent presence of short-term, platform-shaped inhomogeneities in observed temperature series. The efficiencies will be evaluated with the residual root mean square error of monthly and annual values in homogenized series, as well as with the residual trend bias errors for individual time series and network mean trends. Presentación realizada en: 10th EUMETNET Data Management Workshop celebrado en St. Gallen, Suiza, del 28 al 30 de octubre de 2015.

The utilisation of thermoelectric technology as a heat pump in heating applications necessitates comprehensive investigation. The scalable nature of thermoelectric technology enables its operation at elevated temperatures without the requirement of refrigerants. In this work, an accurate computational model that can simulate one- and two-stage thermoelectric heat pumps is developed. This model uses the electric-thermal analogy and the finite difference method, including the thermoelectric effects, temperature dependent properties, thermal contact resistances and all heat exchangers, even the intermediate heat exchanger in the case of a two-stage configuration. Moreover, the model has been experimentally validated by built and tested prototypes, being the first time that a two-stage thermoelectric heat pump model is experimentally validated. The discrepancy between the simulated and experimental results is below the ± 10 % for , ± 8 % for generated heat and temperature lift in the airflow, and less than the ± 6 % for consumed power. Additonally, the model simulates real tendencies under different operating conditions, proving the reliability of the developed thermoelectric heat pump model. Finally, the model is used to optimise a thermoelectric system combining one- and two-stage thermoelectric heat pumps, and hybridising them with electric resistances. An airflow of 16.5 m3/h is heated from 25 °C to 160 °C, achieving a maximum of 1.21. Lastly, the importance of considering the thermal resistances of the heat exchangers is computationally modelled and demonstrated. Not taking them into account would overestimate the performance of the TEHP system by more than the 7 %. The authors would like to acknowledge the support of the grant TED2021-130071A-I00 funded by MCIN/AEI/10.13039/501100011033 and, as appropriate, by 'European Union Next Generation EU/PRTR', as well as the Government of Navarre, as part of the 'Grants to SINAI agents for the realization of collaborative R&D projects' under the PC066-067-068 FlexORCStorage. Open access funding provided by Universidad Pública de Navarra.

Abstract This study develops a novel sustainability assessment methodology for energy systems using life-cycle emission factors and sustainability indicators. Here, the global warming and environmental impact dimensions of the sustainability assessment methodology are examined in detail. A comparative analysis shows that a wind-battery system produces fewer potential global warming, stratospheric ozone depletion, air pollution, and water pollution impacts compared to a gas-fired system. The wind-battery system generates 13% of the life-cycle GHG emissions and 22% of the life-cycle ozone-depleting substance emissions of a gas-fired power plant. Nitrous oxide contributes more than 90% of the stratospheric ozone depletion potential of gas-fired and wind-battery systems.

Abstract In the present study, Loblolly pine biomass residue was converted to bio-oil in a two-step process, consisting of 1) fast pyrolysis in the presence of zeolite ZSM-5 as a catalyst to produce pyrolysis oil, 2) hydrogenation of pyrolysis oil using formic acid as the hydrogen source in presence of Ru/activated carbon catalyst. Pyrolysis oils were analyzed by 13C, 31P and HSQC-NMR and the results revealed that the zeolite-induced catalytic fast pyrolysis process led to effective demethoxylation, producing more catechol and p-hydroxy-phenyl hydroxyl groups in the bio-oils, resulting in a decrease in the methoxyl group content by about 85 % and rich aromatic structures in the pyrolysis oils. The properties of pyrolysis oil with and without zeolite were in the bio-oil range. Hydrogenated pyrolysis oil showed that 79 % of the aromatic protons are eliminated and 87 % of protons are aliphatic in nature, with no oxygen attached to the α-carbon.

The ‘4 per mille Soils for Food Security and Climate’ was launched at the COP21 with an aspiration to increase global soil organic matter stocks by 4 per 1000 (or 0.4 %) per year as a compensation for the global emissions of greenhouse gases by anthropogenic sources. This paper surveyed the soil organic carbon (SOC) stock estimates and sequestration potentials from 20 regions in the world (New Zealand, Chile, South Africa, Australia, Tanzania, Indonesia, Kenya, Nigeria, India, China Taiwan, South Korea, China Mainland, United States of America, France, Canada, Belgium, England & Wales, Ireland, Scotland, and Russia). We asked whether the 4 per mille initiative is feasible for the region. The outcomes highlight region specific efforts and scopes for soil carbon sequestration. Reported soil C sequestration rates globally show that under best management practices, 4 per mille or even higher sequestration rates can be accomplished. High C sequestration rates (up to 10 per mille) can be achieved for soils with low initial SOC stock (topsoil less than 30 t C ha− 1), and at the first twenty years after implementation of best management practices. In addition, areas which have reached equilibrium will not be able to further increase their sequestration. We found that most studies on SOC sequestration only consider topsoil (up to 0.3 m depth), as it is considered to be most affected by management techniques. The 4 per mille number was based on a blanket calculation of the whole global soil profile C stock, however the potential to increase SOC is mostly on managed agricultural lands. If we consider 4 per mille in the top 1m of global agricultural soils, SOC sequestration is between 2-3 Gt C year− 1, which effectively offset 20–35% of global anthropogenic greenhouse gas emissions. As a strategy for climate change mitigation, soil carbon sequestration buys time over the next ten to twenty years while other effective sequestration and low carbon technologies become viable. The challenge for cropping farmers is to find disruptive technologies that will further improve soil condition and deliver increased soil carbon. Progress in 4 per mille requires collaboration and communication between scientists, farmers, policy makers, and marketeers.

Abstract New techniques for emissions reduction and energy efficiency are important challenges of the steel industry. Although great advantages have been reached in these fields, there are still new opportunities. One of them is the possible development of systems to recover energy from slags. The recent policies that encourage the use of renewable and alternative energies determine a favorable scenario for the development of new techniques of heat recovering. In this context, this article presents a new heat recuperation system for the slags produced in the factories of Arcelor–Mittal in Asturias (Spain) and study in detail the design of an innovative slags heat exchanger. To adjust its performance and to determine the influence of the geometric and flow design parameters, the heat exchanger has been simulated using numerical analysis software (CFD).

[ES]Se ha elaborado una nueva base de datos de precipitaciones medias mensuales y temperaturas máximas y mínimas medias mensuales, con la que se han analizado los datos de 142 estaciones meteorológicas obtenidos de la Agencia Estatal de Meteorología (AEMET) para el periodo (1989-2018). En este estudio se presentan los resultados de diferentes pruebas de homogeneización y relleno de 134, 172 y 176 series de temperaturas y precipitaciones provenientes de las estaciones ubicadas en la región de Extremadura. Para ello, se realizó un primer control de calidad de los datos cumpliendo con los requisitos de la Organización Meteorológica Mundial (OMM) y las recomendaciones indicadas por el Real Instituto Meteorológico de los Países Bajos (KNMI). Posteriormente se llevó a cabo la homogeneización de las series utilizando el software Climatol, en el que se han implementado diferentes funciones que permiten depurar los datos a través de un análisis de los valores atípicos y de la homogeneidad, así como la completación de las lagunas de las series. Los análisis confirman la obtención de unos niveles de depuración de los datos muy altos, confiables y de buena calidad; obteniendo así una nueva base de datos para posteriores estudios climáticos. [EN]A new database of monthly average rainfall and monthly average maximum and minimum temperatures has been developed, with which data from 142 weather stations obtained from the Agencia Estatal de Meteorología (AEMET) for the period (1989-2018) have been analysed. This study presents the results of different homogenisation and backfilling tests of 134, 172 and 176 temperature and precipitation series from stations located in the region of Extremadura. For this purpose, a first quality control of the data was carried out in compliance with the requirements of the World Meteorological Organisation (WMO) and the recommendations indicated by the Royal Netherlands Meteorological Institute (KNMI). Subsequently, the series were homogenised using Climatol software, in which different functions have been implemented to clean the data through an analysis of outliers and homogeneity, as well as filling in the gaps in the series. The analyses confirm the achievement of very high, reliable and good quality data cleaning levels, thus obtaining a new database for further climate studies. Esta investigación fue financiada por la Junta de Extremadura y el Fondo Europeo de Desarrollo Regional (FEDER) a través de la ayuda al grupo de investigación Alcántara (TIC008), GR21006, y el Proyecto IB18001 “Análisis y modelización del impacto del cambio climático sobre la distribución de zonas vitícolas en Extremadura”. Ponencia presentada en: XII Congreso de la Asociación Española de Climatología celebrado en Santiago de Compostela entre el 19 y el 21 de octubre de 2022.