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[EN]A systematic approach is developed for the conceptual optimal design of biomethane production via carbon capture. A hybrid heuristic-mathematical procedure is proposed to determine the optimal technology and operating conditions. The heuristic step consists of a literature-based screening of the available technologies. After the prescreening stage, the technologies selected are amine absorption, pressure swing adsorption (PSA), and membrane separation. The mathematical stage is composed of two steps. First, different alternatives for each technology are modeled based on first principles and rules of thumb. These models are used to select the optimal configuration for each process considered. Second, a superstructure model for biomethane production is developed integrating the pre-selected upgrading technologies to select the optimal process, as well as to determine the optimal operating conditions. Four waste sources are analyzed: cattle manure, swine manure, municipal food waste, and sludge. The results suggest that the best amine is diethanolamine (DEA), the best membrane material is the polyimide, and the suggested zeolite is 13X among the ones studied. Finally, among the three technologies, the overall results show that carbon capture using a PSA system using zeolite 13X results in lower production and investment costs, but very close to the use of membranes. The results indicate that food waste shows the lowest production cost for biomethane 0.36 €/Nm3, due to the largest organic matter content, whereas the investment costs are 67 M€, considering a biogas production rate of 0.035 kg of biomethane per kg of waste and the processing of 311 kt/yr of food waste. Credits or incentives are still needed for biomethane to be competitive with fossil natural gas. Junta de Castilla y León y USAL

Hydraulic fracturing drilling technology can cause a high risk of surface spill accidents and thus water contamination. Climate change together with the high water demand and rapid increase in industrial and agricultural activities are valued reasons why we should all care about the availability of water resources and protect them from contamination. Hence, the purpose of this study is to estimate the risk associated with a site contaminated with benzene from oil spillage and its potential impact on groundwater. This study focused on investigating the impact of soil variability and water table depth on groundwater contamination. Temperature-dependent parameters, such as soil water content and the diffusion of pollutants, were considered as key input factors for the HYDRUS 1D numerical model to simulate benzene migration through three types of soil (loamy, sandy clay loam, and silt loam) and evaluate its concentration in the water aquifer. The results indicated that an anticipated increase in earth’s average surface temperature by 4 °C due to climate change could lead to a rise in the level of groundwater pollution in the study area by 0.017 mg/L in loamy soil, 0.00046 mg/L in sandy clay loam soil, and 0.00023 mg/L in silt loam soil. It was found that climate change can reduce the amount of benzene absorbed from 10 to 0.07% in loamy soil, 14 to 0.07% in sandy clay loam soil, and 60 to 53% in silt loam soil. The results showed that the soil properties and solute characteristics that depend on the temperature have a major and important role in determining the level of groundwater pollutants.

Despite the great number of models developed in research projects, only a small percentage have been successfully transferred to the productive sector. The PRIMA programme supported by Horizon 2020, the European Union Framework Programme for Research and Innovation, aims to reverse this situation. The SUPROMED project funded by PRIMA sought to develop an online platform composed of several models adapted to the requirements of end users for increasing the economic and environmental sustainability of Mediterranean agricultural systems. MOPECO, in its research version, was designed to maximize the profitability of irrigated farms in water-scarce regions. A simplified version of this model (MOPECO irrigation scheduling) was included in the SUPROMED platform for improving irrigation efficiency, providing farmers with a useful irrigation scheduling software. This paper shows the approach to adapt and transfer MOPECO to the productive sector. The tool was validated in three different demosite areas across the Mediterranean, involving local stakeholders in the design, validation, and dissemination of the software. The simplified tool reached similar or higher yields than farmers using less water. Thus, the average water saved was around 16%, while the average yield increased around 10% in the plots located in the three demosites of the project (Eastern Mancha in Spain, Bekaa valley in Lebanon, and Sidi Bouzid in Tunisia). This fact decreased the water footprint and increased the profitability of farms. The high applicability of the tool has generated interest among many technicians, farmers, and advisory enterprises. Furthermore, regional and national governmental extension services have shown interest in spreading the use of the tool across their territories, validating the methodology used for adapting and transferring a scientific model to the productive sector.

Global warming and direct anthropogenic impacts, such as water extraction, are largely affecting water budgets in Mediterranean wetlands, thereby increasing wetland salinities and isolation, and decreasing water depths and hydroperiods (duration of the inundation period). These wetland features are key elements structuring waterbird communities. However, the ultimate and net consequences of these dynamic conditions on waterbird assemblages are largely unknown. We combined a regular sampling on waterbird presence through the 2008 annual cycle with in-situ data on these relevant environmental predictors of waterbird distribution to model habitat selection for 69 individual species in a typical Mediterranean wetland network in south-western Spain. Species association with environmental features were subsequently used to predict changes in habitat suitability for each species under three climate change scenarios (encompassing changes in environment that ranged from 10% to 50% change as predicted by climatic models). Waterbirds distributed themselves unevenly throughout environmental gradients and water salinity was the most important gradient structuring the distribution of the community. Environmental suitability for the guilds of diving birds and vegetation gleaners will be reduced according to future climate scenarios, while most small wading birds will benefit from changing conditions. Resident species and those that breed in this wetland network will be also more impacted than those using this area for wintering or stopover. We provide here a tool that can be used in a horizon-scanning framework to identify emerging issues on waterbird conservation and to anticipate suitable management actions : Datasets as supporting information to article “How will climate change affect endangered Mediterranean waterbirds?” to be published in PLOS ONE. Address questions to Francisco Ramírez: ramirez@ub.edu

Integrated multitrophic aquaculture (IMTA) is a versatile technology emerging as an ecological and sustainable solution for traditional monoculture aquacultures in terms of effluent treatment. Nevertheless, IMTA is still poorly applied in aquaculture industry due to, among other reasons, the lack of effective, low-investment and low-maintenance solutions. In this study, one has developed a practical and low maintenance IMTA-pilot system, settled in a semi-intensive coastal aquaculture. The optimisation and performance of the system was validated using Ulva spp., a macroalgae that naturally grows in the fishponds of the local aquaculture. Several cultivation experiments were performed at lab-scale and in the IMTA-pilot system, in static mode. The specific growth rate (SGR), yield, nutrient removal, N and C enrichment, protein and pigment content were monitored. Ulva spp. successfully thrived in effluent from the fish species sea bream (Sparus aurata) and sea bass (Dicentrarchus labrax) production tanks and significantly reduced inorganic nutrient load in the effluent, particularly, NH4+, PO43− and NO3−. The enrichment of nitrogen in Ulva spp.’s tissues indicated nitrogen assimilation by the algae, though, the cultivated Ulva spp. showed lower amounts of protein and pigments in comparison to the wild type. This study indicates that the designed IMTA-pilot system is an efficient solution for fish effluent treatment and Ulva spp., a suitable effluent remediator.

Format: raw binary. The raw binary archive is composed of 576 zipped files, corresponding to the SPEI index at time scales between 1 and 48 months for the whole World and divided by decades (except the last file, containing only data for the period 2001-2006). Each zipped file contains three files, one with the data itselt (.img), and two headers (.doc and .hdr). The information contained in the header files is equivalent, and allows direct access to the data using some widely used commercial programs. Naming convention: spei[tempscale]_[decade].zip, where [tempscale] is a number between 1 and 48 indicating the temporal scale of the index (months), and [decade] indicates the years of data contained in the file. Example: spei12_1910-1919.zip. All currently available gridded drought datasets at continental and global scales are based on either the PDSI or the sc-PDSI. A new global drought dataset based on the Standardised Precipitation-Evapotranspiration Index (SPEI) has been developed, which covers time scales from 1-48 months at a spatial resolution of 0.5°, and provides temporal coverage for the period 1901-2006. This dataset represents an improvement in spatial resolution and operative capability of previous gridded drought datasets based on the PDSI, and enables identification of various drought types. A monthly global dataset of a multiscalar drought index is presented and compared in terms of spatial and temporal variability with the existing continental and global drought datasets based on the Palmer drought severity index (PDSI, scPDSI). The new dataset is based on the standardized precipitation evapotranspiration index (SPEI). The index was obtained from the CRU TS3.0 data, covering time scales from 1 to 48 months for the period 1901-2006, and has a spatial resolution of 0.5°. The advantages of the new dataset are that: i) it improves the spatial resolution of the unique global drought dataset at a global scale; ii) it is spatially and temporally comparable to other datasets, given the probabilistic nature of the SPEI, and, in particular; iii) it enables identification of various drought types, given the multiscalar character of the SPEI. More details at: http://www.eead.csic.es/spei/spei.html A monthly global dataset of a multiscalar drought index is presented and compared in terms of spatial and temporal variability with the existing continental and global drought datasets based on the Palmer drought severity index (PDSI, scPDSI). The new dataset is based on the standardized precipitation evapotranspiration index (SPEI). The index was obtained from the CRU TS3.0 data, covering time scales from 1 to 48 months for the period 1901-2006, and has a spatial resolution of 0.5°. The advantages of the new dataset are that: i) it improves the spatial resolution of the unique global drought dataset at a global scale; ii) it is spatially and temporally comparable to other datasets, given the probabilistic nature of the SPEI, and, in particular; iii) it enables identification of various drought types, given the multiscalar character of the SPEI. More details at: http://www.eead.csic.es/spei/spei.html All currently available gridded drought datasets at continental and global scales are based on either the PDSI or the sc-PDSI. A new global drought dataset based on the Standardised Precipitation-Evapotranspiration Index (SPEI) has been developed, which covers time scales from 1-48 months at a spatial resolution of 0.5°, and provides temporal coverage for the period 1901-2006. This dataset represents an improvement in spatial resolution and operative capability of previous gridded drought datasets based on the PDSI, and enables identification of various drought types. The Global 0.5° gridded SPEI dataset is made available under the Open Database License. Any rights in individual contents of the database are licensed under the Database Contents License. Users of the dataset are free to share, create and adapt under the conditions of attribution and share-alike. Use of the newest version is recommended. Older versions are still available to allow replicability. The dataset is freely available on the web repository of the Spanish National Research Council (CSIC) in three different formats (NetCDF, binary raster, and plain text).

Microbial electrochemical technologies (METs) constitute the core of a number of emerging technologies with a high potential for treating urban wastewater due to a fascinating reaction mechanism—the electron transfer between bacteria and electrodes to transform metabolism into electrical current. In the current work, we focus on the model electroactive microorganism Geobacter sulfurreducens to explore both the design of new start-up procedures and electrochemical operations. Our chemostat-grown plug and play cells, were able to reduce the start-up period by 20-fold while enhancing chemical oxygen demand (COD) removal by more than 6-fold during this period. Moreover, a filter-press based bioreactor was successfully tested for both acetate-supplemented synthetic wastewater and real urban wastewater. This proof-of-concept pre-pilot treatment included a microbial electrolysis cell (MEC) followed in time by a microbial fuel cell (MFC) to finally generate electrical current of ca. 20 A·m−2 with a power of 10 W·m−2 while removing 42 g COD day−1·m−2. The effective removal of acetate suggests a potential use of this modular technology for treating acetogenic wastewater where Geobacter sulfurreducens outcompetes other organisms.

Natural potentials for future cropland expansion The potential for the expansion of cropland is restricted by the availability of land resources and given local natural conditions. As a result, area that is highly suitable for agriculture according to the prevailing local biophysical conditions but is not under cultivation today has a high natural potential for expansion. Policy regulations can further restrict the availability of land for expansion by designating protected areas, although they may be suitable for agriculture. Conversely, by applying e.g. irrigation practices, land can be brought under cultivation, although it may naturally not be suitable. Here, we investigate the potentials for agricultural expansion for near future climate scenario conditions to identify the suitability of non-cropland areas for expansion according to their local natural conditions. We determine the available energy, water and nutrient supply for agricultural suitability from climate, soil and topography data, by using a fuzzy logic approach according to Zabel et al. (2014). It considers the 16 globally most important staple and energy crops. These are: barley, cassava, groundnut, maize, millet, oil palm, potato, rapeseed, rice, rye, sorghum, soy, sugarcane, sunflower, summer wheat, winter wheat. The parameterization of the membership functions that describe each of the crops’ specific natural requirements is taken from Sys et al. (1993). The considered natural conditions are: climate (temperature, precipitation, solar radiation), soil properties (texture, proportion of coarse fragments and gypsum, base saturation, pH content, organic carbon content, salinity, sodicity), and topography (elevation, slope). As a result of the fuzzy logic approach, values in a range between 0 and 1 describe the suitability of a crop for each of the prevailing natural conditions at a certain location. The smallest suitability value over all parameters finally determines the suitability of a crop. The daily climate data is provided by simulation results from the global climate model ECHAM5 (Jungclaus et al. 2006) for near future (2011-2040) SRES A1B climate scenario conditions. Soil data is taken from the Harmonized World Soil Database (HWSD) (FAO et al. 2012), and topography data is applied from the Shuttle Radar Topography Mission (SRTM) (Farr et al. 2007). In order to gather a general crop suitability, which does not refer to one specific crop, the most suitable crop with the highest suitability value is chosen at each pixel. In addition the natural biophysical conditions, we consider today’s irrigated areas according to (Siebert et al. 2013). We assume that irrigated areas globally remain constant until 2040, since adequate data on the development of irrigated areas do not exist, although it is likely that freshwater availability for irrigation could be limited in some regions, while in other regions surplus water supply could be used to expand irrigation practices (Elliott et al. 2014). However, it is difficult to project where irrigation practices will evolve, since it is driven by economic investment costs that are required to establish irrigation infrastructure. In principle, all agriculturally suitable land that is not used as cropland today has the natural potential to be converted into cropland. We assume that only urban and built-up areas are not available for conversion, although more than 80% of global urban areas are agriculturally suitable (Avellan et al. 2012). However, it seems unlikely that urban areas will be cleared at the large scale due to high investment costs, growing cities and growing demand for settlements. Concepts of urban and vertical farming usually are discussed under the aspects of cultivating fresh vegetables and salads for urban population. They are not designed to extensively grow staple crops such as wheat or maize for feeding the world in the near future. Urban farming would require one third of the total global urban area to meet only the global vegetable consumption of urban dwellers (Martellozzo et al. 2015). Thus, urban agriculture cannot substantially contribute to global agricultural production of staple crops. Protected areas or dense forested areas are not excluded from the calculation, in order not to lose any information in the further combination with the biodiversity patterns (see chapter 2.3). We use data on current cropland distribution by Ramankutty et al. (2008) and urban and built-up area according to the ESA-CCI land use/cover dataset (ESA 2014). From this data, we calculate the ‘natural expansion potential index’ (Iexp) that expresses the natural potential for an area to be converted into cropland as follows: Iexp = S * Aav The index is determined by the quality of agricultural suitability (S) (values between 0 and 1) multiplied with the amount of available area (Aav) for conversion (in percentage of pixel area). The available area includes all suitable area that is not cultivated today, and not classified as urban or artificial area. The index ranges between 0 and 100 and indicates where the conditions for cropland expansion are more or less favorable, when taking only natural conditions into account, disregarding socio-economic factors, policies and regulations that drive or inhibit cropland expansion. The index is a helpful indicator for identifying areas where cropland expansion could take place in the near future. Further information Detailled information are available in the following publication: Delzeit, R., F. Zabel, C. Meyer and T. Václavík (2017). Addressing future trade-offs between biodiversity and cropland expansion to improve food security. Regional Environmental Change 17(5): 1429-1441. DOI: 10.1007/s10113-016-0927-1 Contact Please contact: Dr. Florian Zabel, f.zabel@lmu.de, Department für Geographie, LMU München (www.geografie.uni-muenchen.de) This research was carried out within the framework of the GLUES (Global Assessment of Land Use Dynamics, Greenhouse Gas Emissions and Ecosystem Services) Project, which has been supported by the German Ministry of Education and Research (BMBF) program on sustainable land management (grant number: 01LL0901E).