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[EN]A systematic approach is developed for the conceptual optimal design of biomethane production via carbon capture. A hybrid heuristic-mathematical procedure is proposed to determine the optimal technology and operating conditions. The heuristic step consists of a literature-based screening of the available technologies. After the prescreening stage, the technologies selected are amine absorption, pressure swing adsorption (PSA), and membrane separation. The mathematical stage is composed of two steps. First, different alternatives for each technology are modeled based on first principles and rules of thumb. These models are used to select the optimal configuration for each process considered. Second, a superstructure model for biomethane production is developed integrating the pre-selected upgrading technologies to select the optimal process, as well as to determine the optimal operating conditions. Four waste sources are analyzed: cattle manure, swine manure, municipal food waste, and sludge. The results suggest that the best amine is diethanolamine (DEA), the best membrane material is the polyimide, and the suggested zeolite is 13X among the ones studied. Finally, among the three technologies, the overall results show that carbon capture using a PSA system using zeolite 13X results in lower production and investment costs, but very close to the use of membranes. The results indicate that food waste shows the lowest production cost for biomethane 0.36 €/Nm3, due to the largest organic matter content, whereas the investment costs are 67 M€, considering a biogas production rate of 0.035 kg of biomethane per kg of waste and the processing of 311 kt/yr of food waste. Credits or incentives are still needed for biomethane to be competitive with fossil natural gas. Junta de Castilla y León y USAL

Hydraulic fracturing drilling technology can cause a high risk of surface spill accidents and thus water contamination. Climate change together with the high water demand and rapid increase in industrial and agricultural activities are valued reasons why we should all care about the availability of water resources and protect them from contamination. Hence, the purpose of this study is to estimate the risk associated with a site contaminated with benzene from oil spillage and its potential impact on groundwater. This study focused on investigating the impact of soil variability and water table depth on groundwater contamination. Temperature-dependent parameters, such as soil water content and the diffusion of pollutants, were considered as key input factors for the HYDRUS 1D numerical model to simulate benzene migration through three types of soil (loamy, sandy clay loam, and silt loam) and evaluate its concentration in the water aquifer. The results indicated that an anticipated increase in earth’s average surface temperature by 4 °C due to climate change could lead to a rise in the level of groundwater pollution in the study area by 0.017 mg/L in loamy soil, 0.00046 mg/L in sandy clay loam soil, and 0.00023 mg/L in silt loam soil. It was found that climate change can reduce the amount of benzene absorbed from 10 to 0.07% in loamy soil, 14 to 0.07% in sandy clay loam soil, and 60 to 53% in silt loam soil. The results showed that the soil properties and solute characteristics that depend on the temperature have a major and important role in determining the level of groundwater pollutants.

In the current study, we examine the Indonesian government's watershed management program, which was established in 2001. In 2005, the Coordination Team for Rescue of Water Resources (CTRWR) was established to execute the program on a national level. However, at the time, field implementation was a sectoral interest due to the lack of program integration. To this end, the Indonesian government promoted integrated watershed management in 2009, which since then has been implemented by all stakeholders (in Top–Down management form), with application limited to preparing and planning documents. This is mainly driven by the stakeholders’ lack of understanding with regard to watershed systems as integrated management units. Field implementation results have not yet been realized, including the promotion of community-based watershed management (through Bottom–Up management). The purpose of our research was to determine the index numbers by measuring the level of cooperation between watershed management workers based on the Village Watershed Model (VWM) specifically surface water which includes six variables: planning, participation, institutional, fund sharing, gender, and management systems. The method used was an ordinal measure with the Likert scale. Our data showed successful watershed management, in which five of the six VWM variables—planning, participation, institutional, fund sharing, and management systems—were in the “good” category with indices ranging from 73.08 to 78.27. The gender variable index (69.12) was in the “medium” category.

Grid connected energy storage systems are regarded as promising solutions for providing ancillary services to electricity networks and to play an important role in the development of smart grids. Thus far, the more mature battery technologies have been installed in pilot projects and studies have indicated their main advantages and shortcomings. The main concerns for wide adoption are the overall cost, the limited number of charging cycles (or lifetime), the depth of discharge, the low energy density and the sustainability of materials used. Vanadium Redox Flow Batteries (VRFB) are a promising option to mitigate many of these shortcomings, and demonstration projects using this technology are being implemented both in Europe and in the USA. This study presents a model using MATLAB/Simulink, to demonstrate how a VRFB based storage device can provide multi-ancillary services, focusing on frequency regulation and peak-shaving functions. The study presents a storage system at a medium voltage substation and considers a small grid load profile, originating from a residential neighbourhood and fast charging stations demand. The model also includes an inverter controller that provides a net power output from the battery system, in order to offer both services simultaneously. Simulation results show that the VRFB storage device can regulate frequency effectively due to its fast response time, while still performing peak-shaving services. VRFB potential in grid connected systems is discussed to increase awareness of decision makers, while identifying the main challenges for wider implementation of storage systems, particularly related to market structure and standardisation requirements.

Innovation Districts are rising as the banners of the new urban, economic, and social paradigm and as a solution to the renaissance of inner cities since they expedite the creation and commercialization of new ideas which leverage the city goals and its technologic and economic attributes. The configuration of accurate indicators to measure the degree of achievement of the innovation district goals is one of the main requirements to ensure district proper development. Even when the study of innovation districts is a topic that is increasingly under study, little is still known about the insight, and it is still needed tools that favor their evolution and development. The aim of this paper is two-fold: on the one hand, it seeks to collect and analyze the indicators that have been used in literature to measure the degree of maturity over the course of the 20-year existence of the 22@Barcelona, an area of innovation that transformed an old industrial district into a knowledge-based one. On the other hand, guided by the four dimensions of the Knowledge Base Urban Development theory and the main actors that make up Triple Helix approach, the paper designs a framework of indicators in the four spheres that shape the regeneration of the district, that is, urban, economic, social and governance. As we shall see, a total of 47 indicators are proposed, indicating for each of them: the environment in which it is applied, the main purpose to which it responds, and the main actor with the greatest power of action over it.

AbstractSulfate reduction in salt‐rich wastewaters using unadapted granular sludge was investigated in 0.9 L UASB reactors (pH 7.0 ± 0.2; hydraulic retention time from 8–14 h) fed with acetate, propionate, or ethanol at organic loading rates up to 10 gCOD.L−1.day−1 and in excess sulfate (COD/SO of 0.5). High‐rate sulfate reduction rates (up to 3.7 gSO42‐.L−1.day−1) were achieved at salinities exceeding 50 gNaCl.L−1 and 1 gMgCl2.L−1. Sulfate reduction proceeded at a salinity of up to 70 gNaCl.L−1 and 1 gMgCl2.L−1 (corresponding to a conductivity of about 85–90 mS.cm−1), although at lower rates compared to a conductivity of 60–70 mS.cm−1. Ethanol as well as propionate were suitable substrates for sulfate reduction, with acetate and sulfide as the end products. The successful high‐rate treatment was due to the proliferation of a halotolerant incomplete oxidizing SRB population present in the unadapted inoculum sludge. Bioaugmentation of this sludge with the acetate oxidizing halotolerant SRB Desulfobacter halotolerans was unsuccessful, as the strain washed out from the UASB reactor without colonizing the UASB granules. © 2004 Wiley Periodicals, Inc.

Although recent research has demonstrated that waste orange peel (WOP) is a potentially valuable resource that can be transformed into high value products, heat generation, biomethanisation and composting might be considered the most feasible alternatives in terms of yield. This study revealed that WOP can be successfully valorised through combustion. However, a previous drying step, which generates hazardous wastewater, is required and harmful NOx are emitted with the flue gases. In contrast, a high yield of renewable methane (280LSTPCH4/kg added COD, chemical oxygen demand) and an organic amendment can be obtained through the thermophilic biomethanisation of WOP following the removal of valuable essential oils from the peel. Co-composting of WOP combined at different proportions (17-83%) with the organic fraction of municipal solid waste (OFMSW) was also demonstrated to be suitable. Moreover, a 37% reduction in odour generation was observed in co-composting of WOP compared to single composting of OFMSW.

In membrane bioreactors applied to wastewater treatment, fouling is typically a complex function of sludge characteristics. A pilot-scale tertiary submerged membrane bioreactor (tMBR) was continuously operated for over 200 days to assess the effect of biomass physiological state and environmental stress on process performance. Sludge characteristics were evaluated in terms of suspended solid concentration (MLSS and MLVSS), apparent viscosity, bioflocculation state, filterability, bioactivity, biopolymeric clusters (BPCs) and soluble microbial products. During the initial period of the tMBR start-up, when MLSS was below 3000 mg/L, the biomass was found to be very sensitive to environmental stress by sudden oxygen increase or organic shock loading, resulting in temporary biomass deflocculation and BPC release, and consequently, severe induced membrane fouling. However, at higher MLSS values, low stable biomass growth (0.04 ± 0.002 kg MLVSS/kg COD) was measured, regardless of organic overloading shocks or feeding failures. This period was also characterised by low bioactivity, BPC content and membrane fouling. Statistical analysis showed that BPCs have an important role when compared with other sludge properties as indicators of its fouling potential.