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Abstract The impact of CO 2 leakage from underground storage formations on shallow water resources is a concerning aspect in CO 2 capture and storage (CCS) risk assessment. In Campo de Calatrava region (Spain), natural CO 2 fluxes from the Earth’s mantle interact with shallow aquifers, resulting in significant changes in their physical and chemical properties. The resultant water is slightly acidic (pH 5.9-6.4), oxidizing, and enriched in iron (up to 6.1×10 -4 mol·L -1 ) and other metals usually found at trace concentrations. Thermodynamic calculations reveal that aqueous Fe(III) carbonate complexes play an important role in the persistence of this high concentration of iron and trace metals in solution.

AbstractThe adoption of a bioenergy crop is affected by various factors, including but not limited to the characteristics of farmers, farm economics, market forces, and physical environment. This study develops a spatially explicit agent‐based model for ascertaining the adoption rate of carinata (Brassica carinata) among the farmers in the Little River Experimental Watershed located in the southern state of Georgia in the United States. Each farmer's adoption behavior is modeled using the profitability difference between traditional crop rotations (with and without carinata at different contract prices), the adoption rate of neighboring farmers, and their land allocation decisions from managing a risky portfolio of enterprises. Carinata production in the winter season once every 3 years has no conflict with the most profitable and popular traditional row crop rotations, such as cotton‐cotton‐cotton and cotton‐cotton‐peanut, to a larger extent. The results show that 28% and 85% of farmers in the watershed will adopt carinata after 33 years at a contract price of $13/bushel (bu) under two different assumptions of low (2.5%) and high (5%) initial neighborhood adoption rates. The proportions of land allocated to carinata to the total farmland under field crops are 38% and 85% after 33 years under the same low and high neighborhood adoption rates, respectively. Our results suggest that fixing the appropriate contract price of carinata will bring additional profits to farmers without any significant foreseeable agronomic risks, thereby increasing the adoption rate of carinata at a regional level.

In recent years, sustainability concerns have gained increasing attention among countries and stakeholders worldwide. Towards the transition to sustainable rural development, the rural web framework (RWF) has become a consistent tool. Indicators from the RWF have been used to explore sustainable rural development for decision-making tasks, which improves the social, economic, and environmental performance of rural regions. However, the application of the RWF in studies is on the decline. Furthermore, there is a lack of literature reviews on the importance of the RWF and its relationship with different facets of sustainable development. We conducted a systematic literature review (SLR) (a) to explore how studies have used the RWF in the context of sustainable development and (b) to identify areas for further research. This study found that the RWF has mostly been used in developed countries, with fewer applications in developing countries. We suggest that there should be increased application of the RWF, particularly in developing countries, to broaden the rural web–sustainable development discourse and its relevance. This paper presents several areas where the indicators of the RWF can be applied to illustrate their relevance for policy decisions towards the achievement of the sustainable development goals (SDGs).

Activities involving land use, land-use change,forestry, and agriculture (LUCF) can help reducegreenhouse gas (GHG) concentrations in the atmosphereby increasing biotic carbon storage, by decreasing GHGemissions, and by producing biomass as a substitutefor fossil fuels. Potential activities includereducing rates of deforestation, increasing landdevoted to forest plantations, regenerating secondaryforest, agroforestry, improving the management offorests and agricultural areas; and producing energycrops.Policymakers debating the inclusion of a variety ofLUCF activities in the Clean Development Mechanism(CDM) of the Kyoto Protocol need to consider themagnitude of the carbon contribution these activitiescould make. Existing estimates of the cumulative GHGoffset potential of LUCF activities often take aglobal or regional approach. In contrast, land-usedecisions are usually made at the local level anddepend on many factors including productive capacityof the land, financial considerations of thelandowner, and environmental concerns. Estimates ofGHG offset potential made at a local, or at mostcountry, level that incorporate these factors may belower, as well as more useful for policy analyses,than global or large regional estimates. Whilecountry-level estimates exist for forestry activities,similar estimates utilizing local information need tobe generated for agricultural activities and biofuels,as well as for the cumulative potential of all LUCFactivities in a particular location.

High nutrient discharge from groundwater (GW) into surface water (SW) have multiple undesirable effects on river water quality. With the aim to estimate the impact of anthropic pressures and river–aquifer interactions on nitrate status in SW, this study integrates two hydrological simulation and water quality models. PATRICAL models SW–GW interactions and RREA models streamflow changes due to human activity. The models were applied to the Júcar River Basin District (RBD), where 33% of the aquifers have a concentration above 50 mg NO3−/L. As a result, there is a direct linear correlation between the nitrate concentration in rivers and aquifers (Júcar r2 = 0.9, and Turia r2 = 0.8), since in these Mediterranean basins, the main amount of river flows comes from groundwater discharge. The concentration of nitrates in rivers and GW tends to increase downstream of the district, where artificial surfaces and agriculture are concentrated. The total NO3− load to Júcar RBD rivers was estimated at 10,202 tN/year (239 kg/km2/year), from which 99% is generated by diffuse pollution, and 3378 tN/year (79 kg/km2/year) is discharged into the Mediterranean Sea. Changes in nitrate concentration in the RBD rivers are strongly related to the source of irrigation water, river–aquifer interactions, and flow regulation. The models used in this paper allow the identification of pollution sources, the forecasting of nitrate concentration in surface and groundwater, and the evaluation of the efficiency of measures to prevent water degradation, among other applications.

Darfur farming and pastoralist livelihoods are both adaptations to the environmental variability that characterises the region. This article describes this adaptation and the longer‐term transformation of these specialised livelihoods from the perspective of local communities. Over several decades farmers and herders have experienced a continuous stream of climate, conflict and other shocks, which, combined with wider processes of change, have transformed livelihoods and undermined livelihood institutions. Their well‐rehearsed specialist strategies are now combined with new strategies to cope. These responses help people get by in the short term but risk antagonising not only their specialist strategies but also those of others. A combination of factors has undermined the former integration between farming and pastoralism and their livelihood institutions. Efforts to build resilience in similar contexts must take a long‐term view of livelihood adaptation as a specialisation, and consider the implications of new strategies for the continuity and integration of livelihood specialisations.

In this study, pyrolysis of microalgal remnants was investigated for recovery of energy and nutrients. Chlorella vulgaris biomass was first solvent-extracted for lipid recovery then the remnants were used as the feedstock for fast pyrolysis experiments using a fluidized bed reactor at 500 °C. Yields of bio-oil, biochar, and gas were 53, 31, and 10 wt.%, respectively. Bio-oil from C. vulgaris remnants was a complex mixture of aromatics and straight-chain hydrocarbons, amides, amines, carboxylic acids, phenols, and other compounds with molecular weights ranging from 70 to 1200 Da. Structure and surface topography of the biochar were analyzed. The high inorganic content (potassium, phosphorous, and nitrogen) of the biochar suggests it may be suitable to provide nutrients for crop production. The bio-oil and biochar represented 57% and 36% of the energy content of the microalgae remnant feedstock, respectively.

This work has been developed under the AGROinLOG Project, “Demonstration of innovative integrated biomass logistics centres for the Agro-industry sector in Europe”. An Integrated Biomass Logistics Center (IBLC), is based on the introduction of new production chains into existing agro-industries by using new biomass feedstock. The AGROinLOG Project has dedicated great attention to investigate the potential of cereal chaff as a valuable resource.Chaff is the fine fraction of the thrashing residues, not usually collected. Chaff is made up of glumes, seed husks, rachis and the tinner part of the cereal stems, whole and cracked kernels, as well as weed seeds.Currently there are several mechanical solutions available on the market for chaff recovery, and others are still at prototype stage, but theyare not so common and very often unknown to the farmers.So far, the literature reportsfew cases of chaff collection with the specific purpose of weed seeds removal, but it still lacks specificexperiments on these machinesintentionally used for biomass collection.For this reason, during the Project AGROinLOG a series of large field tests were performed using an independent scientific approach with different kind of chaff harvesting technologiesin France, Sweden and Italy from 2017 to 2019.The present study collects the results of these activities with the aim to fill that gap and provide deeper understanding in the possibility to enhance the current cereal harvesting method, in order to improve the quantity of biomass collected by including the chaff. Proceedings of the 29th European Biomass Conference and Exhibition, 26-29 April 2021, Online, pp. 62-68

Access to reliable and affordable energy is vital for sustainable development. In the off-grid areas of developing countries, decentralized energy solutions have received increasing attention due to their contributions to reducing poverty. However, most of the rural population in many developing countries still has little or no access to modern energy technologies. This paper assesses the factors that determine the successes and failures of decentralized energy solutions based on local harmonized case studies from heterogeneous contexts from Asia, sub-Saharan Africa, and South America. The case studies were analyzed through the coupled lenses of energy transition and the Water–Energy–Food Security (WEF) Nexus. The findings indicate that access to modern decentralized energy solutions has not resulted in complete energy transitions due to various tradeoffs with the other domains of the WEF Nexus. On the other hand, the case studies point at the potential for improvements in food security, incomes, health, the empowerment of women, and resource conservation when synergies between decentralized energy solutions and other components of the WEF Nexus are present.

Abstract Higher resolution rock formation characterization is of paramount priority, amid growing interest in injecting carbon dioxide, CO2, into subsurface rock formations of depeleting/depleted hydrocarbon reservoirs or saline aquifers in order to reduce emissions of greenhouse gases. In this paper, we present a case study for a Mississippian carbonate characterization integrating post-stack seismic attributes, well log porosities, and seismic petrophysical facies classification. We evaluated changes in petrophysical lithofacies and reveal structural facies-controls in the study area. Three cross-plot clusters in a plot of well log porosity and acoustic impedance corroborated a Neural Network petrophysical facies classification, which was based on training and validation utilizing three petrophysically-different wells and three volume seismic attributes, extracted from a time window including the wavelet of the reservoir-top reflection. Reworked lithofacies along small-throw faults has been revealed based on comparing coherency and seismic petrophysical facies. The main objective of this study is to put an emphasis on reservoir characterization that is both optimized for and subsequently benefiting from pilot tertiary CO2 carbon geosequestration in a depleting reservoir and also in the deeper saline aquifer of the Arbuckle Group, south central Kansas. The 3D seismic coherency attribute, we calculated from a window embracing the Mississippian top reflection event, indicated anomalous features that can be interpreted as a change in lithofacies or faulting effect. An Artificial Neural Network (ANN) lithofacies modeling has been used to better understand these subtle features, and also provide petrophysical classes, which will benefit flow-simulation modeling and/or time-lapse seismic monitoring feasibility analysis. This paper emphasizes the need of paying greater attention to small-scale features when embarking upon characterization of a reservoir or saline-aquifer for CO2 based carbon geosequestration.