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Bioplastics are alternatives of conventional petroleum-based plastics. Bioplastics are polymers processed from renewable sources and are biodegradable. This study aims at conducting an environmental impact assessment of the bioprocessing of agricultural wastes into bioplastics compared to petro-plastics using an LCA approach. Bioplastics were produced from potato peels in laboratory. In a biochemical reaction under heating, starch was extracted from peels and glycerin, vinegar and water were added with a range of different ratios, which resulted in producing different samples of bio-based plastics. Nevertheless, the environmental impact of the bioplastics production process was evaluated and compared to petro-plastics. A life cycle analysis of bioplastics produced in laboratory and petro-plastics was conducted. The results are presented in the form of global warming potential, and other environmental impacts including acidification potential, eutrophication potential, freshwater ecotoxicity potential, human toxicity potential, and ozone layer depletion of producing bioplastics are compared to petro-plastics. The results show that the greenhouse gases (GHG) emissions, through the different experiments to produce bioplastics, range between 0.354 and 0.623 kg CO2 eq. per kg bioplastic compared to 2.37 kg CO2 eq. per kg polypropylene as a petro-plastic. The results also showed that there are no significant potential effects for the bioplastics produced from potato peels on different environmental impacts in comparison with poly-β-hydroxybutyric acid and polypropylene. Thus, the bioplastics produced from agricultural wastes can be manufactured in industrial scale to reduce the dependence on petroleum-based plastics. This in turn will mitigate GHG emissions and reduce the negative environmental impacts on climate change.

Atmospheric concentrations of the greenhouse gas nitrous oxide (N(2)O) have increased significantly since pre-industrial times owing to anthropogenic perturbation of the global nitrogen cycle, with animal production being one of the main contributors. Grasslands cover about 20 per cent of the temperate land surface of the Earth and are widely used as pasture. It has been suggested that high animal stocking rates and the resulting elevated nitrogen input increase N(2)O emissions. Internationally agreed methods to upscale the effect of increased livestock numbers on N(2)O emissions are based directly on per capita nitrogen inputs. However, measurements of grassland N(2)O fluxes are often performed over short time periods, with low time resolution and mostly during the growing season. In consequence, our understanding of the daily and seasonal dynamics of grassland N(2)O fluxes remains limited. Here we report year-round N(2)O flux measurements with high and low temporal resolution at ten steppe grassland sites in Inner Mongolia, China. We show that short-lived pulses of N(2)O emission during spring thaw dominate the annual N(2)O budget at our study sites. The N(2)O emission pulses are highest in ungrazed steppe and decrease with increasing stocking rate, suggesting that grazing decreases rather than increases N(2)O emissions. Our results show that the stimulatory effect of higher stocking rates on nitrogen cycling and, hence, on N(2)O emission is more than offset by the effects of a parallel reduction in microbial biomass, inorganic nitrogen production and wintertime water retention. By neglecting these freeze-thaw interactions, existing approaches may have systematically overestimated N(2)O emissions over the last century for semi-arid, cool temperate grasslands by up to 72 per cent.

SummaryThe German government has adopted a law that requires sewage plants to go beyond the recovery of phosphorus from wastewater and to promote recycling. We argue that there is no physical global short‐ or mid‐term phosphorus scarcity. However, we also argue that there are legitimate reasons for policies such as those of Germany, including: precaution as a way to ensure future generations’ long‐term supply security, promotion of technologies for closed‐loop economics in a promising stage of technology development, and decrease in the current supply risk with a new resource pool.

Abstract Rare earth permanent magnets are important components for modern (energy) technologies and are employed to reduce GHG emissions and combat climate change. The process of extracting these minerals from the ore has contentious economic, environmental and social implications. While the environmental impacts of their production have already been analyzed in several studies, the economic and the social perspective is still under-researched. The Social Life Cycle Assessment (S-LCA) approach employed in the present research explores whether there is a difference in social risks for rare earth permanent magnet production from three different rare earth ore production locations and the associated value chains. While one is located completely in China, another is composed of processes in Australia and Malaysia. The third process chain combines processes in the United States and Japan. The Product Social Impact Life Cycle Assessment (PSILCA) 2.0 database is used to assess the social implications. The analysis focuses on value chain actors, a stakeholder group of great interest to businesses but often underrepresented in S-LCA research. The impact categories describing this stakeholder group pertain to issues of social responsibility along the value chain, fair competition and corruption. Overall, the US value chain indicates the lowest level of social risk along the supply chain. However, in order to gain a deeper understanding of the social risks a sectoral and geographical analysis is conducted. Across all three cases, the mineral, fossil fuel and chemical sectors are shown to be problematic.

Alpine grasslands on the Qinghai-Tibetan Plateau are sensitive and vulnerable to climate change and human activities. Climate warming and overgrazing have already caused degradation in a large fraction of alpine grasslands on this plateau. However, it remains unclear how human activities (mainly livestock grazing) regulates vegetation dynamics under climate change. Here, alpine grassland productivity (substituted with the normalized difference vegetation index, NDVI) is hypothesized to vary in a nonlinear trajectory to follow climate fluctuations and human disturbances. With generalized additive mixed modelling (GAMM) and residual-trend (RESTREND) analysis together, both magnitude and direction of climatic (in terms of temperature, precipitation, and radiation) and anthropogenic impacts on NDVI variation were examined across alpine meadows, steppes, and desert-steppes on the Qinghai-Tibetan Plateau. The results revealed that accelerating warming and greening, respectively, took place in 76.2% and 78.8% of alpine grasslands on the Qinghai-Tibetan Plateau. The relative importance of temperature, precipitation, and radiation impacts was comparable, between 20.4% and 24.8%, and combined to explain 66.2% of NDVI variance at the pixel scale. The human influence was strengthening and weakening, respectively, in 15.5% and 14.3% of grassland pixels, being slightly larger than any sole climatic variable across the entire plateau. Anthropogenic and climatic factors can be in opposite ways to affect alpine grasslands, even within the same grassland type, likely regulated by plant community assembly and species functional traits. Therefore, the underlying mechanisms of how plant functional diversity regulates nonlinear ecosystem response to climatic and anthropogenic stresses should be carefully explored in the future.

Abstract Waste disposal is a core issue worldwide. Different researches are being carried out in order to handle waste materials, generated in industrial production and application processes, e.g. paint residue from metal coating in the automobile industry. Often waste is disposed in landfills at substantial economic and environmental cost. Combustion is another way to get rid of possibly hazardous waste. Pulverized fuel combustion is one of the latest combustion technologies. However, pulverized fuel combustion faces severe problems if the waste (fuel) contains components with low melting point. Having a low melting point, it gets difficult to manage and convey the pulverized material to the hot combustion chamber. The melting of fuel causes clogging in the fuel transport nozzle used to convey the material into the combustion chamber. In this work, a new technology for combustion of materials with low melting points is proposed, focusing on apparatus and nozzle design to prevent clogging. For this purpose, different nozzle designs were evaluated by multi-phase CFD simulations. Two sets of nozzle air flow rates were used in four nozzles. Effect of different flow rates and fuel particle size on combustion temperatures are also discussed. It was noted that nozzle air flow rate has a strong influence on the temperature distributions. Small fuel particle sizes result in wider combustion zones while larger particles give longer combustion zones. The results come up with optimized nozzle design and nozzle air flow for transportation of pulverized material with low melting point.

Abstract Continuous bio-methanization of an energy crop, namely the beet silage, was investigated in this laboratory-scale work as mono-substrate, using a mesophilic biogas digester controlled by a fuzzy logic control (FLC) technique and without using any supplementing or buffering agent, despite the low pH of the substrate around 3.80. The temperature, pH, redox potential (ORP), daily biogas production and composition of digester biogas were continuously measured online. During the operation, the hydraulic retention time (HRT) varied between 24.8 and 9 days, as the organic loading rate (OLR) ranged from 2.6 to 4.7 g L −1 d −1 . The average pH, specific gas production rate (spec. GPR) and volumetric gas production rate (vol. GPR) were determined to be 7.12, 0.31 L g VS −1 d −1 and 1.084 L L −1 d −1 , respectively. The average methane (CH 4 ) content of digester biogas was about 56%. The FLC technique, which was developed at HAW Hamburg for anaerobic conversion of acidic energy crops to methane, determined the daily feeding volume (∼ OLR/HRT) for the biogas digester, depending on the feedback from online pH and methane measurements, and on the calculation of the spec. GPR. The spec. GPR was calculated by the corrected daily biogas production. Through online monitoring of pH, biogas production rate and composition, and by use of the FLC technique, the acidic beet silage could continuously be converted to biogas, without using manure or any other kind of buffering or supplementing agent(s). The lab-scale anaerobic biogas digester performed stable and safe, without encountering any problems of instability, as indicated by an adequate amount of buffering capacity, a VFA content below 0.5 g L −1 and a neutral pH range throughout the study.

Abstract The most pressing global challenges have been summarized in the UN Sustainable Development Goals. Given the complex feedbacks and interdependencies among them, fulfilling these goals requires a holistic approach leading to profound transitions. The food-energy-water nexus is often proposed to be one such holistic approach. However, to date no consistent definition of the nexus concept exists, while research interest in the nexus rapidly grows. Therefore, in this paper, the nexus is defined as a concept of systems thinking. A nexus systems thinking test is developed that can be used as a new way of categorizing nexus research. To examine the test's viability and suitability, it is applied to a sample data set of nexus-related research papers. By means of a multi- and mixed methods document analysis it is analyzed if the papers conceptualize the nexus approach as a systems thinking concept. The results show that all papers meet the four system criteria. Different emphasis, however, is put on certain aspects. The nexus systems thinking test proved to be a viable systematic method to investigate if and in which way nexus research incorporates a systems thinking perspective. It does not only offer a new way of categorizing nexus related research, but also allows assessing its quality from a comprehensive nexus perspective. The test thus provides valuable and systematic understanding of a rapidly developing, central research field within sustainability science.

Abstract This paper examines the impact of climate targets which have been adapted to individuals’ behavior based on global political events. As the global climate targets of the Paris Agreement are largely supported by society, we investigate the potential of these targets to lead to personal and social norms concerning individual contributions to the Paris Agreement´s climate goals. We assume that these norms mediate the influence of personal involvement in the Paris agreement and of environmental values on greenhouse gas avoiding decisions. Also, we expect that these norms predict greenhouse gas avoiding behavior, rather than norms related to climate change. The research is based on a laboratory study with students conducted in December 2017 in Germany (n = 226). The main results show for the students surveyed in the research that norms in favor of contribution to the Paris Agreement substantially influence objective carbon offsetting, as well as consumption of local food and green electricity; and these norms partially mediate the influence of personal involvement in the Paris Agreement and of environmental values on decision-making.