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Hydrogen, as a maritime fuel, is one of the solutions that will assist the shipping sector in addressing the challenges regarding decarbonization, taking into consideration the targets set for 2030 and 2050. The extensive utilization of hydrogen requires massive production of green hydrogen and the development of proper infrastructure to support a sustainable supply chain. An alternative solution is based on the on-board production of hydrogen, where production units are installed on-board the vessel. Along these lines, the HYMAR project aims to test the utilization of a hydrogen production unit for on-board use. The article deals with the use of hydrogen as a fuel for internal combustion engines, taking into consideration reports from literature and the preliminary results of the HYMAR project, focusing on the environmental impact and the reduction in emissions. Experimental investigation on a marine auxiliary engine for power generation, under the HYMAR project, leads to promising results regarding the environmental footprint of the internal combustion engine when hydrogen is added in the fuel mix with increasing percentages.

Microbial electrochemical technologies (METs) constitute the core of a number of emerging technologies with a high potential for treating urban wastewater due to a fascinating reaction mechanism—the electron transfer between bacteria and electrodes to transform metabolism into electrical current. In the current work, we focus on the model electroactive microorganism Geobacter sulfurreducens to explore both the design of new start-up procedures and electrochemical operations. Our chemostat-grown plug and play cells, were able to reduce the start-up period by 20-fold while enhancing chemical oxygen demand (COD) removal by more than 6-fold during this period. Moreover, a filter-press based bioreactor was successfully tested for both acetate-supplemented synthetic wastewater and real urban wastewater. This proof-of-concept pre-pilot treatment included a microbial electrolysis cell (MEC) followed in time by a microbial fuel cell (MFC) to finally generate electrical current of ca. 20 A·m−2 with a power of 10 W·m−2 while removing 42 g COD day−1·m−2. The effective removal of acetate suggests a potential use of this modular technology for treating acetogenic wastewater where Geobacter sulfurreducens outcompetes other organisms.

The prevailing need for a more sustainable management of natural resources depends not only on the decisions made by governments and the will of the population, but also on the knowledge of the role of energy in our society and the relevance of preserving natural resources. In this sense, critical work is being done to instill key concepts—such as the circular economy and sustainable energy—in higher education institutions. In this way, it is expected that future professionals and managers will be aware of the importance of energy optimization, and will learn a series of computational methods that can support the decision-making process. In the context of higher education, this paper reviews the main trends and challenges related to the concepts of circular economy and sustainable energy. Besides, we analyze the role of simulation and serious games as a learning tool for the aforementioned concepts. Finally, the paper provides insights and discusses open research opportunities regarding the use of these computational tools to incorporate circular economy concepts in higher education degrees. Our findings show that, while efforts are being made to include these concepts in current programs, there is still much work to be done, especially from the point of view of university management. In addition, the analysis of the teaching methodologies analyzed shows that, although their implementation has been successful in favoring the active learning of students, their use (especially that of serious games) is not yet widespread.

In this study, our aim was to explore the potential energy savings obtainable from the recycling of 1 tonne of Construction and Demolition Waste (C&DW) generated in the Metropolitan City of Naples. The main fraction composing the functional unit are mixed C&DW, soil and stones, concrete, iron, steel and aluminium. The results evidence that the recycling option for the C&DW is better than landfilling as well as that the production of recycled aggregates is environmentally sustainable since the induced energy and environmental impacts are lower than the avoided energy and environmental impacts in the life cycle of recycled aggregates. This LCA study shows that the transition to the Circular Economy offers many opportunities for improving the energy and environmental performances of the construction sector in the life cycle of construction materials by means of internal recycling strategies (recycling C&DW into recycled aggregates, recycled steel, iron and aluminum) as well as external recycling by using input of other sectors (agri-food by-products) for the manufacturing of construction materials. In this way, the C&D sector also contributes to realizing the energy and bioeconomy transition by disentangling itself from fossil fuel dependence.

The large potential for waste resource and heat recovery in industry has been motivating research toward increasing efficiency. Process integration methods have proven to be effective tools in improving industrial sites while decreasing their resource and energy consumption; however, location aspects and their impact are generally overlooked. This paper presents a method based on process integration, which considers the location of plants. The impact of the locations is included within the mixed integer linear programming framework in the form of heat losses, temperature and pressure drop, and piping cost. The objective function is selected as minimisation of the total cost of the system excluding piping cost and ϵ -constraints are applied on the piping cost to systematically generate multiple solutions. The method is applied to a case study with industrial plants from different sectors. First, the interaction between two plants and their utility integration are illustrated, depending on the piping cost limit which results in the heat pump and boiler on one site being gradually replaced by excess heat recovered from the other plant. Then, the optimisation of the whole system is carried out, as a large-scale application. At low piping cost allowances, heat is shared through high pressure steam in above-ground pipes, while at higher piping cost limits the system switches toward lower pressure steam sharing in underground pipes. Compared to the business-as-usual operation of the sites, the optimal solution obtained with the proposed method leads to 20% reduction in the overall cost of the system, including the piping cost. Further reduction in the cost is possible using a state of the art method but the technical and economic feasibility is not guaranteed. Thus, the present work provides a tool to find optimal industrial symbiosis solutions under different investment limits on the infrastructure between plants.

The yeast Yarrowia lipolytica is an industrially relevant microorganism, which is able to convert low-value wastes into different high-value, bio-based products, such as enzymes, lipids, and other important metabolites. Waste cooking oil (WCO) represents one of the main streams generated in the food supply chain, especially from the domestic sector. The need to avoid its incorrect disposal makes this waste a resource for developing bioprocesses in the perspective of a circular bioeconomy. To this end, the strain Y. lipolytica W29 was used as a platform for the simultaneous production of intracellular lipids and extracellular lipases. Three different minimal media conditions with different pH controls were utilized in a small-scale (50 mL final volume) screening strategy, and the best condition was tested for an up-scaling procedure in higher volumes (800 mL) by selecting the best-performing possibility. The tested media were constituted by YNB media with high nitrogen restriction (1 g L−1 (NH4)2SO4) and different carbon sources (3% w v−1 glucose and 10% v v−1 WCO) with different levels of pH controls. Lipase production and SCO content were analyzed. A direct correlation was found between decreasing FFA availability in the media and increasing SCO levels and lipase activity. The simultaneous production of extracellular lipase (1.164 ± 0.025 U mL−1) and intracellular single-cell oil accumulation by Y. lipolytica W29 growing on WCO demonstrates the potential and the industrial relevance of this biorefinery model.

Liquid biowaste represents more than 98% of the total municipal waste streams on wet basis and 4–5% on dry basis. Recent attention has been focused on how to manage it optimally, and several novel technologies are being developed to valorize it. Among the developing alternatives is a technology that operates continuously by integrating a hydrothermal reactor, a gasifier and condenser to recover hydrochar using any produced gases to power the system. This study introduces the “3-step evolution model” in order to simulate the hydrothermal reactor. The model has been developed in a MATLAB/Cantera environment and calculates the outputs as the products of a series of sub-stoichiometric char-gas reactions. Experiments with chicken manure slurry as feedstock were implemented for the validation of the model. Treatment of 32.16 kg/h of chicken manure produces 4.57 kg/h of hydrochar and 3.45 kg/h of syngas. The 3-step evolution model simulated the correct ratio of solid-to-gas, 57–43% (excluding the liquids). The experimentally measured carbon dioxide is used as a correction factor to calculate all the other parameters that cannot be assessed during the continuous operation of the hydrothermal reactor. The simulated compositions for carbon dioxide and methane were 94–96% and 0.5–0.8%, respectively. The values were close to the experimental results that ranged from 94.7% to 95.6% for the carbon dioxide and from 0.5% to 0.7% for the methane. The model predicts that higher temperatures of operation would increase carbon monoxide composition from 4–5% up to 7–8%.