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The hygrothermal behaviour of an internally insulated historic wall is still hard to predict, mainly because the physical characteristics of the materials composing the historic wall are unknown. In this study, the hygrothermal assessment of an internally thermal insulated masonry wall of an historic palace located in Ferrara, in Italy, is shown. In situ non-destructive monitoring method is combined with a hygrothermal simulation tool, aiming to better analyse and discuss future refurbishment scenarios. In this context, the original U-value of the wall (not refurbished) is decreased from 1.44 W/m2K to 0.26 W/m2K (10 cm stone wool). Under the site specific conditions of this wall, not reached by the sun or rain, it was verified that even in the absence of vapour barrier, no frost damage is likely to occur and the condensation risk is very limited. Authors proposed further discussion based on simulation. The results showed that the introduction of a second gypsum board to the studied technology compensated such absence, while the reduction of the insulation material thickness provides a reduction of RH peaks in the interstitial area by 1%; this second solution proved to be more efficient, providing a 3% RH reduction and the avoidance of further thermal losses.

The European Union’s energy policy favors increasing the share of renewable energy in total energy production. In this context, the co-digestion of various waste streams seems an interesting option. This study aimed to determine the effect of selected pretreatment methods on the efficiency and kinetics of the co-digestion process of poultry manure with sewage sludge and organic waste. This research was carried out in four stages: (1) the selection of the third component of the co-digestion mixture; (2) the determination of the most favorable inoculum-to-substrate ratio for the co-digestion mixture; (3) the selection of the most favorable pretreatment parameters based on changes in volatile fatty acids, ammonium nitrogen, extracellular polymers substances (EPS) and non-purgeable organic carbon (NPOC); and (4) the evaluation of anaerobic co-digestion based on the result of the BMP tests and kinetic studies. All the pretreatment methods increased the degree of organic matter liquefaction as measured by the NPOC changes. Waste with a high fat content showed the highest methane potential. The addition of grease trap sludge to feedstock increased methane yield from 320 mL/g VSadd to 340 mL/g VSadd. An optimal inoculum-to-substrate ratio was 2. The pretreatment methods, especially the thermochemical one with NaOH, increased the liquefaction of organic matter and the methane yield, which increased from 340 mL/g VSadd to 501 mL/g VSadd (trial with 4.5 g/L NaoH).

The large potential for waste resource and heat recovery in industry has been motivating research toward increasing efficiency. Process integration methods have proven to be effective tools in improving industrial sites while decreasing their resource and energy consumption; however, location aspects and their impact are generally overlooked. This paper presents a method based on process integration, which considers the location of plants. The impact of the locations is included within the mixed integer linear programming framework in the form of heat losses, temperature and pressure drop, and piping cost. The objective function is selected as minimisation of the total cost of the system excluding piping cost and ϵ -constraints are applied on the piping cost to systematically generate multiple solutions. The method is applied to a case study with industrial plants from different sectors. First, the interaction between two plants and their utility integration are illustrated, depending on the piping cost limit which results in the heat pump and boiler on one site being gradually replaced by excess heat recovered from the other plant. Then, the optimisation of the whole system is carried out, as a large-scale application. At low piping cost allowances, heat is shared through high pressure steam in above-ground pipes, while at higher piping cost limits the system switches toward lower pressure steam sharing in underground pipes. Compared to the business-as-usual operation of the sites, the optimal solution obtained with the proposed method leads to 20% reduction in the overall cost of the system, including the piping cost. Further reduction in the cost is possible using a state of the art method but the technical and economic feasibility is not guaranteed. Thus, the present work provides a tool to find optimal industrial symbiosis solutions under different investment limits on the infrastructure between plants.

In this study, uncertainty and sensitivity analyses were performed with MELCOR 2.2.18 to study the hydrogen generation (figure-of-merit (FoM)) during the in-vessel phase of a severe accident in a light water reactor. The focus of this work was laid on a large generation-III pressurized water reactor (PWR) and a double-ended hot leg (HL) large break loss of coolant accident (LB-LOCA) without a safety injection (SI). The FPT-1 Phebus integral experiment emulating LOCA was studied, where the experiment outcomes were applied for the plant scale modelling. The best estimate calculations were supplemented with an uncertainty analysis (UA) based on 400 input-decks and Latin hypercube sampling (LHS). Additionally, the sensitivity analysis (SA) utilizing the linear regression and linear and rank correlation coefficients was performed. The study was prepared with a new open-source MELCOR sensitivity and uncertainty tool (MelSUA), which was supplemented with this work. The FPT-1 best-estimate model results were within the 10% experimental uncertainty band for the final FoM. It was shown that the hydrogen generation uncertainties in PWR were similar to the FPT-1, with the 95% percentile being covered inside a ~50% band and the 50% percentile inside a ~25% band around the FoM median. Two different power profiles for PWR were compared, indicating its impact on the uncertainty but also on the sensitivity results. Despite a similar setup, different uncertainty parameters impacted FoM, showing the difference between scales but also a significant impact of boundary conditions on the sensitivity analysis.

Hydrogen as a carbon-free fuel is commonly expected to play a major role in future energy supply, e.g., as an admixture gas in natural gas grids. Which impacts on residential and commercial gas appliances can be expected due to the significantly different physical and chemical properties of hydrogen-enriched natural gas? This paper analyses and discusses blends of hydrogen and natural gas from the perspective of combustion science. The admixture of hydrogen into natural gas changes the properties of the fuel gas. Depending on the combustion system, burner design and other boundary conditions, these changes may cause higher combustion temperatures and laminar combustion velocities, while changing flame positions and shapes are also to be expected. For appliances that are designed for natural gas, these effects may cause risk of flashback, reduced operational safety, material deterioration, higher nitrogen oxides emissions (NOx), and efficiency losses. Theoretical considerations and first measurements indicate that the effects of hydrogen admixture on combustion temperatures and the laminar combustion velocities are often largely mitigated by a shift towards higher air excess ratios in the absence of combustion control systems, but also that common combustion control technologies may be unable to react properly to the presence of hydrogen in the fuel.

The increasing demand for energy and commodities has led to escalating greenhouse gas emissions, the chief of which is represented by carbon dioxide (CO2). Blue hydrogen (H2), a low-carbon hydrogen produced from natural gas with carbon capture technologies applied, has been suggested as a possible alternative to fossil fuels in processes with hard-to-abate emission sources, including refining, chemical, petrochemical and transport sectors. Due to the recent international directives aimed to combat climate change, even existing hydrogen plants should be retrofitted with carbon capture units. To optimize the process economics of such retrofit, it has been proposed to remove CO2 from the pressure swing adsorption (PSA) tail gas to exploit the relatively high CO2 concentration. This study aimed to design and numerically investigate a vacuum pressure swing adsorption (VPSA) process capable of capturing CO2 from the PSA tail gas of an industrial steam methane reforming (SMR)-based hydrogen plant using NaX zeolite adsorbent. The effect of operating conditions, such as purge-to-feed ratio and desorption pressure, were evaluated in relation to CO2 purity, CO2 recovery, bed productivity and specific energy consumption. We found that conventional cycle configurations, namely a 2-bed, 4-step Skarstrom cycle and a 2-bed, 6-step modified Skarstrom cycle with pressure equalization, were able to concentrate CO2 to a purity greater than 95% with a CO2 recovery of around 77% and 90%, respectively. Therefore, the latter configuration could serve as an efficient process to decarbonize existing hydrogen plants and produce blue H2.