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The purpose of this study was to investigate the influence of increasing sulfate concentrations on chromium removal, to evaluate the effect of the presence of Cr(VI) on sulfate removal by Streptomyces sp. MC1 and to analyze the differential protein expression profile in the presence of this metal for the identification of proteins repressed or overexpressed. In the presence of Cr(VI) but in the absence of sulfate ions, bacterial growth was negligible, showing the Cr(VI) toxicity for this bacterium. However, the sulfate presence stimulated bacterium growth and Cr(VI) removal, regardless of its concentrations. Streptomyces sp. MC1 showed ability to remove chromium and sulfate simultaneously. Also, the sulfate presence favored the decrease of total chromium concentration from supernatants reaching a decrease of 50% at 48 h. In presence of chromium, seven proteins were down‐expressed and showed homology to proteins involved in protein biosynthesis, energy production and free radicals detoxification while two proteins involved in oxidation‐reduction processes identified as dihydrolipoamide dehydrogenase and S‐adenosyl‐l‐methionine synthase were overexpressed.

Purpose This study aims to consider environmental sustainability, a global challenge under the preview of sustainable development goals, highlighting the significance of knowledge economy in attaining sustainable aggregate demand behavior globally. For this purpose, 155 countries that have data available from 1995 to 2021 were selected. The purpose of selecting these countries is to test the global responsibility of the knowledge economy to attain environmental sustainability. Design/methodology/approach Results are estimated with the help of panel quantile regression. The empirical existence of aggregate demand-based environmental Kuznets curve (EKC) was tested using non-linear tests. Moreover, principal component analysis has been incorporated to construct the knowledge economy index. Findings U-shaped aggregate demand-based EKC at global level is validated. However, environmental deterioration increases with an additional escalation after US$497.945m in aggregate demand. As a determinant, the knowledge economy is reducing CO2 emissions. The knowledge economy has played a significant role in global responsibility, shifting the EKC downward and extending the CO2 reduction phase for every selected country. Further, urbanization, energy intensity, financial development and trade openness significantly deteriorate the environmental quality. Originality/value This study contains the empirical existence of aggregate demand-based EKC. The role of the knowledge economy is examined through an index which is calculated by using four pillars of the knowledge economy (technology, innovations, education and institutions). This study is based on a combined panel of all the countries for which the data was available.

Paper mill sludge (PMS) is a residual biomass that is generated at paper mills in large quantities. Currently, PMS is commonly disposed in landfills, which causes environmental issues through chemical leaching and greenhouse gas production. In this research, we are exploring the potential of fast pyrolysis process for converting PMS into useful bio-oil and biochar products. We demonstrate that by subjecting PMS to a combination of acid hydrolysis and torrefaction pre-treatment processes it is possible to alter the physicochemical properties and composition of the feedstock material. Fast pyrolysis of pretreated PMS produced bio-oil with significantly higher selectivity to levoglucosenone and significantly reduced the amount of ketone, aldehyde, and organic acid components. Pretreatment of PMS with combined 4% mass fraction phosphoric acid hydrolysis and 220 °C torrefaction processed prior to fast pyrolysis resulted in a 17 times increase of relative selectivity towards levoglucosenone in bio-oil product along with a reduction of acids, ketones, and aldehydes combined from 21 % to 11 %. Biochar, produced in higher yield, has characteristics that potentially make the solid byproduct ideal for soil amendment agent or sorbent material. This work reveals a promising process system to convert PMS waste into useful bio-based products. More in-depth research is required to gather more data information for assessing the economic and sustainability aspects of the process.

This paper develops a strategy for the continuing and improved supply of woodfuels to urban and industrial consumers in Sub-Sahara Africa. It argues that continued use of these fuels is not only a necessity, but is also in the best economic interest of most of the countries in this region. It shows that intensified and more orderly utilization of woodfuels can help to enhance, rather than impinge upon environmental parameters. Some examples are provided that illustrate how such strategies can be put into practice.

This paper presents experimental results of the impact of CO(2) co-feed on a gasification/pyrolysis process for various feedstocks (biomass, coal, and municipal solid waste (MSW)). Various feedstocks were thermo-gravimetrically characterized under various atmospheric conditions and heating rates. A substantial amount of char burn out was identified in the presence of CO(2) via a series of thermo-gravimetric analysis tests, which enabled high conversion of final mass (approximately 99%) to be achieved. The impact of CO(2) co-feed on the volatilization regime during the pyrolysis/gasification process was not apparent at a heating rate of 10-40 degrees C min(-1). However, the impact of CO(2) on the volatilization regime at a fast heating rate (950 degrees C min(-1)) was substantial. For example, significant enhancement in the generation of CO, by a factor of approximately 2, was observed in the presence of CO(2). The generation of major chemical species, such as CH(4) and C(2)H(4), were enhanced, but this was not as apparent as in the case with CO. In addition, introducing CO(2) to the pyrolysis/gasification process enabled the amount of condensable liquid hydrocarbons, such as tar (approximately 30-40%) to be significantly reduced in the presence of CO(2), in that injecting CO(2) into the pyrolysis/gasification process expedites cracking the volatilized chemical species. Experimental work confirmed that biomass and MSW could be feasible and desirable feedstocks for the pyrolysis/gasification process as these feedstocks can be easily treated compared to coal. To extend this understanding to a more practical level, various feedstocks were tested in a tubular reactor and drop tube reactor under various experimental conditions.

Bioenergy is considered a sustainable substitute to fossil-fuel resources and the development of a prudent combination of renewable and innovative conversion technologies are essential for the valorization and effective conversion of biowaste to value-added commodities. Here, a negative pressure-induced carbonization process was proposed for the valorization of lignin-enriched biowaste precursor to bio-oil and environmental materials (biochar) at various temperatures. The high heating values (HHV) of the as-prepared biochars from the lignin enriched precursor under negative pressure (low-medium vacuum) were within 25.9-31.5 MJ/kg, which matched satisfactorily to the commercial charcoal. Whereas, the bio-oils produced from the lignin enriched precursor under vacuum conditions was a blend of complex aromatic and straight-chain hydro-carbons, including aldehyde, ketone, phenol, and furans, exhibiting ability as potential heating-oil with HHV within 21.2-28.2 MJ/kg. Moreover, the biochars produced under vacuum environments at higher temperature showed greater stability (22.5-35.9%) than those produced under N2 atmosphere.

A promising route to transition wastewater treatment facilities (WWTFs) from energy-consuming to net energy-positive is to retrofit existing facilities with process modifications, residual biosolid upcycling, and effluent thermal energy recovery. This study assesses the economics and life cycle environmental impacts of three proposed retrofits of WWTFs that consider thermochemical conversion technologies, namely, hydrothermal liquefaction, slow pyrolysis, and fast pyrolysis, along with advanced bioreactors. The results are in turn compared to the reference design, showing the retrofitting design with hydrothermal liquefaction, and an up-flow anaerobic sludge blanket has the highest net present value (NPV) of $177.36MM over a 20-year plant lifetime despite 15% higher annual production costs than the reference design. According to the ReCiPe method, chlorination is identified as the major contributor for most impact categories in all cases. There are several uncertainties embedded in the techno-economic analysis and life cycle assessment, including the discount rate, capital investment, sewer rate, and prices of main products; among which, the price of biochar presents the widest variation from $50 to $1900/t. Sensitivity analyses reveal that the variation of discount rates causes the most significant changes in NPVs. The impact of the biochar price is more pronounced in the slow pyrolysis-based pathway compared to the fast pyrolysis since biochar is the main product of slow pyrolysis.

Abstract Bamboo has been considered a potential feedstock of energy for the future. It can be subjected to the pyrolysis for biofuels production. The thermogravimetric analysis (TGA) combined with differential thermogravimetric analysis (DTG) for bamboo was carried out prior to pyrolysis. The thermal degradation of bamboo was mainly between 230 and 420 °C. The conventional pyrolysis of bamboo was investigated in a bubbling fluidized-bed reactor using silica sand. The product distribution and composition of pyrolysis bio-oil were dependent on biomass component and operating conditions such as pyrolysis temperature, fluidization velocity, and particle size of biomass. The fractional catalytic pyrolysis of bamboo was also studied to upgrade the pyrolysis vapor, using HZSM-5 and red mud. The highest yield of bio-oil was 54.03 wt% compared to 49.14 wt% and 50.34 wt% of HZSM-5 and red mud catalyst, respectively. In the red mud catalytic pyrolysis, the oxygen content was rejected from pyrolysis vapor mostly via decarboxylation to produce more CO2 than CO; in contrast, for the HZSM-5 catalytic pyrolysis, the production of CO through decarbonylation was more favored than CO2. The main composition of catalytic pyrolysis bio-oil was 4-vinylphenol, which was employed as a raw material source to synthesize valuable material for energy storage.

Trace elements can have profound adverse effects on the health of people burning coal in homes or living near coal deposits, coal mines, and coal-burning power plants. Trace elements such as arsenic emitted from coal-burning power plants in Europe and Asia have been shown to cause severe health problems. Perhaps the most widespread health problems are caused by domestic coal combustion in developing countries where millions of people suffer from fluorosis and thousands from arsenism. Better knowledge of coal quality characteristics may help to reduce some of these health problems. For example, information on concentrations and distributions of potentially toxic elements in coal may help delineate areas of a coal deposit to be avoided. Information on the modes of occurrence of these elements and the textural relations of the minerals in coal may help to predict the behavior of the potentially toxic trace metals during coal cleaning, combustion, weathering, and leaching.