• Energy Research
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AbstractThe presented synthesis of the title compounds (II), (IV), (VI) and (VIII) is extremely simple and highly efficient without the use of any chromatographic purification.

This paper presents an experimental study of indoor thermal environment near a full-scale glass facade with different types of shading devices under varying climatic conditions in winter. Interior glazing and shading temperature, operative temperature and radiant temperature asymmetry were measured for facade sections with roller shades and venetian blinds at different positions. Interior glass surface temperatures can be high during sunny days with low outdoor temperature. Shading systems significantly improved operative temperature and radiant temperature asymmetry during cold sunny days, depending on their properties and tilt angle. During cloudy days the impact was smaller, however the shading layers could still decrease the amount of heat loss through the facade. A transient building thermal model, which also calculates indoor environmental indices under the presence of solar radiation, was developed and compared with the experimental measurements. Part II of this paper uses this validated model with a transient, two-node thermal comfort model (including transmitted solar radiation) for assessment of indoor environmental conditions with different building envelope and shading properties, facade location and orientation.

Abstract Recharging infrastructure (RI) deployment plays a vital role in improving the public recharging availability for transport electrification. Decarbonizing transportation using low-emission electricity requires massive RI network. Even though the consumers are reluctant to purchase electric vehicles (EVs) until RIs are sufficiently placed, the investors are not willing to invest in RIs due to recharging demand uncertainties. Therefore, a scientific planning framework is needed to ensure the sustainable deployment of EV-RIs in complex networks. In this study, a lifecycle thinking-based multi-period infrastructure-planning framework is proposed to develop sustainable public EV-RIs in an urban context. This framework consists of a temporal model to find the dynamic EV-RI demands, a stochastic model to obtain travel distances, and a multi-objective optimization model to select the best desirable capacities and locations for potential EV-RIs. A case study of a typical medium-scale municipality in Canada was assessed using the proposed framework and validated using conventional infrastructure planning scenarios. The geo-processing data, regional travel behaviors, and recharging characteristics were used as model inputs. The results of the case study showed that the proposed framework can be used to estimate multi-period public recharging demands, minimize lifecycle costs, maximize service coverage and infrastructure utilization, and ensure reasonable paybacks compared to conventional planning approaches. Moreover, this framework can be used to compare different investment assistances, which are required in the early stages of the RI deployment process to encourage investors. Furthermore, government and private institutions can use this framework to identify recharging demands, permitting, and developing RIs in the long-run.

Abstract The residential sector accounts for most of energy-consumption in developing countries in the form of traditional energy. The use of commercial energy is nominal and confined mostly to urban areas where fuelwood is already monetized. A model, based on an end-use/process analysis approach, is developed on a spreadsheet, which is capable of simulating scenarios to address issues of increasing traditional energy-demand caused by population growth, sustainable supply capacity of the existing energy resources, potential for development of new and renewable energy resources, technology. This paper is divided into two parts: general energy issues and the modelling approach, and the application of this approach to Nepal in the context of fuelwood-supply sustainability.

Abstract In Canada, space heating accounts for the largest proportion of energy consumption in residential buildings. Therefore, accurately predicting the heating demand and interior temperature of a residential building plays a vital role in estimating the building’s total energy consumption with the consideration of thermal comfort. The prediction results obtained through different models could be used to develop predictive controllers to achieve peak shifting as well as to provide utility providers with valuable information for electric power distribution. Common methods to predict heating demand mainly include physical models and statistical methods. This study used two physical models (i.e. TRNSYS model and TRNSYS-CONTAM model) and one statistical model using supervised machine learning algorithm to predict the heating demand as well as the indoor temperature of a residential building, located in Quebec, Canada. Results show that TRNSYS-CONTAM model has higher accuracy than TRNSYS model no matter in terms of interior air temperature or heating demand prediction, while the statistical model shows better interior air temperature prediction result than physical models.

Abstract Communication between vehicles and road infrastructure can enable more efficient use of the road network and hence reduce congestion in urban areas. This improvement can be enhanced by distributed control due to its lighter computational load and higher reliability. Despite favourable impacts on traffic, little is known about the effects of such systems on near-road air quality. In this study, an End-To-End (E2E) dynamic distributed routing algorithm in Connected and Automated Vehicles (CAVs) was applied in downtown Toronto, to identify whether benefits to network throughput were associated with lower near-road NO2 concentrations. We observe significant reductions in the emissions of Greenhouse Gases (GHGs) with increased penetration of CAVs. Nonetheless, at times, the emissions of nitrogen oxides (NOx) increased with higher CAVs. Besides, a higher frequency and severity of NO2 hot-spots were observed under a 100% CAV scenario. Impacts of the proposed system on electric energy consumption in a full electric vehicle network were also investigated, indicating that the addition of CAVs that are electric did not contribute to high energy savings. We propose that such new transformative technologies in transportation should be designed with air pollution and public health goals.

Abstract Conversion of carbon contained in the solid residues (tars + biochar) derived from urban biomass gasification named herein TC would allow enhancing the yield of carbon species (CO/CO2) in synthetic gas. For this purpose, three low cost materials have been tested as possible catalysts: iron species (reduced Fe), bone meal (BM), and ashes (ash) recovered from biochar complete oxidation. The parametric study used the following as variables: air GHSV, onset of reaction temperature, reaction time to optimize CO/CO2 molar ratio and tar content in the produced gas. Results showed an autocatalytic effect of biochar leading to the catalytic conversion of approximately 78% of tars by the native metals contained in TC. The catalytic effect was further enhanced by adding Fe, BM, and extra ash. Addition of Fe catalyst resulted in significant heat generation (temperature increase of ca. 500 °C) and a twofold decrease in reaction time to consume all the carbon. Use of ash and BM as catalysts exhibit heat generation comparable to Fe, along with an improved reaction time, complete tars conversion and a CO/CO2 molar ratio to above 1.3 in the produced gas.

Abstract This paper gives an experimental investigation of the effect of climatic conditions on the performance and degradation of crystalline silicon photovoltaic modules under Saharan environment in Adrar region in the south of Algeria. The first part of this study is focused on the analysis and assessment of UDTS 50 PV modules degradation after a long term outdoor exposure to these conditions (more than 12 years). The visual inspection of 62 PV modules has allowed to observe and determine the degradation modes such as, EVA discoloration, delamination, busbar corrosion, cracking of solar cell, glass breakage, AR coating and solder bond. The degradation evaluation of three modules with different defects was also performed, using (I-V/P-V) characteristics and the degradation rates of the parameters (Pmax, Imp, Vmp, Isc, Voc, FF) at Standard test conditions (STC) in order to compare with the nominal data delivered by the manufacturer of photovoltaic panels. Finally, the combination of the partial shading effect and the presence of EVA browning defect was examined to assess the changes in I-V and P-V curves caused by the drop in electrical parameters.