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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: orcid Franziska Schöniger;
    Franziska Schöniger
    ORCID
    Harvested from ORCID Public Data File

    Franziska Schöniger in OpenAIRE
    orcid Philipp Mascherbauer;
    Philipp Mascherbauer
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    Philipp Mascherbauer in OpenAIRE
    orcid Gustav Resch;
    Gustav Resch
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    Gustav Resch in OpenAIRE
    orcid Lukas Kranzl;
    Lukas Kranzl
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    Harvested from ORCID Public Data File

    Lukas Kranzl in OpenAIRE
    +1 Authors

    AbstractDecarbonising the energy system requires high shares of variable renewable generation and sector coupling like power to heat. In addition to heat supply, heat pumps can be used in future energy systems to provide flexibility to the electricity system by using the thermal storage potential of the building stock and buffer tanks to shift electricity demand to hours of high renewable electricity production. Bridging the gap between two methodological approaches, we coupled a detailed building technology operation model and the open-source energy system model Balmorel to evaluate the flexibility potential that decentral heat pumps can provide to the electricity system. Austria in the year 2030 serves as an example of a 100% renewable-based electricity system (at an annual national balance). Results show that system benefits from heat pump flexibility are relatively limited in extent and concentrated on short-term flexibility. Flexible heat pumps reduce system cost, CO2 emissions, and photovoltaics and wind curtailment in all scenarios. The amount of electricity shifted in the assessed standard flexibility scenario is 194 GWhel and accounts for about 20% of the available flexible heat pump electricity demand. A comparison of different modelling approaches and a deterministic sensitivity analysis of key input parameters complement the modelling. The most important input parameters impacting heat pump flexibility are the flexible capacity (determined by installed capacity and share of control), shifting time limitations, and cost assumptions for the flexibility provided. Heat pump flexibility contributes more to increasing low residual loads (up to 22% in the assessed scenarios) than decreasing residual load peaks. Wind power integration benefits more from heat pump flexibility than photovoltaics because of the temporal correlation between heat demand and wind generation.

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    Energy Efficiency
    Article . 2024 . Peer-reviewed
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      Energy Efficiency
      Article . 2024 . Peer-reviewed
      License: CC BY
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    Authors: orcid Thomas Peprah Agyekum;
    Thomas Peprah Agyekum
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    Thomas Peprah Agyekum in OpenAIRE
    orcid John Arko-Mensah;
    John Arko-Mensah
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    John Arko-Mensah in OpenAIRE
    orcid bw Paul Kingsley Botwe;
    Paul Kingsley Botwe
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    Paul Kingsley Botwe in OpenAIRE
    Jonathan Nartey Hogarh; +6 Authors

    Abstract Background Malaria remains one of the most devastating diseases globally, and the control of mosquitoes as the vector is mainly dependent on chemical insecticides. Elevated temperatures associated with future warmer climates could affect mosquitoes' metabolic enzyme expression and increase insecticide resistance, making vector control difficult. Understanding how mosquito rearing temperatures influence their susceptibility to insecticide and expression of metabolic enzymes could aid in the development of novel tools and strategies to control mosquitoes in a future warmer climate. This study evaluated the effects of temperature on the susceptibility of Anopheles gambiae sensu lato (s.l.) mosquitoes to pyrethroids and their expression of metabolic enzymes. Methods Anopheles gambiae s.l. eggs obtained from laboratory-established colonies were reared under eight temperature regimes (25, 28, 30, 32, 34, 36, 38, and 40 °C). Upon adult emergence, 3- to 5-day-old female non-blood-fed mosquitoes were used for susceptibility tests following the World Health Organization (WHO) bioassay protocol. Batches of 20–25 mosquitoes from each temperature regime (25–34 °C) were exposed to two pyrethroid insecticides (0.75% permethrin and 0.05% deltamethrin). In addition, the levels of four metabolic enzymes (α-esterase, β-esterase, glutathione S-transferase [GST], and mixed-function oxidase [MFO]) were examined in mosquitoes that were not exposed and those that were exposed to pyrethroids. Results Mortality in An. gambiae s.l. mosquitoes exposed to deltamethrin and permethrin decreased at temperatures above 28 °C. In addition, mosquitoes reared at higher temperatures were more resistant and had more elevated enzyme levels than those raised at low temperatures. Overall, mosquitoes that survived after being exposed to pyrethroids had higher levels of metabolic enzymes than those that were not exposed to pyrethroids. Conclusions This study provides evidence that elevated temperatures decreased An. gambiae s.l. mosquitoes' susceptibility to pyrethroids and increased the expression of metabolic enzymes. This evidence suggests that elevated temperatures projected in a future warmer climate could increase mosquitoes' resistance to insecticides and complicate malaria vector control measures. This study therefore provides vital information, and suggests useful areas of future research, on the effects of temperature variability on mosquitoes that could guide vector control measures in a future warmer climate. Graphical Abstract

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    Parasites & Vectors
    Article . 2022 . Peer-reviewed
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    PubMed Central
    Other literature type . 2022
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      Parasites & Vectors
      Article . 2022 . Peer-reviewed
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      PubMed Central
      Other literature type . 2022
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    Authors: Tedesco, Pauline;

    Cette thèse est basée sur des simulations numériques régionales et aborde, d’un point de vue énergétique, la variabilité à Méso (O(10-100)km) et Sous-mésoéchelle (O(0.1-10)km) dans la région du Courant des Aiguilles.(i) La variabilité de sous-mésoéchelle à la transition entre les deux branches du Courant des Aiguilles (28◦E-26◦E) est dominée, en l’absence de méandres de mésoéchelle, par des tourbillons cycloniques frontaux formant un ‘vortex street’. La tension ambiante frontogénétique intensifie le cisaillement frontal qui déclenche l’instabilité barotrope menant à la génération de tourbillons de sous-mésoéchelle.(ii) Un budget modal d’Energie Cinétique des Tourbillons est développé pour caractériser les transferts d’énergie entre les différentes structures verticales. Les interactions canalisées par la topographie (3 processus) résultent globalement en une perte d’énergie pour les tourbillons de mésoéchelle plus grande que les processus de dissipation (friction au fond et vent) et une cascade verticale inverse (interactions triadiques) renforce les tourbillons de mésoéchelle dans les zones au large.(iii) Notre budget modal permet de caractériser la région du Courant des Aiguilles comme une source nette d’énergie pour les tourbillons de mésoéchelle en contradiction avec celui estimé à partir de données d’altimétrie. Cette différence vient des données d’altimétrie ne tenant pas compte de la contribution principale de la dynamique aux sources et puits d’énergie des tourbillons de mésoéchelle (partie linéaire de la dynamique agéostrophique du mode barotrope et du 1er mode barocline). This dissertation is based on regional numerical simulations and addresses, from an energetic perspective, the Meso (O(10-100)km) and Submesoscale (O(0.1- 10)km) variability in the Agulhas Current region.(i) Submesoscale variability at the transition between the two Agulhas Current branches (28◦E-26◦E) is dominated, in the absence of mesoscale meanders, by cyclonic frontal eddies forming a ’vortex street’. The frontogenetic background strain intensifies the frontal shear which triggers the barotropic instability leading to submesoscale eddies generation.(ii) A modal Eddy Kinetic Energy budget is derived to characterize the energy transfers between the different vertical structures. Interactions canalized by topography (3 processes) globally result in a larger energy loss for mesoscale eddies than dissipation processes (bottom friction and wind) and an inverse vertical cascade (triadic interactions) reinforces mesoscale eddies in offshore areas.(iii) Our modal budget allows to characterize the Agulhas Current region as a net energy source for mesoscale eddies in contradiction with one inferred from altimetry data. The discrepancies come from altimetry data not accounting for the main contribution of the dynamics to mesoscale eddies energy sources and sinks (ageostrophic linear part of the dynamics of the barotropic and 1st baroclinic modes).

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    Doctoral thesis . 2021
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    Doctoral thesis . 2021
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    Authors: orcid Chaker Briki;
    Chaker Briki
    ORCID
    Harvested from ORCID Public Data File

    Chaker Briki in OpenAIRE
    Maha M. Almoneef; Abdelhakim Settar; Mbarek Mohamed; +1 Authors

    In the present study, we explored the temperature evolution and hydrogen desorption properties of the Mg50Ni50 alloy through both numerical simulation and experimental analyses. Desorption kinetics characterization was carried out using the volumetric method, specifically employing a Sievert's-type apparatus to investigate solid-gas reactions. The experiments covered a temperature range from 313 K to 353 K, with an initial hydrogen pressure of 12 bar. Simultaneously, a mathematical approach was employed to numerically investigate the temperature evolution within the hydride bed. Using COMSOL Multiphysics as a simulator, a numerical simulation was conducted based on experimental data. The study examined the impact of cooling temperature on hydride temperature evolution. Results revealed that hydrogen desorption kinetics of the amorphous Mg50Ni50 alloy are more significant compared to those of Mg2Ni compounds. Moreover, the effect of the warming temperature on the equilibrium pressure can also be observed in the hydrogen desorption isotherm curves. The experimental study of the Mg50Ni50 alloy provided activation energy data, along with determination of hydride formation enthalpy and entropy. On the other hand, we showed that the hydride temperature is maximum at the hydride-hydrogen interface within the hydride center.

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    Heliyon
    Article . 2024 . Peer-reviewed
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    Authors: orcid Tyler J. Lark;
    Tyler J. Lark
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    Tyler J. Lark in OpenAIRE
    orcid Nathan P. Hendricks;
    Nathan P. Hendricks
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    orcid Aaron Smith;
    Aaron Smith
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    orcid bw Nicholas Pates;
    Nicholas Pates
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    Nicholas Pates in OpenAIRE
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    Proceedings of the National Academy of Sciences
    Article . 2022 . Peer-reviewed
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    Authors: Serikbayeva Akmaral; Boranbayeva Assiya; Abdibattayeva Maral; Nurbayeva Farida; +2 Authors

    Abstract In this paper, the prevention of negative technogenic impact on the environment of oil sludge by using it as a secondary resource is considered. Oil sludge from various objects of oil fields in Kazakhstan (Mangystau region) has been studied. The possibilities of using oil (after its separation from oil sludge by bioremidiation) as a partial substitute for bitumen base in the production of modified bitumen are considered. The main physical and mechanical characteristics of modified bitumen are determined. The results confirm that the modified bitumen prepared with oil sludge and oil separated by bioremiation method meets the requirements for polymer-bitumen binder to Kazakhstan standards and is suitable for the production of modified bitumen in its physico-chemical characteristics.

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    Environmental and Climate Technologies
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    Authors: orcid bw K. Rhino;
    K. Rhino
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    orcid J. Iyer;
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    S.D.C. Walsh; orcid S.A. Carroll;
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    Abstract Fractures along interfaces between host rock and wellbore cement have long been identified as potential CO2 leakage pathways from subsurface CO2 storage sites. As a consequence, cement alteration due to exposure to CO2 has been studied extensively to assess wellbore integrity. Previous studies have focused on the changes to either chemical or mechanical properties of cement upon exposure to CO2-enriched brine, but not on the effects of loading conditions. This paper aims to correct this deficit by considering the combined effects of the fracture pathway and changing effective stress on chemical and mechanical degradation at conditions relevant to geologic carbon storage. Flow-through experiments on fractured cores composed of cement and tight sandstone caprock halves were conducted to study the alteration of cement due to exposure to CO2-enriched brine at 3, 7, 9, and 12 MPa effective stress. We characterized relevant reactions via solution chemistry; fracture permeability via changes to differential pressure; mechanical changes via micro-hardness testing, and pore structure changes via x-ray tomography. This study showed that the nature and the rates of the chemical reactions between cement and CO2 were not affected by the effective stress. The differences in the permeability responses of the fractures were attributed to interactions among the geometry of the flow path, the porosity increase of the reacted cement, and the mechanical deformation of reacted asperities. The suite of observed chemical reactions contributed to change in cement mechanical properties. Compared to the unreacted cement, the average hardness of the amorphous silica and depleted layers was decreased while the hardness of the calcite layer was increased. Tomographic imaging showed that preferential flow paths formed in some of the core-flood experiments, which had a significant impact on the permeability response of the fractured samples. We interpreted the observed permeability responses in terms of competition between dissolution of cement phases (leading to enhanced permeability) and mechanical deformation of reacted regions (leading to reduced permeability).

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    International Journal of Greenhouse Gas Control
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  • Authors: Gatti, Donatella; Vauday, Julien;

    FAERE Working Paper, 2019.23 ; While environmental values are spreading among societies, theyhardly lead to effective political actions. This may be due to an overestimation of the sharing of those values among people, or to a lack ofpolitical power of environmentalists vis-à-vis materialist citizens. Wepropose a theoretical model to investigate these two channels, based ona setup a la Grossman and Helpman (1994), in which lobby is a strategy available to social groups, in order to influence the government onenvironmental taxes. Because societies have being historically markedby materialist habits, citizens sharing those habits face lower costswhen getting organized. By considering endogenous lobby formation ala Mitra (1999), we show that, in order for environmental and materialist lobbies to coexist, the society must be mixed enough. Based on adynamic framework a la Besley and Persson (2019), we investigate howsocial values change over time. Whenever lobbying by materialists prevails, a unique social equilibrium exists, featuring a stable hegemonyby materialist values. If environmentalists get organized too, a secondsocial equilibrium emerges, that is locally stable and more favorableto them. However, the threshold might be very high, above which thecultural transition effectively takes off. By calibrating the model, westudy counter-acting forces allowing to improve the odds of the environmental transition, such as cultural mutations, social-signaling, andlowering organizational costs. Finally, we provide policy implications. ; Alors que les valeurs environnementales se répandent dans les sociétés, elles ne débouchent guère sur des actions politiques efficaces. Cela peut être dû à une surestimation du partage de ces valeurs entre les gens, ou à un manque de pouvoir politique des écologistes vis-à-vis des citoyens matérialistes. Nous proposons un modèle théorique pour investiguer ces deux canaux, basé sur un cadre à la Grossman et Helpman (1994), dans lequel le lobbying est une stratégie à la disposition des ...

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    At the 1972 Stockholm Conference, participating States expressed concern about the extent and consequences of air pollution, laying the groundwork for international legal cooperation to address it. The Action Plan for the Human Environment included the need to promote scientific observation of the atmosphere, and the principles set out in the Stockholm Declaration served, as in other areas of environmental international law, to articulate the response to the threats identified. Since that meeting, the evolution of international legal protection of the atmosphere has been marked by the implementation of three international regimes. The European regime on transboundary air pollution, inaugurated in 1979, was the first model of international cooperation in this field, and influenced subsequent developments in the regimes on ozone layer protection and climate change. Taking into account the foundational impetus that the Stockholm Conference provided for the development of these regimes, this paper analyses the evolution of international legal protection of the atmosphere in the fifty years since the Conference was held

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    Authors: orcid Vannini M.;
    Vannini M.
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    orcid Marchese P.;
    Marchese P.
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    With the aim to fully exploit the by-products obtained after the industrial extraction of starch from sweet potatoes, a cascading approach was developed to extract high-value molecules, such as proteins and pectins, and to valorize the solid fraction, rich in starch and fibrous components. This fraction was used to prepare new biocomposites designed for food packaging applications. The sweet potato residue was added to poly(3-hydroxybutyrate-co-3-hydroxyvalerate) in various amounts up to 40 wt % by melt mixing, without any previous treatment. The composites are semicrystalline materials, characterized by thermal stability up to 260 °C. For the composites containing up to 10 wt % of residue, the tensile strength remains over 30 MPa and the strain stays over 3.2%. A homogeneous dispersion of the sweet potato waste into the bio-polymeric matrix was achieved but, despite the presence of hydrogen bond interactions between the components, a poor interfacial adhesion was detected. Considering the significant percentage of sweet potato waste used, the biocomposites obtained show a low economic and environmental impact, resulting in an interesting bio-alternative to the materials commonly used in the packaging industry. Thus, according to the principles of a circular economy, the preparation of the biocomposites closes the loop of the complete valorization of sweet potato products and by-products.

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    Polymers
    Article . 2021 . Peer-reviewed
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Polymersarrow_drop_down
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      Polymers
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      Polymers
      Article . 2021 . Peer-reviewed
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      Polymers
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      Polymers
      Article . 2021
      Data sources: DOAJ
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      Polymers
      Article . 2021 . Peer-reviewed
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