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Abstract The elemental dissolution of Cu-Zn alloys was investigated as a function of Zn content ranging from 0 to 45 wt%. Atomic emission spectroelectrochemistry (AESEC) was utilized to directly monitor Cu2+ and Zn2+ release and oxide growth as function of time during potentiodynamic experiments. It was determined that Cu dissolution undergoes a simultaneous mechanism of Cu2O formation and Cu2+ release. The addition of Zn in Cu-Zn alloy does not measurably change the dissolution mechanism of Cu2+ and the rate of aqueous Cu2+ was only dependent on the potential. Zn dissolution was however blocked by the formation of a Cu(0) film which shifted the Zn dissolution in the anodic direction.

This paper presents the direct power control (DPC) of asymmetrical six-phase permanent magnet synchronous generator (A6PMSG) which supplied the isolated load via two PWM rectifiers. The study concerns the method of control by the converter (DPC). The proposed method is around two hysteresis controllers that enable the adjustment of active and reactive power. The research in this paper is verified by MATLAB SIMULINK software. It has been demonstrated through the simulation results that the proposed strategy can be an attractive and practical solution to multi-phase machines applications.

Abstract The hybrid pneumatic power system (HPPS) proposed in this research replaces the battery’s electric-chemical energy with flow work and optimizes the management and utilization of the energy. This power system is able to keep the internal-combustion engine working at its optimal condition and turn its waste energy into effective mechanical energy and so enhance the thermal efficiency of the whole system. Using computer simulation software ITI-SIM, this study simulates the overall dynamic characteristics of the system in accordance with the regulated running-vehicle test-mode ECE47, and, with experimental verification and analysis, proves that this system can meet the requirements of the standard running-car mode. As for recycling the waste energy, the experimental results show that this design could offset the shortcomings of the low-density of pneumatic power and so effectively enhance the efficiency of the whole system.

In this paper, we present the conjugate heat transfer analysis in a 167-kVA dry-type transformer using the parallel version of the computational fluid dynamics code Fluent 6.0. The renormalization group kappa-epsiv model is proposed to compute the turbulent aspect of the convective airflow inside the transformer metal tank for Air Natural/Air Natural cooling conditions. An experimental approach was used to assess Joule losses in the low-/high-voltage windings and eddy-current losses in the magnetic core. The resulting mathematical model was solved using 14 compute nodes on a distributed machine.

Resume Les resultats de la simulation d'un cycle a absorption fonctionnant en refrigeration a trois niveaux de pression font apparaitre un gain appreciable des performances par rapport a un cycle travaillant a deux niveaux de pression. Le n-butane (R600) est propose comme refrigerant et la dimethyl formamide (DMF) comme solvant. L'influence d'un certain nombre de parametres a ete etudiee et est presentee; ainsi, il a pu etre montre que le coefficient de performance peut atteindre des valeurs interessantes pour de faibles valeurs de la temperature de regeneration, redant ainsi possible l'utilisation de rejets thermiques ou bien de capteurs solaires peu sophistiques.

Abstract This paper gives an experimental investigation of the effect of climatic conditions on the performance and degradation of crystalline silicon photovoltaic modules under Saharan environment in Adrar region in the south of Algeria. The first part of this study is focused on the analysis and assessment of UDTS 50 PV modules degradation after a long term outdoor exposure to these conditions (more than 12 years). The visual inspection of 62 PV modules has allowed to observe and determine the degradation modes such as, EVA discoloration, delamination, busbar corrosion, cracking of solar cell, glass breakage, AR coating and solder bond. The degradation evaluation of three modules with different defects was also performed, using (I-V/P-V) characteristics and the degradation rates of the parameters (Pmax, Imp, Vmp, Isc, Voc, FF) at Standard test conditions (STC) in order to compare with the nominal data delivered by the manufacturer of photovoltaic panels. Finally, the combination of the partial shading effect and the presence of EVA browning defect was examined to assess the changes in I-V and P-V curves caused by the drop in electrical parameters.

Abstract This work presents a numerical study on the performance of a stand-alone adsorption cooling system based on the silica gel/water couple driven by hybrid photovoltaic/thermal (PVT) collectors. This system is intended for the conservation of perishable agricultural products which require air-conditioned premises to preserve them. The weather conditions are those of North Africa (Algiers). Considering the above, this paper aims at analyzing the PVT-Adsorption system with energy storage to guarantee a stabilized production and increase the solar coverage. trnsys was used to simulate the system taking into account hourly series of irradiation and ambient temperature covering one year. The performance study reveals that the DualSun PVT hybrid collectors used provide optimal annual production and that the adsorption cooling system offers more reliable production during summer. The temperature difference between the inside and outside of the cooled enclosure balances supply and demand. The loss analysis of the storage device indicates that losses depend, on the one hand, on the interior/exterior temperature difference of the storage tank with more significant values during the summer season. On the other hand, the losses also depend on the volume of the storage tank which was optimized in order to limit the heat exchange with the surroundings.

Use of a pilot-scale fixed-film bioreactor was investigated for remediation of bromate contamination within groundwater. Bromate reduction with stoichiometric production of bromide was observed, providing supporting evidence for complete reduction of bromate with no production of stable intermediates. Reduction of 87-90% bromate from an influent concentration of 1.1 mg L(-1) was observed with retention times of 40-80 h. Lower retention times led to decreases in bromate reduction capability, with 11.5% removal at a 10 h retention time. Nitrate reduction of 76-99% from a 30.7 mg L(-1) as NO(3)(-) influent was observed at retention times of 10-80 h, although an increase in nitrite production to 2.7 mg L(-1) occurred with a 10 h retention time. Backwashing was not required, with the large plastic packing media able to accommodate biomass accumulation without decreases in operational efficiency. This study has provided proof of concept and demonstrated the potential of biological bromate reduction by fixed-film processes for remediation of a bromate contaminated groundwater source.

Biodiesel is a fuel generally consisting of a mixture of fatty acid methyl esters (FAMEs) which is used in alternative or in combination with petroleum diesel for its environmental benefits. Biodiesel is conveniently manufactured from vegetable oils by transesterification of triglycerides with methanol. However, the process brings about the concurrent formation of glycerol, which may become an oversupplied chemical if biodiesel production keeps growing. A novel biodiesel-like material (abbreviated as DMC-BioD) was developed by reacting soybean oil with dimethyl carbonate (DMC), which avoided the co-production of glycerol. The main difference between DMC-BioD and biodiesel produced from vegetable oil and methanol (MeOH-biodiesel) was the presence of fatty acid glycerol carbonate monoesters (FAGCs) in addition to FAMEs. In the following study, details regarding synthesis and composition of DMC-BioD are provided along with physical properties relevant for its use as a fuel. In addition, the production of potential pyrogenic contaminants was investigated by analytical pyrolysis and compared with those from MeOH-biodiesel, and the model compounds tristearin, triolein, trilinolein and oleic acid glycerol carbonate ester (OAGC). The presence of FAGCs influenced both fuel and flow properties, while the distribution of main pyrogenic compounds, including polycyclic aromatic hydrocarbons (PAHs), was little affected. Benefits and drawbacks of DMC as a candidate transmethylating reagent for producing biofuel from renewable resources and alternative co-products (glycerol carbonate and glycerol dicarbonate) are discussed.