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Received 4 September 2013 Received in revised form 21 November 2013 Accepted 28 November 2013 Available online 31 December 2013 Keywords: Anisole Pyrolysis Oxidation Tars Biomass Kinetic modeling 1. Introduction Environmental concerns such as the control of greenhouse gas emissions have led to an increased interest in the use of renewable energy. Biomass is widely used in combustion but can also be uti- lized in more advanced applications such as the production of a synthesis gas (syngas, a mixture of CO and H2), which can be used for the production of liquid fuels such as Fisher-Tropsch or meth- anol. Lignocellulosic biomass may be a promising feedstock through the gasification processes [1,2], but tar is also formed dur- ing gasification [3]. The tar content in the product gas is the major cumbersome and problematic parameter in the gasification pro- cesses [4]. Tar represents a complex mixture of over 100 com- pounds [5,6]. It leads to fouling, coke deposition, and catalyst deactivation. Hence, tar conversion or removal is one of the main challenges for the successful development of commercial gasifica- tion technologies and has been extensively studied [7,8]. Evans and Milne [5] defined three main classes of tars: primary tars (low temperature, oxygenated) and secondary and tertiary tars (benzene, polycyclic aromatic hydrocarbons--PAHs, etc.). In com- bustion and gasification reactors, the heaviest (tertiary) tars are ⇑ Corresponding author. Fax: +33 3 83 37 81 20. E-mail address: pierre-alexandre.glaude@univ-lorraine.fr (P.-A. Glaude). abstract Anisole was chosen as the simplest surrogate for primary tar from lignin pyrolysis to study the gas-phase chemistry of methoxyphenol conversion. Methoxyphenols are one of the main precursors of PAH and soot in biomass combustion and gasification. These reactions are of paramount importance for the atmospheric environment, to mitigate emissions from wood combustion, and for reducing tar formation during gasification. Anisole pyrolysis and stoichiometric oxidation were studied in a jet-stirred reactor (673-1173 K, residence time 2 s, 800 Torr (106.7 kPa), under dilute conditions) coupled with gas chromatography-flame ionization detector and mass spectrometry. Decomposition of anisole starts at 750 K and a conversion degree of 50% is obtained at about 850 K under both studied conditions. The main products of reaction vary with temperature and are phenol, methane, carbon monoxide, benzene, and hydrogen. A detailed kinetic model (303 species, 1922 reactions) based on a combustion model for light aromatic compounds has been extended to anisole. The model predicts the conversion of anisole and the formation of the main products well. The reaction flux analyses show that anisole decomposes mainly to phenoxy and methyl radicals in both pyrolysis and oxidation conditions. The decomposition of phenoxy radicals is the main source of cyclopentadienyl radicals, which are the main precursor of naphthalene and heavier PAH in these conditions.

Abstract During successive industrial revolutions, the objective has not only been for industry to improve and satisfy its direct needs, it has also been to improve society’s standard of living and make life easier for the consumer. Therefore, economic growth should always go hand in hand with each industrial revolution. The medical industry, energy conservation and, in particular, production technologies will be transformed through new value chain models. Globalization, urbanization, demographic change and energy transformation are the transforming forces estimating the technological impetus for a better identification of solutions for a world on the move. In recent years, successive revolutions have made remarkable contributions to a person’s quality of life, safety, industrial economy, comfort and health. This work aims at improving the energy consumption of buildings. To achieve this goal, we have created a Digital Twin that accurately reflects the behavior and characteristics of a future or existing building. To reproduce a copy of the future or existing building, we chose to use the Autodesk REVIT solution to meet several constraints. These have a significant influence on the energy behavior of the building.

To help policymakers form a judgment on inflation risks and the required monetary policy stance the OECD has developed an analytical framework based on a set of 'eclectic' Phillips curves estimated for the two largest OECD economies, the United States and the euro area, which is presented in this paper. This framework is used in the preparation of the Economic Outlook to explain recent developments in core inflation, excluding food and energy, based on developments in measures of economic slack (the output gap), spill-over effects from energy prices onto core inflation and lagged responses to past inflation via expectations formation. The fact that the knock-on effects from energy shocks onto core inflation appear small in comparison with the 1970s can be explained by the secular fall in energy intensity, a low and stable rate of 'mean inflation' -- to which observed inflation reverts after a shock has worked its way through -- and persistent slack in the aftermath of the bursting of the dotcom bubble.

This paper gives a definition of collective self-consumption and introduces the current regulatory framework in some European countries. It proposes a review of relevant Demand Side Management (DSM) methods applicable to improve the collective self-consumption rate. It also introduces the concept of blockchain and its possible applications to collective self-consumption, with a focus on some current experimentations. Current blockchain applications include validation of measured data and energy transactions. New architectures propose a completely decentralized energy market and grid control based on the blockchain technology. However, a deeper analysis of the benefit of blockchain is required. The legal framework will also play a role on the future deployment of these applications.

Abstract The dates production is usually accompanied by considerable loss of fruit byproducts. The chemical analysis showed that ‘Deglet Nour’ discarded flesh is rich in soluble sugars (79.8% ± 0.8%) and fibers (12.3% ± 0.4%). A processing approach was implemented to permit the production of biohydrogen from the flesh and biogas from the crude fiber fraction after soluble sugars extraction. This approach showed interesting results since the obtained biochemical hydrogen potential and the maximum methane yield were 292 mL H2/gVS initial and 235 mL CH4/gVS fibers respectively. Parallelly, the “hot water” soluble sugar fraction (date syrup) was of interest for agro-alimentary applications and showed a high sucrose, glucose and fructose content of 33.5%, 11.8% and 13.17% respectively. This study presents a proof of concept allowing an efficient sustainable energetic conversion of the date by-products biomass to biohydrogen via dark fermentation or to soluble sugars fraction and biogas via a biorefinery approach.

In this paper a survey of solar-based driven thermoelectric technologies and their applications is presented. Initially, a brief analysis of the environmental problems related to the use of conventional technologies and energy sources is presented and the benefits offered by thermoelectric technologies and renewable energy systems are outlined. The development history of solar-based thermoelectric technologies is introduced together with the discussion of the existing drawbacks of current systems. Typical applications of the solar-driven thermoelectric refrigeration and the solar-driven thermoelectric power generation are presented in order to show to the reader the extent of their applicability. The application areas described in this paper show that solar-driven thermoelectric technologies could be used in a wide variety of fields. They are attractive technologies that not only can serve the needs for refrigeration, air-conditioning applications and power generation, but also can meet demand for energy conservation and environment protection.

Thin (approximately 10 nm) oxide buffer layers grown over lead-halide perovskite device stacks are critical for protecting the perovskite against mechanical and environmental damage. However, the limited perovskite stability restricts the processing methods and temperatures (<=110 C) that can be used to deposit the oxide overlayers, with the latter limiting the electronic properties of the oxides achievable. In this work, we demonstrate an alternative to existing methods that can grow pinhole-free TiOx (x = 2.00+/-0.05) films with the requisite thickness in <1 min without vacuum. This technique is atmospheric pressure chemical vapor deposition (AP-CVD). The rapid but soft deposition enables growth temperatures of >=180 ��C to be used to coat the perovskite. This is >=70 ��C higher than achievable by current methods and results in more conductive TiOx films, boosting solar cell efficiencies by >2%. Likewise, when AP-CVD SnOx (x ~ 2) is grown on perovskites, there is also minimal damage to the perovskite beneath. The SnOx layer is pinhole-free and conformal, which reduces shunting in devices, and increases steady-state efficiencies from 16.5% (no SnOx) to 19.4% (60 nm SnOx), with fill factors reaching 84%. This work shows AP-CVD to be a versatile technique for growing oxides on thermally-sensitive materials. R.D.R and R.A.J contributed equally. 23 pages. 6 figures