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This study introduces novel phenothiazine-based organic dyes, 2-LBH-100, 2-LBH-44, and 2-Ryu-4, specifically designed for quasi-solid-state dye-sensitized solar cells (QsDSSCs). Employing a donor-π-acceptor architecture, these dyes incorporate varying electron-donating moieties, including bis(3-(hexyloxy)phenyl)amine and diphenylamino, coupled with a cyanoacrylic acid acceptor. Alkoxy substitutions in 2-LBH-100 and 2-LBH-44 enhanced solubility and dye loading on TiO2, leading to improved performance in QsDSSCs. 2-LBH-100 exhibited a power conversion efficiency (PCE) exceeding 5% with excellent stability, while 2-LBH-44 demonstrated a PCE of over 3%, increasing to 4% over time. 2-Ryu-4, with its diphenylamino donor, achieved an initial PCE of over 6%. This research highlights the crucial role of donor–acceptor interactions in optimizing organic dye design for high-performance QsDSSCs, paving the way for efficient and stable next-generation solar energy technologies.

• Key message Insurance might be an efficient tool to strengthen adaptation of forest management to climate change. A theoretical model under uncertainty is proposed to highlight the effect, on adaptation decisions, of considering adaptation efforts in forest insurance contracts. Results show that insurance is relevant to increase adaptation efforts under some realistic conditions on forest owner’s uncertainty and risk preferences, and on the observability or not of adaptation efforts. • Context One of the challenges of forest adaptation to climate change is to encourage private forest owners to implement adaptation strategies. • Aims We suggest the analysis of forest insurance contracts against natural hazards as a vector to promote the implementation of adaptation efforts by private forest owners. • Methods We propose a theoretical model of insurance economics under risk and under uncertainty. • Results Our results indicate that when climate change makes the probability of the occurrence of the natural event uncertain, then it may be relevant to include adaptation efforts in the insurance contract, leading to an increase in the adaptation efforts of risk-averse and uncertainty-averse forest owners. In addition, we show that the relevance of insurance as a vector to promote adaptation efforts is greater when the forest owner’s effort is unobservable by the insurer as compared to a situation of perfectly observable effort. • Conclusion Under some realistic assumptions, the forest insurance contract seems to be a relevant tool to encourage forest owners to adapt to climate change.

To mitigate the temperature increase in urban environments and reduce its impact on energy consumption and the quality of the environment, urban retrofitting technologies have been developed and applied worldwide. High albedo in urban surfaces and additional vegetation are the most efficient strategies to accomplish these goals. The objective of this study is to estimate the weight of these strategies, both individually and integrated, on the cooling potential of two Latin American cities. To do this, 36 low and high urban density scenarios were simulated with the ENVI-Met software. The simulation models were calibrated using air temperature curves which were monitored during the summer periods from 2010 to 2013. A Principal Components Analysis was carried out to establish possible associations between the proposed mitigation strategies and then the weight of anthropogenic heat was evaluated according to the configuration. The results show that the integrated mitigation strategies in urban areas -i. e. increase vegetation and albedo on horizontal surfaces- has a great potential to mitigate urban warming, showing a more significant impact on low-density urban configuration. The contribution of anthropogenic heat mainly produced by motorized transport and air conditioning systems, is a crucial input data for the urban microclimate simulations. Its impact on the urban densification processes may cancel out the benefits derived by the application of the mitigation strategies considered.

AbstractThe ethylene glycol oxidation reaction on nickel and ruthenium modified palladium nanocatalysts was investigated with electrochemical, spectroelectrochemical, and chromatographic methods. These carbon‐supported materials, prepared by a revisited polyol approach, exhibited high activity towards the ethylene glycol electrooxidation in alkaline medium. Electrolysis coupled with high performance liquid chromatography/mass spectrometry (HPLC‐MS) and in situ Fourier transform infrared spectroscopy (FTIRS) measurements allowed us to determine the different compounds electrogenerated in the oxidative conversion of this two‐carbon molecule. High value‐added products such as oxalate, glyoxylate, and glycolate were identified in all electrolytic solutions, whereas glyoxylate was selectively formed at the Ru45@Pd55/C electrode surface. In situ FTIRS results also showed a decrease in the pH value in the thin layer near the electrode as a consequence of OH− consumption during the spectroelectrochemical experiments.

Abstract Additional experimental data concerning the kinetics of Ni-Mo codeposition were obtained by investigating cathodic polarization using a rotating disc electrode. The Ni-Mo alloys were deposited from an ammonium citrate bath. The alloy deposition was controlled by activation in the case of low values of the cathode potential and by diffusion in the case of higher values. The hydrogen discharge was found to be diffusion controlled. The inductive influence of nickel results in depolarization of the reduction of molybdenum which cannot be deposited separately. An increase in the disc rotation speed caused an increase in the maximum cathode efficiency and in the molybdenum content of the alloy.

In the present study, we explored the temperature evolution and hydrogen desorption properties of the Mg50Ni50 alloy through both numerical simulation and experimental analyses. Desorption kinetics characterization was carried out using the volumetric method, specifically employing a Sievert's-type apparatus to investigate solid-gas reactions. The experiments covered a temperature range from 313 K to 353 K, with an initial hydrogen pressure of 12 bar. Simultaneously, a mathematical approach was employed to numerically investigate the temperature evolution within the hydride bed. Using COMSOL Multiphysics as a simulator, a numerical simulation was conducted based on experimental data. The study examined the impact of cooling temperature on hydride temperature evolution. Results revealed that hydrogen desorption kinetics of the amorphous Mg50Ni50 alloy are more significant compared to those of Mg2Ni compounds. Moreover, the effect of the warming temperature on the equilibrium pressure can also be observed in the hydrogen desorption isotherm curves. The experimental study of the Mg50Ni50 alloy provided activation energy data, along with determination of hydride formation enthalpy and entropy. On the other hand, we showed that the hydride temperature is maximum at the hydride-hydrogen interface within the hydride center.

According to the renewable energy directive 2009/28/EC, the European Union Member States should increase by 2020 the use of renewable energy to 20% of gross final energy consumption and to reach a mandatory share of 10% renewable energy in the transport sector. This study aims to quantify the impact of 2020 bioenergy targets on the land use in the EU, based on the projections of the National Renewable Action Plans in four scenarios: Scenario 1. Bioenergy targets according to NREAPs; Scenario 2. Bioenergy targets according to NREAPs, no second generation biofuels; Scenario 3. Bioenergy targets according to NREAPs, reduced import of biofuels and bioliquids; Scenario 4. Bioenergy targets according to NREAPs, high imports of biofuels and bioliquids. This study also considers the credit for co-products generated from biofuel production. The analysis reveals that the land used in the EU for bioenergy would range between 13.5 Mha and 25.2 Mha in 2020. This represent between 12.2% and 22.5% of the total arable land used and 7.3% and 13.5% of the Utilised Agricultural Area (UAA). In the NREAPS scenario, about 17.4 Mha would be used for bioenergy production, representing 15.7% of arable land and 9.4% of UAA. The increased demand from biofuels would lead to an increased generation of co-products, replacing conventional fodder for animal feed. Considering the co-products, the land used for bioenergy would range between 8.8 Mha and 15.0 Mha in 2020 in the various scenarios. This represent between 7.9% and 13.3% of the total arable land used in the EU and 4.7% and 8.0% of the UAA. In the NREAPS scenario, when co-products are considered, about 10.3 Mha would be used for biofuels, bioliquids and bioenergy production, representing 9.3% of arable land and 5.6% of agricultural land. This study further provides detailed data on the impact on land use in each Member State.