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In ecological risk assessment, exposure is generally modelled assuming static conditions, herewith neglecting the potential role of emission, environmental and biomass dynamics in affecting bioavailable concentrations. In order to investigate the influence of such dynamics on predicted bioavailable concentrations, the spatially-resolved dynamic model "ChimERA fate" was developed, incorporating macrophyte and particulate/dissolved organic carbon (POC/DOC) dynamics into a water-sediment system. An evaluation against three case studies revealed a satisfying model performance. Illustrative simulations then highlighted the potential spatio-temporal variability of bioavailable concentrations after a pulsed emission of four chemicals in a system composed of a pond connected to its inflow and outflow streams. Changes in macrophyte biomass and POC/DOC levels caused exposure variations which were up to a factor of 4.5 in time and even more significant (several orders of magnitude) in space, especially for highly hydrophobic chemicals. ChimERA fate thus revealed to be a useful tool to investigate such variations and to identify those environmental and ecological conditions in which risk is expected to be highest.

Over half of the world's forests are disturbed, and the rate at which ecosystem processes recover after disturbance is important for the services these forests can provide. We analyze the drivers' underlying changes in rates of key ecosystem processes (biomass productivity, litter productivity, actual litter decomposition, and potential litter decomposition) during secondary succession after shifting cultivation in wet tropical forest of Mexico.We test the importance of three alternative drivers of ecosystem processes: vegetation biomass (vegetation quantity hypothesis), community‐weighted trait mean (mass ratio hypothesis), and functional diversity (niche complementarity hypothesis) using structural equation modeling. This allows us to infer the relative importance of different mechanisms underlying ecosystem process recovery.Ecosystem process rates changed during succession, and the strongest driver was aboveground biomass for each of the processes. Productivity of aboveground stem biomass and leaf litter as well as actual litter decomposition increased with initial standing vegetation biomass, whereas potential litter decomposition decreased with standing biomass. Additionally, biomass productivity was positively affected by community‐weighted mean of specific leaf area, and potential decomposition was positively affected by functional divergence, and negatively by community‐weighted mean of leaf dry matter content.Our empirical results show that functional diversity and community‐weighted means are of secondary importance for explaining changes in ecosystem process rates during tropical forest succession. Instead, simply, the amount of vegetation in a site is the major driver of changes, perhaps because there is a steep biomass buildup during succession that overrides more subtle effects of community functional properties on ecosystem processes. We recommend future studies in the field of biodiversity and ecosystem functioning to separate the effects of vegetation quality (community‐weighted mean trait values and functional diversity) from those of vegetation quantity (biomass) on ecosystem processes and services.

In wetlands, a distinct zonation of plant species composition occurs along moisture gradients, due to differential flooding tolerance of the species involved. However, "flooding" comprises two important, distinct stressors (soil oxygen demand [SOD] and partial submergence) that affect plant survival and growth. To investigate how these two flooding stressors affect plant performance, we executed a factorial experiment (water depth x SOD) for six plant species of nutrient-rich and nutrient-poor conditions, occurring along a moisture gradient in Dutch dune slacks. Physiological, growth, and biomass responses to changed oxygen availability were quantified for all species. The responses were consistent with field zonation, but the two stressors affected species differently. Increased SOD increased root oxygen deprivation, as indicated by either raised porosity or increased alcohol dehydrogenase (ADH) activity in roots of flood-intolerant species (Calamagrostis epigejos and Carex arenaria). While SOD affected root functioning, partial submergence tended more to reduce photosynthesis (as shown both by gas exchange and 13C assimilation), leaf dark respiration, 13C partitioning from shoots to roots, and growth of these species. These processes were especially affected if the root oxygen supply was depleted by a combination of flooding and increased SOD. In contrast, the most flood-tolerant species (Juncus subnodulosus and Typha latifolia) were unaffected by any treatment and maintained high internal oxygen concentrations at the shoot : root junction and low root ADH activity in all treatments. For these species, the internal oxygen transport capacity was well in excess of what was needed to maintain aerobic metabolism across all treatments, although there was some evidence for effects of SOD on their nitrogen partitioning (as indicated by 865N values) and photosynthesis. Two species intermediate in flooding tolerance (Carex nigra and Schoenus nigricans) responded more idiosyncratically, with different parameters responding to different treatments. These results show that partial submergence and soil flooding are two very different stressors to which species respond in different ways, and that their effects on physiology, survival, and growth are interactive. Understanding species zonation with water regimes can be improved by a better appreciation of how these factors affect plant metabolism independently and interactively.

Sustainability is commonly assessed along environmental, societal, economic and technological dimensions. A crucial aspect of sustainability is that inter-generational equality must be ensured. This requires that sustainability is attained in the here and now as well as into the future. Therefore, what is perceived as 'sustainable' changes as a function of societal opinion and technological and scientific progress. A concept that describes the ability of systems to change is adaptive capacity. Literature suggests that the ability of systems to adapt is an integral part of sustainable development. This paper demonstrates that indicators measuring adaptive capacity are underrepresented in current urban water sustainability studies. Furthermore, it is discussed under which sustainability dimensions adaptive capacity indicators are lacking and why. Of the >90 indicators analysed, only nine are adaptive capacity indicators, of which six are socio-cultural, two technological, one economical and none environmental. This infrequent use of adaptive capacity indicators in sustainability assessments led to the conclusion that the challenge of dynamic and uncertain urban water systems is, with the exception of the socio-cultural dimension, not yet sufficiently reflected in the application of urban water sustainability indicators. This raises concerns about the progress towards urban water systems that can transform as a response variation and change. Therefore, research should focus on developing methods and indicators that can define, evaluate and quantify adaptive capacity under the economic, environmental and technical dimension of sustainability. Furthermore, it should be evaluated whether sustainability frameworks that focus on the control processes of urban water systems are more suitable for measuring adaptive capacity, than the assessments along environmental, economic, socio-cultural and technological dimensions.

ABSTRACTEnzymatic wheat gluten hydrolysis at high solid concentrations is advantageous from an environmental and economic point of view. However, increased wheat gluten concentrations result in a concentration effect with a decreased hydrolysis rate at constant enzyme‐to‐substrate ratios and a decreased maximum attainable degree of hydrolysis (DH%). We here identified the underlying factors causing the concentration effect. Wheat gluten was hydrolyzed at solid concentrations from 4.4% to 70%. The decreased hydrolysis rate was present at all solid concentrations and at any time of the reaction. Mass transfer limitations, enzyme inhibition and water activity were shown to not cause this hydrolysis rate limitation up to 50% solids. However, the hydrolysis rate limitation can be, at least partly, explained by a second‐order enzyme inactivation process. Furthermore, mass transfer impeded the hydrolysis above 60% solids. Addition of enzyme after 24 h at high solid concentrations scarcely increased the DH%, suggesting that the maximum attainable DH% decreases at high solid concentrations. Reduced enzyme activities caused by low water activities can explain this DH% limitation. Finally, a possible influence of the plastein reaction on the DH% limitation is discussed. Biotechnol. Bioeng. 2014;111: 1304–1312. © 2014 Wiley Periodicals, Inc.

The drought prone North-West Bangladesh is vulnerable to the impacts of climate change, particularly because of less water availability in the dry period and high water requirement for crop production. Improved understanding of recent changes in crop water demand in the dry season is important for the water resources management in the region. A study was carried out to determine the potential impacts of recent climate change during last three decades on trends of water requirements of Boro rice. The reference crop evapotranspiration (ETo), potential crop water requirement (∑ETC), effective rainfall during the crop growing period (ER), potential irrigation requirement for crop evapotranspiration (∑ETC − ER) and net irrigation requirement of Boro rice were estimated using observed daily climate data in the CropWat model for the period of 1980 to 2013 for four North-West districts. Significant decreasing trends of ETo were observed in most of the dry months due to increasing relative humidity and decreasing wind-speed and sun-shine hours. The results showed decreasing trends of potential crop water requirement, i.e. the total crop evapotranspiration (∑ETC), of Boro rice due to decreasing reference crop evapotranspiration and shorter crop growing periods. The variations in trends of potential irrigation requirement for crop evapotranspiration (∑ETC − ER) found among different districts, are mainly linked to variations in trends of changes in effective rainfall. The net irrigation requirement of Boro rice has decreased, by 11% during the last three decades at an average rate of −4.4 mm year−1, instead of decreasing effective rainfall, mainly because of high rate of decrease of crop evapotranspiration (−5.9 mm year−1). Results indicate that a warming climate does not always result in higher agricultural water use and that climate change can also result in reduced water demands because of changes in humidity, wind-speed and sun-shine hours.

With the concept of climate services rapidly climbing research and research-funding agendas worldwide, the time is ripe for a debate about the objectives, scope and content of such services.

This paper compares the quantity and quality of solid waste obtained from traditional ponds and recirculating aquaculture systems (RAS) for striped catfish and evaluates methane and compost production from these wastes. Striped catfish sludge was collected from four commercial ponds along the Mekong river and from three indoor RAS. The amount of sludge dry matter produced per kilogram of fish in ponds was 6 times higher than that in RAS. However, the concentration of nutrients in solid waste from RAS was much higher, with better compost quality and higher methane yield than that of sludge from ponds. Out of the collected 381 L biogas, the methane yield of striped catfish's solid waste in RAS systems was 201 L per kg chemical oxygen demand (COD). In ponds, the collected 267 L biogas yielded 125 L CH4 per kg COD. The higher methane production from RAS sludge concurred with higher digestibility of COD: 58% for RAS versus 38% for ponds. The quality and quantity of methane from striped catfish sludge were lower than that for other animal manures, and the resulting electricity yield was low. Considering the higher nutrient concentration in RAS-sludge, we recommend the combination RAS and composting in reusing sludge, which is presently the best option for a more sustainable and cleaner striped catfish production system.