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In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

In the present study, we explored the temperature evolution and hydrogen desorption properties of the Mg50Ni50 alloy through both numerical simulation and experimental analyses. Desorption kinetics characterization was carried out using the volumetric method, specifically employing a Sievert's-type apparatus to investigate solid-gas reactions. The experiments covered a temperature range from 313 K to 353 K, with an initial hydrogen pressure of 12 bar. Simultaneously, a mathematical approach was employed to numerically investigate the temperature evolution within the hydride bed. Using COMSOL Multiphysics as a simulator, a numerical simulation was conducted based on experimental data. The study examined the impact of cooling temperature on hydride temperature evolution. Results revealed that hydrogen desorption kinetics of the amorphous Mg50Ni50 alloy are more significant compared to those of Mg2Ni compounds. Moreover, the effect of the warming temperature on the equilibrium pressure can also be observed in the hydrogen desorption isotherm curves. The experimental study of the Mg50Ni50 alloy provided activation energy data, along with determination of hydride formation enthalpy and entropy. On the other hand, we showed that the hydride temperature is maximum at the hydride-hydrogen interface within the hydride center.

In the present study, we explored the temperature evolution and hydrogen desorption properties of the Mg50Ni50 alloy through both numerical simulation and experimental analyses. Desorption kinetics characterization was carried out using the volumetric method, specifically employing a Sievert's-type apparatus to investigate solid-gas reactions. The experiments covered a temperature range from 313 K to 353 K, with an initial hydrogen pressure of 12 bar. Simultaneously, a mathematical approach was employed to numerically investigate the temperature evolution within the hydride bed. Using COMSOL Multiphysics as a simulator, a numerical simulation was conducted based on experimental data. The study examined the impact of cooling temperature on hydride temperature evolution. Results revealed that hydrogen desorption kinetics of the amorphous Mg50Ni50 alloy are more significant compared to those of Mg2Ni compounds. Moreover, the effect of the warming temperature on the equilibrium pressure can also be observed in the hydrogen desorption isotherm curves. The experimental study of the Mg50Ni50 alloy provided activation energy data, along with determination of hydride formation enthalpy and entropy. On the other hand, we showed that the hydride temperature is maximum at the hydride-hydrogen interface within the hydride center.

Abstract Newer generation sources and loads are posing new challenges to the conventional power system protection schemes. Adaptive and intelligent protection methodology, based on advanced measurement techniques and intelligent fault diagnosis such as machine learning (ML), is found to be useful to meet these challenges. A large number of research works are reported on ML-based power system fault diagnosis. However, ML techniques are evolving at a very fast pace, and an inclusive, as well as state-of-the-art review on ML-based power system fault diagnosis, is not available in the literature. Given this need and growing trend towards ML, the study presented in this paper aims to provide a comprehensive review of ML-based power system fault diagnosis. At first, efforts have been made to enlist the issues present in conventional fault diagnosis which led to the popularity of ML techniques. Also, a baseline framework and workflow for ML-based fault diagnosis are presented. Next, various unsupervised and supervised learning techniques have been discussed separately which have been used by several researchers for fault diagnosis. The discussion throughout is supported with tabulated facts for fault detection, classification and localization works with techniques used, different simulation tools used, and their application system. The advantages and disadvantages of all the techniques of fault diagnosis have also been discussed which will help the readers in the selection of techniques for their research. A brief review of reinforcement learning and transfer learning is also given as they are gaining popularity in power system-related studies and have the potential to be used for fault diagnosis. Finally, the research trends, some key issues, and directions for future research have been highlighted.

Abstract Newer generation sources and loads are posing new challenges to the conventional power system protection schemes. Adaptive and intelligent protection methodology, based on advanced measurement techniques and intelligent fault diagnosis such as machine learning (ML), is found to be useful to meet these challenges. A large number of research works are reported on ML-based power system fault diagnosis. However, ML techniques are evolving at a very fast pace, and an inclusive, as well as state-of-the-art review on ML-based power system fault diagnosis, is not available in the literature. Given this need and growing trend towards ML, the study presented in this paper aims to provide a comprehensive review of ML-based power system fault diagnosis. At first, efforts have been made to enlist the issues present in conventional fault diagnosis which led to the popularity of ML techniques. Also, a baseline framework and workflow for ML-based fault diagnosis are presented. Next, various unsupervised and supervised learning techniques have been discussed separately which have been used by several researchers for fault diagnosis. The discussion throughout is supported with tabulated facts for fault detection, classification and localization works with techniques used, different simulation tools used, and their application system. The advantages and disadvantages of all the techniques of fault diagnosis have also been discussed which will help the readers in the selection of techniques for their research. A brief review of reinforcement learning and transfer learning is also given as they are gaining popularity in power system-related studies and have the potential to be used for fault diagnosis. Finally, the research trends, some key issues, and directions for future research have been highlighted.

AbstractPreparation of uniform, spherical Li4Ti5O12 with high tap density is significant to achieve a high volumetric energy density in lithium‐ion batteries. Herein, Li4Ti5O12 microspheres with variable tap density and tunable size distribution were synthesized by a newly designed industrial spray‐drying approach. The slurry concentration, sintering time, sintering conditions after spraying, and the effect of lithium/titanium molar ratio on the lithium‐ion (Li+) storage capability were investigated. A narrow particle size distribution of around 10 μm and a high tap density close to 1.4 g cm−3 of the Li4Ti5O12 spheres can be obtained under the optimized conditions. The Li4Ti5O12 spheres can deliver a much higher capacity of 168 mAh g−1 at a rate of 1 C and show a high capacity retention of 97.7 % over 400 cycles. The synthetic conditions are confirmed to be critical for improving the electron conductivity and Li+ diffusivity by adjusting the crystal and spatial structures. As‐prepared high‐performance Li4Ti5O12 is an ideal electrode for lithium‐ion batteries or capacitors; meanwhile, the presented approach is also applicable for preparing other kind of spherical materials.