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AbstractThe efficacy of thyroid (FNAB) processed by liquid‐based cytology (LBC) in Hashimoto's Thyroiditis (HT) in two reference periods, is evaluated. The morphologic features of 820 cases with both methods and the cyto‐histological comparison are analyzed. The diagnosis of hyperplastic nodules (HN) in HT, its mimickers especially in presence of oxyphilic cells and the role of immunocytochemistry (IHC) are studied.150 cases of HT processed by conventional smear (CS) in 1996–98 and 670 with LBC in 2005–2007,were included. The majority of FNAB were carried out under USguidance and fixed with ethyl alcohol for the CS. LBC material was rinsed in the Cytolit solution, processed according to the manufacturer's recommendations. Among the 150 CS, 83 were HT while 67 were HN in HT; in the second triennium 245 LBC were HT and 425 were HN in HT. In the first period a follow‐up (including a second FNA or surgery) was done in 92 cases, in the second period in 116.In the surgical group 97.1% in the first period were benign (all HT and 34/36 HN) and 2.8% malignant(all HN). In 2005–2007, 94% were benign (15 HT and 45/49 HN) and 6%malignant. Thirty HN from the second triennium had ICC for HBME‐1 and Galectin‐3 resulting negative in 93.5%. Among these cases, 10 had a benign histology and a concordant negative ICC.LBC can be used as a valid method for HT, especially for the possible application of ICC to HN, and it allows a correct preoperative selection of lesions Diagn. Cytopathol. 2011; © 2011 Wiley‐Liss, Inc.

Efficiency of energy resource use is a key factor for a sustainable energy future. By matching the exergy levels of supply and demand, Energy Quality Management (EQM) of building energy supply systems may achieve more efficient use of energy resources. Beyond this, environmental impact of energy supply systems is another essential issue. This work addresses the influence of EQM on CO 2 emissions in the operation optimization of a Distributed Energy System (DES). A multi-objective linear programming problem is formulated to reduce energy costs and increase the overall exergy efficiency. Total CO 2 emissions are evaluated for the optimized operation strategies of the DES. The operators of the DES can choose the operation strategy from the Pareto front, based on their priorities and also aware of effects on CO 2 emissions. Results demonstrate more efficient use of energy resources and reduction in CO 2 emissions through EQM, as compared with conventional energy supply systems.

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

Alkylated furan derivatives, such as 2,5-dimethylfuran (2,5-DMF) and 2-methylfuran (2-MF), have shown, at laboratory scale, a relatively high tendency to form soot. However, soot emissions from die...

Abstract In this paper, an exergoeconomic analysis and optimization of a combined solar and wind energy based system is proposed. The trigeneration system produces ammonia, hydrogen and electricity through integrated solar photovoltaic panels and wind turbines. Also, an ammonia fuel cell unit is utilized for generating power during insufficient available energy. The overall exergetic efficiency is found to be 29.7% and the corresponding energetic efficiency is 28.5% under design conditions. In addition, the total cost rate is obtained as 63,345 $/h. Moreover, multi-objective optimization is performed with various decision variables at different combinations of solar intensities and wind speeds, considering the maximization of exergy efficiency and minimization of total cost rates. The developed system provides better optimal operation points under high wind speeds. The optimal exergy efficiency is found to vary between 10.9% and 38.2% depending on the available solar and wind energy. The corresponding optimal total cost rates vary between 11,959 $/h and 59,755 $/h, respectively. Several parametric studies are also performed to determine the effects of changing system conditions on the thermodynamic and economic performance of the developed system.

Dolomite-based binders are characterised by interesting technical and environmental features. For their synthesis, sources of both CaO and MgO are required. The idea developed in this work is to couple the synthesis of dolomite-based binders, starting from a natural dolomite, through the concept of concentrated solar energy (needed to drive the endothermal dolomite calcination process) in fluidised bed reactors. To this end, a fluidised bed system, where the concentrated solar radiation is mimicked by the use of Xe-lamps (short-arc), has been set up and operated. Natural dolomite (sieved in the 420-590 ?m size range) was calcined at a nominal temperature of 850 °C, and bed temperature profiles during solar-driven calcination were investigated. Then, four binders were prepared by mixing slaked dolomite (obtained from the hydration of solar calcined dolomite) with either blast furnace slag or coal fly ash as supplementary cementitious materials. The binders were hydrated for curing times ranging from 7 to 56 days. X-ray fluorescence, X-ray diffraction and combined differential thermal and thermogravimetric analyses were employed as characterisation techniques both to analyse the chemical composition of starting materials and to investigate the evolution of the hydration in the four systems.

Abstract Catalyst layer structural changes in polymer electrolyte membrane fuel cells have significant impact on the cell performance and durability. In this study, ex-situ experiments are designed to investigate the effect of humidity and/or thermal cycles on the structural changes of catalyst layers. The relative humidity and temperature are controlled by an environmental chamber and the catalyst layer structure is characterized by scanning electron microscopy and optical microscopy. The experimental results indicate that crack growth and development, catalyst agglomerate detachment, and surface bulges are the main structural changes of the catalyst layers. Applying relative humidity and thermal cycling simultaneously causes the most significant crack growth, while applying thermal cycling alone causes no appreciable changes. This indicates that the absolute humidity is the key parameter for the crack growth. Through cyclic voltammetry analysis, it is shown that the electrochemical active surface area decreases from 64.1 m2 g−1 to 49.1 m2 g−1 after 500 combined relative humidity and thermal cycles. Analyses of electrochemical impedance spectroscopy show that the charge transfer resistance and ohmic resistance increase significantly after 500 combined relative humidity and thermal cycles, causing the cell performance degradation.

It's not only the carbon in the trees Forest loss affects climate not just because of the impacts it has on the carbon cycle, but also because of how it affects the fluxes of energy and water between the land and the atmosphere. Evaluating global impact is complicated because deforestation can produce different results in different climate zones, making it hard to determine large-scale trends rather than more local ones. Alkama and Cescatti conducted a global assessment of the biophysical effects of forest cover change. Forest loss amplifies diurnal temperature variations, increases mean and maximum air temperatures, and causes a significant amount of warming when compared to CO 2 emission from land-use change. Science , this issue p. 600