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It is crucial to reduce the energy penalties related to CO2 capture processes if CCS is to be implemented at industrial scale. In this context, gas-solid sorption has become a relevant technology. The absence of large amounts of water when using dry solid sorbents and their high heat capacity reduce the energy requirements in the gas-solid sorption CO2 capture process. Depending on the sorbent composition, the gas-solid sorption process carries out at high or low temperatures. High temperature sorbents allow the utilization of waste energy while energy requirements in low temperature processes will be less demanding. This study is focused on the assessment and comparison of the final energy penalty of low-temperature (amine impregnated alumina-based solid particles) and high-temperature solid sorbents capture process (calcium oxide).

Flexible butyl interconnection segments are synthetically incorporated into an electronically conductive poly(pyrene methacrylate) homopolymer and its copolymer. The insertion of butyl segment makes the pyrene polymer more flexible, and can better accommodate deformation. This new class of flexible and conductive polymers can be used as a polymer binder and adhesive to facilitate the electrochemical performance of a silicon/graphene composite anode material for lithium ion battery application. They act like a “spring” to maintain the electrode mechanical and electrical integrity. High mass loading and high areal capacity, which are critical design requirements of high energy batteries, have been achieved in the electrodes composed of the novel binders and silicon/graphene composite material. A remarkable area capacity of over 5 mAh/cm2 and volumetric capacity of over 1700 Ah/L have been reached at a high current rate of 333 mA/g.

AbstractThis report illustrates the experimental data associated with solar overheating. The experimental data has validated an analytical model which allows for the study of the influences a primary circuit's design has on the overheating of the solar tank.Secondly, the report includes a study of the stagnation in a solar facility. The evolution of the temperature in the hydraulic circuit by means of its measurement at 30 different points, together with the data of the pressure and flow, allow for the real behavior of the solar installation in stagnation conditions to be investigated.Finally, the study shows the measurements obtained on a solar thermal installation located in Alicante (southern Spain). Every installation has been monitored for several months and the main temperatures and pressures around the solar circuit have been noted. The measurements and their processing have allowed for the detection of overheating and stagnation problems in real operating conditions.

Abstract In this paper, we analyze the rationale for an energy policy mix when the European Emissions Trading Scheme (ETS) is considered from a public choice perspective. That is, we argue that the economic textbook model of the ETS implausibly assumes (1) efficient policy design and (2) climate protection as the single objective of policy intervention. Contrary to these assumptions, we propose that the ETS originates from a political bargaining game within a context of multiple policy objectives. In particular, the emissions cap is negotiated between regulators and emitters with the emitters' abatement costs as crucial bargaining variable. This public choice view yields striking implications for an optimal policy mix comprising RES supporting policies. Whereas the textbook model implies that the ETS alone provides sufficient climate protection, our analysis suggests that support for renewable energies (1) contributes to a more effective ETS-design and (2) may even increase the overall efficiency of climate and energy policy if other externalities and policy objectives besides climate protection are considered. Thus, our analysis also shows that a public choice view not necessarily entails negative evaluations concerning efficiency and effectiveness of a policy mix.

Model projections show that production of high-value products from microalgae could be profitable nowadays and commodities will become profitable within 10 years.

Avoiding irreversible climate change as effectively as possible is one of the most pressing challenges of society. Carbon pricing that is uniformly valid on a global and cross-sectoral basis represents a cost-efficient policy tool to meet this challenge. Carbon pricing allows external costs to be allocated or internalized on a polluter-pays principle. It is shown that a global emissions cap-and-trade system is the most suitable market-based instrument for reducing global emissions levels, in line with the temperature goal set by the Paris Agreement. A proposal for its design is presented in this paper. This instrument encourages worldwide measures, with the lowest marginal abatement cost, according to a pre-defined reduction path. Thereby, it ensures compliance with a specified remaining carbon budget to meet a certain temperature limit in a cost-efficient manner. Possible reduction paths are presented in this paper. Weaknesses in the design of existing emissions trading systems (ETS), such as the EU ETS, are identified and avoided in the proposed instrument. The framework solves several problems of today’s climate change policies, like the free rider problem, carbon leakage, rebound effects or the green paradox. The introduction of a global uniform carbon pricing instrument and its concrete design should be the subject of policy, especially at the United Nations climate change conferences, as soon as possible in order to allow for rapid implementation. If a global ETS with a uniform carbon price could be introduced, additional governmental regulations with regard to carbon emissions would become obsolete.

Abstract. Reliable quantification of the sources and sinks of greenhouse gases, together with trends and uncertainties, is essential to monitoring the progress in mitigating anthropogenic emissions under the Paris Agreement. This study provides a consolidated synthesis of CH4 and N2O emissions with consistently derived state-of-the-art bottom-up (BU) and top-down (TD) data sources for the European Union and UK (EU27+UK). We integrate recent emission inventory data, ecosystem process-based model results, and inverse modelling estimates over the period 1990–2018. BU and TD products are compared with European National GHG Inventories (NGHGI) reported to the UN climate convention secretariat UNFCCC in 2019. For uncertainties, we used for NGHGI the standard deviation obtained by varying parameters of inventory calculations, reported by the Member States following the IPCC guidelines recommendations. For atmospheric inversion models (TD) or other inventory datasets (BU), we defined uncertainties from the spread between different model estimates or model specific uncertainties when reported. In comparing NGHGI with other approaches, a key source of bias is the activities included, e.g. anthropogenic versus anthropogenic plus natural fluxes. In inversions, the separation between anthropogenic and natural emissions is sensitive to the geospatial prior distribution of emissions. Over the 2011–2015 period, which is the common denominator of data availability between all sources, the anthropogenic BU approaches are directly comparable, reporting mean emissions of 20.8 Tg CH4 yr−1 (EDGAR v5.0) and 19.0 Tg CH4 yr−1 (GAINS), consistent with the NGHGI estimates of 18.9 ± 1.7 Tg CH4 yr−1. TD total inversions estimates give higher emission estimates, as they also include natural emissions. Over the same period regional TD inversions with higher resolution atmospheric transport models give a mean emission of 28.8 Tg CH4 yr−1. Coarser resolution global TD inversions are consistent with regional TD inversions, for global inversions with GOSAT satellite data (23.3 Tg CH4yr−1) and surface network (24.4 Tg CH4 yr−1). The magnitude of natural peatland emissions from the JSBACH-HIMMELI model, natural rivers and lakes emissions and geological sources together account for the gap between NGHGI and inversions and account for 5.2 Tg CH4 yr−1. For N2O emissions, over the 2011–2015 period, both BU approaches (EDGAR v5.0 and GAINS) give a mean value of anthropogenic emissions of 0.8 and 0.9 Tg N2O yr−1 respectively, agreeing with the NGHGI data (0.9 ± 0.6 Tg N2O yr−1). Over the same period, the average of the three total TD global and regional inversions was 1.3 ± 0.4 and 1.3 ± 0.1 Tg N2O yr−1 respectively, compared to 0.9 Tg N2O yr−1 from the BU data. The TU and BU comparison method defined in this study can be operationalized for future yearly updates for the calculation of CH4 and N2O budgets both at EU+UK scale and at national scale. The referenced datasets related to figures are visualized at https://doi.org/10.5281/zenodo.4288969 (Petrescu et al., 2020).

The hydraulic balance of heating network is considered as a pre-condition for the implementation of low temperature district heating (LTDH). Its imbalance result into high energy consumption and heat-losses in the network. In this study, a novel hydraulic model is presented which investigates hydraulic imbalance in the LTDH network, using real weather and hourly monitored operational heating data from an existing boiler based building. Analysis of delta t in space-heating system shows that the delta t is maximum when the outside air temperature is lowest and it decreases with increase in outside air temperature. Furthermore, the hydraulic imbalance is analysed for four different control scenarios with the aim to find an optimum scenario with minimum pumping power, energy consumption and heat-losses in the LTDH network. Results show that the hydraulic imbalance is due to the absence of flow-limiters and balancing valves on the return pipe and thermostatic radiator valves (TRVs) alone are unable to maintain hydraulic balance in the space-heating system of buildings. Moreover, the control scenario with variable flow-rate and fixed supply water temperature from the sub-station is found to be optimum. Compared to the constant flow-rate scenario, the pumping power, energy consumption and heat-losses in the LTDH network are reduced by approximately 2%, 63% and 14%, respectively.

Wind turbine gearboxes are required to operate under adverse operational conditions over a long service lifetime. Unfortunately, gearbox designers are yet to achieve the reliability anticipated by wind turbine manufacturers and operators. The poor understanding of variable loading conditions has resulted in the majority of wind turbine gearboxes being unable to reach their expected service lifetime of 20-25 years. This has led to an increasing need to investigate the fundamental issues associated with the degradation of wind turbine gearbox materials during operation in order to improve existing designs and optimise future ones. This paper investigates the various challenges that need to be addressed in order to achieve a noteworthy increase in the operational service lifetime of large-scale industrial wind turbine gearboxes.