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Abstract Additional experimental data concerning the kinetics of Ni-Mo codeposition were obtained by investigating cathodic polarization using a rotating disc electrode. The Ni-Mo alloys were deposited from an ammonium citrate bath. The alloy deposition was controlled by activation in the case of low values of the cathode potential and by diffusion in the case of higher values. The hydrogen discharge was found to be diffusion controlled. The inductive influence of nickel results in depolarization of the reduction of molybdenum which cannot be deposited separately. An increase in the disc rotation speed caused an increase in the maximum cathode efficiency and in the molybdenum content of the alloy.

AbstractAn arc‐furnace model consisting of non‐linear, time‐varying resistance, realized by the Alternative Transients Program (ATP), is presented in this paper. It is shown that the model is appropriate for flicker investigation in electrical networks supplying arc furnaces, constituting a valid alternative to the linear arc modelling realized by amplitude modulation of voltage generators. Block diagram of the procedure for ATP modelling of the nonlinear, time‐varying arc resistance, dynamic voltage‐current characteristic of the furnace electric arc, voltage and current arc waveforms and characteristic curves of an arc furnace, obtained by ATP simulation, are presented, referring to circuit parameters taken from an actual plant and to a sinusoidal law for arc‐length time variation. Aflickermeter ATP simulation is realized to derive equivalent voltage‐variation values in agreement with the actual flicker measurements.

Abstract The central role of occupants for achieving energy savings in residential buildings is increasingly recognised. Simulation programmes able to take into account occupant behaviour are considered to be powerful tools for bridging the gap between the predicted and the actual energy consumption for new buildings. Nevertheless, the majority of residential buildings that will constitute the housing stock in 2050 have already been built today, therefore occupant behaviour and building simulation tools need to be fully exploited for supporting the renovation of existing housing stock. The aim of this paper is to explore the role of occupant behaviour modelling in supporting decision-makers dealing with the design of renovation strategies for residential buildings. An Italian multi-family public housing building is assumed as case study to estimate the influence of three dimensions linked with occupant behaviour – management of the thermostat, management of the heating system, variation of building characteristics – on energy heating consumption. The results show that, while the occupant behaviour influences the heating loads up to 1/3 in case of high level of building retrofit, the less the building is renovated, the higher is the behavioural impact in absolute terms of energy reduction. Therefore, in order to be effective, renovation strategies are required to design appropriate informative instruments at an early stage to support behaviour changes towards responsible energy consumption.

The main objective of this paper is to illustrate the current state of the art of the newborn smart gas grid concept. We provide a detailed discussion of the envisaged features of the smart gas grid, giving attention to both the related academic literature and to the ongoing world-wide projects. In doing so, we also discuss the potentialities of rethinking the smart grid paradigm from the perspective of a whole energy system, that both encompasses the electrical and the gas grid, and identify some critical key aspects that must be handled while developing the new smart energy paradigm.

We present the architecture and design of the IANOS scheduling framework. The goal of the new Grid scheduling system is to provide a general job submission framework allowing optimal positioning and scheduling of HPCN applications. The scheduling algorithms used to calculate best-suited resources are based on an objective cost function that exploits information on the parameterization of applications and resources. This standard-based, interoperable scheduling framework comprises four general web services and three modules. The middleware is complemented with one client and one admin console. The implementation is based on proposed Grid and Web services standards (WSRF, WS-Agreement, JSDL, and GLUE). It is agnostic to a specific Grid middleware. The beta version of IANOS has been tested and integrated with UNICORE. The validation of IANOS is in progress by running different types of HPCN applications on a large-scale Grid testbed.

Abstract In this paper, a general mathematical model for the dynamic simulation of a single-effect LiBr/water absorption chiller is presented. The model is based on mass and energy balances applied to the internal components of the machine, and it accounts for the non-steady behaviour due to thermal and mass storage in the components. The validation of the mathematical model is performed through experimental data collected on a commercial small-capacity water-cooled unit. Due to the peculiar technology adopted in the real chiller, a special effort was made to identify the appropriate values of the main physical parameters. The validation of the model is based on the values of the water temperature at the outlet of the machine, as no measurement inside the machine was possible; anyway, a consistency analysis applied to the internal parameters is also presented. The agreement between experimental and simulated results is very good, both on a daily and on a seasonal basis.

Abstract In this work, we intend to solve the equations governing two laminar isothermal or non-isothermal coaxial plane jets with variable density in an ambient fluid at rest in order to study the initial conditions influence (i.e. the nozzles ejection conditions) on the jet characteristic parameters. A finite difference method is developed to solve the dimensionless Navier–Stokes and energy equations resulting from some assumptions. The discussion about the results relates primarily to the concentration core length according to the nozzles thicknesses ratios. The influences of the gas velocity and temperature resulting from the external nozzle are also examined. This made it possible to deduce correlations of practical use between these parameters in order to apply them in engineering processes.

Abstract This paper aims to present a feasibility study of the innovative plant for methanol synthesis from carbon dioxide-sequestered by fossil fuel power plant and hydrogen, which is produced by water electrolyzer employing the over-production on the electrical grid. The thermo-economic analysis is performed in the framework of the MefCO2 H2020 EU project and it is referred to the German economic scenario, properly taking into account the real market costs and cost functions for different components of the plant. Three different plant capacities for methanol production (4000 10,000 and 50,000 ton/year) have been investigated, assuming an average cost for electrical energy to feed electrolysers and analyzing the influence of the most significant parameters (oxygen selling option, methanol selling price and electrolysers’ capital cost) on the profitability of the plant. The analysis has been performed in W-ECoMP, software for the thermo-economic analysis and plant optimization developed by the University of Genoa.