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Abstract Economically harvesting energy from a microbial fuel cell (MFC), increasing its electrical power production, and developing its role as a practical energy supply, needs a low-cost and high-performance design of the MFC compartments. According to this strategy, a novel monolithic membrane electrode assembly (MEA) was fabricated and evaluated as an air–cathode in a single-chamber MFC (SCMFC). The MEA was made of bacterial cellulose (BC), conductive multi-walled carbon nanotubes (CNT), and nano-zycosil (NZ). BC, as a nano-celluloses with oxygen barrier property, can maintain anaerobic conditions for the anode compartment. Binder-less CNT coating on BC avoids costly binders such as poly-tetra fluoro ethylene (PTFE) and Nafion and decreases the MEA charge transfer resistance. NZ, as a very cheap modifier, not only prevents the anolyte leakage but also provides more MEA’s active sites for the oxygen reduction reaction (ORR). The electrochemical performance of the MEA was compared to a PTFE- based gas diffusion electrode (GDE) in the SCMFC. The MEA cell provided a pulse power density of 1790 mW/m2, roughly twice as high as the pulse power density of GDE (920 mW/m2). SCMFC’s internal resistance decreased from 1.84 KΩ (with GDE) to 0.8 KΩ (with MEA). Also, the cell’s columbic efficiency increased from 4.2% (with GDE) to11.7% (with MEA). Additionally, the capacitance of the MEA (65 mF) was much higher than the value for GDE (0.73 mF). Thus, the MEA compared to the GDE showed higher performance in the SCMFC for electricity generation and wastewater treatment at a lower cost.

Abstract In Concentrated Solar Power Plants, steam turbines controlled with standard Proportional Integrative Derivative (PID) methods may suffer from performance downgrading in power generation when the steam conditions deviate from nominal ones. An enhancement of standard steam turbine controller can be the key to achieve optimal performance also in non-nominal steam conditions. This paper presents the improvement of the PID control concept by exploiting Fuzzy Logic, an artificial intelligence technique that allows taking into account the human experience and knowledge on the system behavior. A real Concentrated Solar Power Plant has been modeled focusing on generated power control loop, its stability and performance analysis, knowledge useful to design a Fuzzy Inference System. A fuzzy logic controller is proposed to continuously adapt the PID parameters, to improve the steam turbine governor action. Its performance is compared to the classical PID tuned according to three different approaches. The fuzzy logic PID controller extends the simplicity of PID and adapts the control action to actual operating condition by providing the system with a sort of “decision-making skill”. The possibility to design implementable algorithms on a Programmable Logic Controller, which have stringent computational speed and memory requirements, has been explicitly taken into account in the developed work, through the minimization of the controller complexity with a reduced number of fuzzy sets and fuzzy rules within the fuzzy inference system.

Abstract This paper presents an original model capable of simulating the thermal behavior of a vanadium redox flow battery stack in standby condition, i.e. without power and reactant flow, where the temperature distribution in the cells evolves because of ions crossover through the membrane, Joule losses due to shunt currents and inherent self-discharge effects. For the first time, a model is presented that is capable of simulating the cell temperature distribution in the stack and its time evolution considering all above effects. The model is applied to a 9 kW/40-cell stack and validated against measurements from a thermal imager. Numerical results show that shunt currents affect the temperature in the stack and can be responsible for local increases of cell temperatures up to 10 °C if the solutions are initially at high state of charge. This effect can be critical if standby occurs after a period of operation, with the electrolyte stack temperature markedly higher than air temperature. In addition, results show that shunt currents can play a major role in the thermal behavior of compact stacks, based on new materials capable of high power density and low ion crossover. The model presented here can constitute the basis for advanced cooling strategies.

Abstract Small Mediterranean islands are remote, off-grid communities characterized by carbon intensive electricity systems coupled with high energy consuming desalination technologies to produce potable water. The aim of this study is to propose a novel dynamic, multi-objective optimization approach for improving the sustainability of small islands through the introduction of renewable energy sources. The main contributions of our approach include: (i) dynamic modelling of desalination plant operations, (ii) joint optimization of system design and operations, (iii) multi-objective optimization to explore trade-offs between potentially conflicting objectives. We test our approach on the real case study of the Italian Ustica island by means of a comparative analysis with a traditional non-dynamic, least cost optimization approach. Numerical results show the effectiveness of our approach in identifying optimal system configurations, which outperform the traditional design with respect to different sustainability indicators, limiting the structural interventions, the investment costs and the environmental impacts. In particular, the optimal dynamic solutions able to satisfy the whole water demand allow high levels of penetration of renewable energy sources (up to more than 40%) to be reached, reducing the net present cost by about 2–3 M€ and the CO2 emissions by more than 200 tons/y.

Abstract We present a general method, based on controlled static aberrations induced in the reflectors, to boost receiver performances in solar concentrators. Imaging mirrors coupled with dense arrays suffer from severe performance degradation since the solar irradiance distribution is bell-shaped: mismatch losses occur in particular when the cells are series connected. The method consists in computing static deformations of the reflecting surfaces that can produce, for an adopted concentration ratio, a light spot matching the receiver features better than conventional reflectors. The surfaces and the deformations have been analytically described employing the Zernike polynomials formalism. The concept here described can be applied to a variety of optical configurations and collecting areas. As an example, we extensively investigated a dense array photovoltaic concentrator, dimensioned for a nominal power of about 10 kWe. The “flat” distribution of light we obtain can exploit the PV device cells close to their efficiency limit. A significant gain is thus obtained, with no need of secondary optics or complex dish segmentation and of special features in the receiver electrical scheme. In the design, based on seven 2.6 m mirrors, we addressed also non-optical aspects as the receiver and the supporting mechanics. Optical and mechanical tolerances are demonstrated not to exceed accurate, but conventional, industrial standards.

Abstract In recent years, distributed energy systems (DESs) have been recognized as a promising option for sustainable development of future energy systems, and their application has increased rapidly with supportive policies and financial incentives. With growing concerns on global warming and depletion of fossil fuels, design optimization of DESs through economic assessments for short-run benefits only is not sufficient, while application of exergy principles can improve the efficiency in energy resource use for long-run sustainability of energy supply. The innovation of this paper is to investigate exergy in DES design to attain rational use of energy resources including renewables by considering energy qualities of supply and demand. By using low-temperature sources for low-quality thermal demand, the waste of high-quality energy can be reduced, and the overall exergy efficiency can be increased. The goal of the design optimization problem is to determine types, numbers and sizes of energy devices in DESs to reduce the total annual cost and increase the overall exergy efficiency. Based on a pre-established DES superstructure with multiple energy devices such as combined heat and power and PV, a multi-objective linear problem is formulated. In modeling of energy devices, the novelty is that the entire available size ranges and the variation of their efficiencies, capital and operation and maintenance costs with sizes are considered. The operation of energy devices is modeled based on previous work on DES operation optimization. By minimizing a weighted sum of the total annual cost and primary exergy input, the problem is solved by branch-and-cut. Numerical results show that the Pareto frontier provides good balancing solutions for planners based on economic and sustainability priorities. The total annual cost and primary exergy input of DESs with optimized configurations are reduced by 21–36% as compared with conventional energy supply systems, where grid power is used for the electricity demand, and gas-fired boilers and electric chillers fed by grid power for thermal demand. A sensitivity analysis is also carried out to analyze the influence of energy prices and energy demand variation on the optimized DES configurations.

Abstract The methodology, the site and the dataset as well as the emissions scenario considered in the weather file definition influence the numerical evaluation of efficiency measures resilience. With a complete statistical and critical approach, the paper analyzes the importance of these aspects by means of a residential case study simulated in Benevento, a city of south Italy. Using data monitored from 2015 to 2020, a current weather file is built with different methodologies. The comparison indicates that there is not repeatability of the year chosen as a reference for the various months and thus the resolution of the building energy balance could bring different results. Some future climate projections are also generated on medium (2050 s) and long (2080 s) term considering different emission scenarios. With long term projection, the heating degree days are reduced also of − 21% meanwhile the cooling degree days are more than double compared with the current condition. This suggests a remarked transition towards a dominant cooling climate for Benevento. Moreover, when the climate change is considered, the insulation intervention and the installation of double glazed low emissive window is not resilient because the heating energy need decreases also of −56%, but the cooling energy need increases of + 62% (2080 s). If the efficiency measures include also the cool roof and the external shadings, the cooling demand could be reduced until –33% in some scenarios (e.g. RCP 4.5-50th percentile) and increased (+31%) in some others (e.g. 2080 s).

Abstract Air temperature is an effective predictor for electricity demand, especially during hot periods where the need of electric air conditioning can be high. This paper presents for the first time an assessment of the use of seasonal climate forecasts of temperature for medium-term electricity demand prediction. The retrospective seasonal climate forecasts provided by ECWMF (European Centre for Medium-Range Weather Forecasts) are used to forecast the June–July Italian electricity demand for the period 1990–2007. We find a relationship between summer (June–July) average temperature patterns over Europe and Italian electricity demand using both a linear and non-linear regression approach. With the aim to evaluate the potential usefulness of the information contained into the climate ensemble forecast, the analysis is extended considering a probabilistic approach. Results show that, especially in the Center-South of Italy, seasonal forecasts of temperature issued in May lead to a significant correlation coefficient of electricity demand greater than 0.6 for the summer period. The average correlation obtained from seasonal forecasts is 0.53 for the temperature predicted in May and 0.19 for the predictions issued in April for the linear model, while the non-linear approach leads to the coefficients of 0.62 and 0.36 respectively. For the probabilistic approach, seasonal forecasts exhibit a positive and significant skill-score in predicting the demand above/below the upper/lower tercile in many regions. This work is a significant progress in understanding the relationship between temperature and electricity demand. It is shown that much of the predictable electricity demand anomaly over Italy is connected with so-called heat-waves (i.e. long lasting positive temperature anomalies) over Europe.