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With the increasing needs of clean water supplies, the use of biomass wastes and residues for environmental remediation is essential for environmental sustainability. In this study, the residues from winery and citrus juice industries, namely grape skin and orange peel, respectively, were first converted to hydrochars by hydrothermal carbonization (HTC) and then a cationic dye (methylene blue) adsorption was studied on hydrochars. Hydrochars from both feedstocks were produced at three different temperatures (180, 220, and 250 °C) and a fixed residence time (1 h) to evaluate the hydrochar’s performance on the dye adsorption. The hydrochars were characterized in terms of their pH, pH at point of zero charge (pHPZC), surface functionalities, and surface area. A batch adsorption study of the dye was carried out with variable adsorbate concentration, pH, and temperature. Two adsorption isotherms namely Langmuir and Freundlich models were fitted at 4, 20, and 36 °C. The thermodynamic properties of adsorption (Gibbs free energy (ΔG), enthalpy (ΔH) and entropy (ΔS)) were evaluated from the isotherms fittings. Results showed that the dye adsorption on both hydrochars was significant and followed Langmuir isotherm. The maximum adsorption capacity on citrus waste hydrochar was higher than the winery waste hydrochar at any corresponding HTC temperature. Although hydrochars showed the lowest surface area (46.16 ± 0.11 and 34.08 ± 1.23 m2/g for citrus and winery wastes, respectively) at 180 °C, their adsorption was the highest, owing to their maximum density of total oxygen functional groups (23.24 ± 0.22 and 32.69 ± 1.39 µmol/m2 for citrus and winery wastes, respectively), which decreased with the increase in HTC temperature. This research shows a sustainable route for the production of highly effective adsorbent materials at lower HTC temperatures from citrus and winery wastes.

For the agricultural sector to develop sustainably in the future, progress toward more environmentally friendly technologies and methods is crucial. It is necessary to increase output while reducing the demand for energy, agrochemicals, and water resources. Although greenhouses can be utilized successfully for this purpose, significant technical advancements are required, especially when it comes to heating, to lower the use of fossil fuels and boost energy efficiency. Microwaves can warm plants without heating the entire greenhouse volume, which takes a significant amount of energy to compensate for heat loss in the outdoor environment. In this paper, through a thorough examination of the state of the art, a general overview of novel greenhouse heating systems based on radiation is reported. First, the strengths and weaknesses of microwave heating are discussed, and finally, the use of microwaves for soil sterilization is examined. All outcomes suggest these irradiation-based technologies can contribute significantly to energetically sustainable agriculture; moreover, they can be used to increase plant comfort.

The perennial rhizomatous grass giant reed (Arundo donax L.) can be exploited to produce hydrogen by dark fermentation. This implies a high availability of simple sugars, like glucose and xylose, and, thus, a pre-treatment is necessary to remove lignin and expose the holocellulose to enzymatic attack. This study aimed at evaluating the hydrogen production from giant reed hydrolysates. Giant reed dry meal was pre-treated with diluted NaOH (1.2% weight/weight), then the solid fraction was separated from the alkaline black liquor by filtration, enzymatically hydrolyzed with a cellulase blend (Cellic CTec2), and fermented in mesophilic batch conditions with a microbial consortium derived from pig slurry. The impact on hydrogen yield of initial pH was evaluated by comparing the hydrogen production from hydrolysates with not adjusted (5.3) or adjusted initial pH (8.7) using NaOH or alkaline black liquor. The highest hydrogen yield, 2.0 mol/mol of hexoses, was obtained with alkaline initial pH 8.7, regardless of how the pH adjustment was managed. The yield was 39% higher than that obtained in reactors with initial pH 5.3. In conclusion, thermo-alkaline pre-treatment followed by enzymatic saccharification and initial pH adjustment at 8.7 with the black liquor remaining after pre-treatment is a promising strategy to produce hydrogen from giant reeds in dark fermentation.

Hydrothermal depolymerization of lignin-rich streams (LRS) from lignocellulosic ethanol was successfully carried out in a lab-scale batch reactors unit. A partial depolymerization into oligomers and monomers was achieved using subcritical water as reaction medium. The influence of temperature (300–350–370 °C) and time (5–10 minutes) was investigated to identify the optimal condition on the monomers yields in the lighter biocrude (BC1) and aqueous phase (AP) fractions, focusing on specific phenolic classes as well as carboxylic acids and alcohols. The effect of base catalyzed reactions (2–4 wt. % of KOH) was compared to the control tests as well as to acid-catalyzed reactions obtained with a biphasic medium of supercritical carbon dioxide (sCO2) and subcritical water. KOH addition resulted in enhanced overall depolymerization without showing a strong influence on the phenolic generation, whereas sCO2 demonstrated higher phenolic selectivity even though no effect was observed on the overall products mass yields. In conclusion, a comparison between two different biocrude collection procedures was carried out in order to understand how the selected chemical extraction mode influences the distribution of compounds between BC1 and AP.

The flow ripple in an internal gear pump was measured by means of a new instantaneous high-pressure flowmeter. The flowmeter consists of two pressure sensors mounted on a piece of the straight steel pump delivery line, and a variable-diameter orifice was installed along such a line, downstream of the flowmeter, to generate a variable load. Three distinct configurations of the high-pressure flowmeter, characterized by a different distance between the pressure transducers, were analyzed. Furthermore, a comprehensive fluid dynamic 3D model of the pump and of its high-pressure delivery line was developed and validated in terms of both the delivery pressure and the flow ripple for different pump working conditions. For the three examined configurations of the flowmeter, the measured flowrate time histories matched the corresponding numerical distributions at the various operating points. Finally, the validated 3D model was applied to predict the incomplete filling working of the interteeth chambers, and the obtained numerical pressure time histories along the delivery line were used, as input data, to assess the reliability of the flowmeter algorithm even in these severe operating conditions.

Water scarcity is a pressing global issue driving the need for efficient and sustainable water reuse and desalination technologies. In the last two decades, humidification–dehumidification (HDH) has emerged as a promising method for small-scale and decentralized systems. This paper presents a comprehensive review of recent scientific literature highlighting key advancements, challenges, and potential future directions of HDH research. Because the HDH process suffers from low heat and mass transfer, as well as thermodynamic limitations due to the mild operating conditions, this work indicates three main strategies for HDH enhancement: (1) Advanced Heat and Mass Transfer Techniques, (2) Integration with Other Technologies, and (3) Optimization of System Operative Conditions. Particularly for advanced HDH systems, the reference GOR values exceed 3, and certain studies have demonstrated the potential to achieve even higher values, approaching 10. In terms of recovery ratio, there appear to be no significant process constraints, as recycling the brine prepared in innovative schemes can surpass values of 50%. Considering electricity costs, the reference range falls between 1 and 3 kWh m–3. Notably, multi-stage processes and system couplings can lead to increased pressure drops and, consequently, higher electricity costs. Although consistent data are lacking, a baseline SEC reference value is approximately 360 kJ kg–1, corresponding to 100 kWh m–3. For comparable SEC data, it is advisable to incorporate both thermal and electric inputs, using a reference power plant efficiency of 0.4 in converting thermal duty to electrical power. When considering the utilization of low-temperature solar and waste heat, the proposed exergy-based comparison of the process is vital; this perspective reveals that a low-carbon HDH desalination domain, with II-law efficiencies surpassing 0.10, can be achieved.

The transition towards renewable energy sources and “green” technologies for energy generation and storage is expected to mitigate the climate emergency in the coming years [...]

Conventional activated sludge systems, still widely used to treat wastewater, produce large amounts of solid waste that is commonly landfilled or incinerated. This study addresses the potential use of Hydrothermal Carbonization (HTC) to valorize sewage sludge residues examining the properties of hydrochars depending on HTC process conditions and sewage sludge withdrawal point. With increasing HTC severity (process residence time and temperature), solid yield, total Chemical Oxygen Demand (COD) and solid pH decrease while ash content increases. Hydrochars produced from primary (thickened) and secondary (digested and dewatered) sludge show peculiar distinct properties. Hydrochars produced from thickened sludge show good fuel properties in terms of Higher Heating Value (HHV) and reduced ash content. However, relatively high volatile matter and O:C and H:C ratios result in thermal reactivity significantly higher than typical coals. Both series of carbonized secondary sludges show neutral pH, low COD, enhanced phosphorous content and low heavy metals concentration: as a whole, they show properties compatible with their use as soil amendments.