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Abstract This paper presents a non-stoichiometric equilibrium model for the simulation of biomass downdraft gasifiers. The chemical equilibrium is determined by minimizing the Gibbs free energy. Five elements characterize the biomass and 15 chemical species are considered in the syngas. The model calculates the lower heating value of the syngas and the relative abundances of gasification products. An advantage of this model is that it can easily calculate not only the concentrations of the main gasification products, but also the concentrations of minor product, especially the pollutant chemical species containing Nitrogen and Sulfur. To analyse the model behaviour, a sensitivity analysis on process parameters is presented. The model is validated by comparing its results with the results of simulation carried out with a stoichiometric model and with experimental data found in literature. Finally, the model is applied to the study of the gasification of forest waste.

AbstractAn analysis of Italy's National Energy Budget of in the last decades shows the important role of the civil sector and the impact of fossil fuels in air conditioning systems. The high consumption of fossil fuel is Likely due to the predominance of plants with conventional boilers in buildings. Based on the analysis of the Exergy flow this paper proposes the Cogeneration technology for Air conditioning systems with heat pumps to implement the Rational Use of Energy. The feasibility of a retrofit intervention on existing systems of a large size is shown, by the projection of a cogeneration plant for the buildings of the University of Cagliari currently equipped with fossil fuel plants.

AbstractThe penetration of renewable sources, particularly wind and solar, into the grid has been increasing in recent years. As a consequence, there have been serious concerns over reliable and safety operation of power systems. One possible solution, to improve grid stability, is to integrate energy storage devices into power system network: storing energy produced in periods of low demand to later use, ensuring full exploitation of intermittent available sources. Focusing on stand-alone photovoltaic (PV) energy system, energy storage is needed with the purpose of ensuring continuous power flow, to minimize or, if anything, to neglect electrical grid supply.A comprehensive study on a hybrid stand-alone photovoltaic power system using two different energy storage technologies has been performed. This study examines the feasibility of replacing electricity provided by the grid with hybrid system to meet household demand. This paper is a part of an experimental and a theoretical study which is currently under development at University of Bologna. A test facility is under construction, at the University of Bologna, for the experimental characterization of the cogenerative performance of small scale hybrid power systems, composed of micro-CHP systems of different technologies : a Micro Rankine Cycles (MRC), a Proton Exchange Membrane Fuel Cells (PEM-FC), a battery, an electrolyzer and a heat recovery subsystem. The test set-up is also integrated with an external load simulator, in order to generate variable load profiles.This paper presents the theoretical results of the performance simulations developed considering an hybrid system consisting on a photovoltaic array (PV), electrochemical batteries (B) and electrolyzer (HY) with a H2 tank and a Proton Exchange Membrane Fuel Cell (PEM-FC) stack, in case of a household electrical demand. The performance of this system have been evaluated by the use of a calculation code, in-house developed by University of Bologna; future activities will be the tuning of the software with the experimental results, in order to realize a code able to define the correct size of each sub-system, ones the load profile of the utility is known or estimated.

AbstractVineyard pruning is a potential lignocellulosic feedstock for bioethanol production from agricultural woody residues, due to its high sugar content and ready availability in whole Europe. Ethanol production from lignocellulosic biomass requires a pretreatment step and then enzymatic hydrolysis process to release sugars for fermentation to ethanol. In this work, alkaline pretreatment with NaOH on vineyard residues was investigated on laboratory scale. The raw material was firstly characterized in order to determine cellulose, hemicellulose and lignin content, using the standard laboratory analytical procedures for biomass analysis provided by the National Renewable Energy Laboratory (NREL). Then, based on Response Surface Methodology tool (RSM), a Box-Behnken model was chosen to define a design of experiments (DoE) in terms of the three independent variables that influence the process: the NaOH concentration, the reaction time and the temperature of the pretreatment process. According to the design, 15 samples of raw material were submitted to alkaline pretreatment and subsequent enzymatic hydrolysis and the glucose yield from whole process was calculated. The statistical optimization was carried out with Minitab 17 software, in order to determine the best operative pretreatment condition by maximizing the glucose yield from enzymatic hydrolysis.Results show that the best glucose yield was obtained at the highest sodium hydroxide concentration and temperature of the reaction; this condition allowed to achieve very significant glucose yield thanks to lignin removal performed with the pretreatment.

AbstractAlthough the application of internal insulation to existing perimeter walls poses significant challenges in terms of building physics and loss of habitable space, it is sometimes an inevitable choice because of practical or legislative constraints. Innovative solutions are then required to deliver satisfying performances and reduce nuisance to inhabitants of residential buildings in case they are going to remain in their flats during the retrofit works.Three systems for inner thermal retrofitting purposes have been designed and produced as prototypes. Two of them are composed by silica aerogel containing fibrous material: the first one is a rigid flat laminated panel, the second one is a rollable solution with a fabric finishing layer. The third insulating system is a perlite based board with a hydrophobic layer. All the materials composing the retrofit solutions have been characterized by means of laboratory tests in order to measure their main hygrothermal properties. In fact, some parameters are fundamental for determining the hygrothermal performance of the composite systems: thermal conductivity, at dry and wet state (moisture dependant), water vapour diffusion resistance factor, hygroscopic sorption at isotherm condition and water absorption coefficient. All those measured data were necessary for optimizing the solutions, guaranteeing energy efficiency and vapour open layers to systems that are intended for installation on existing walls.

Abstract European and Italian standards establish high levels of energy performance of buildings that have to be designed considering their energy balance near zero. To achieve this goal, the reduction of energy demand, attainable by improving energy efficiency of the construction, and the use of renewable energy available both on site and off site are effective solutions to be applied. In particular, in buildings that use energy produced from renewable sources, due to their unstable and unpredictable nature, having the right strategy to compensate the variations is essential. A technical solution reevaluated as a consequence of passive design principles, is to provide an adequate thermal inertia in order to store energy when it is offered and to use it when the source is not available. In these cases, the ability of construction elements to retain heat becomes fundamental as they contribute to maintain internal comfort conditions. This paper aims to investigate how various types of heating and cooling systems, based on different modes of heat transfer, are able to interact differently with the thermal mass of the building, producing a different level of its activation. The investigation considers a case study used to carry out dynamic simulation by means of DesignBuilder which is a user interface of EnergyPlus. The model consists of a building with elementary geometry and a single thermal zone, delimited by walls with outside thermal insulation and a heat accumulation layer inside. The variation of the internal temperature by using different types of conditioning system is analyzed in order to individuate the technology that takes the greatest advantages from the thermal mass.

Abstract The heating, ventilation and air conditioning plant of a historical valuable building in the centre of Vicenza (Italy) was retrofitted during 2007-2012 period. An underground water source electrical compression heat pump was installed with a monitoring and data logging system. In this paper the analysis of the performance data of the last three cooling seasons and the last two heating seasons (2014-2016) is developed. The analysis reveals that some critical aspects determined poor energy performance of the plant during the first operation period. Such issues and the technical solutions suggested by the Authors are presented in this work.

AbstractIn the last years, the number of installed biofuels power plants is increased in northern Italy, due to favorable legislation on renewable energy sources, posing the issue to assess the resulting environmental effects. The European legislation on emissions for renewable fuels power plants provides guidelines to be integrated in the local regulations; moreover, local authorities have to identify the critical power plants in terms of pollution and the key parameters to grant licenses for the future plants.The aim of this paper is to describe a methodology and the calculation routine developed to assess the environmental effects of biomass plants in terms of simple indexes. The used approach is based on the Cross-Media Effects described by a European Commission Reference Document. In particular, several indexes are introduced to cover the most relevant environmental effects, as: air toxicity, global warming, acidification, eutrophication and photochemical ozone creation. For every considered pollutant (such as NOx, CO, etc.) directly emitted by the power plant, specific factors have been identified, in order to calculate the contribution to the different environmental indexes. Finally, a numerical evaluation of different biomass power plants, installed in Emilia Romagna region, is provided, in order to assess their environmental cross-media potential and to compare such kind of power plants with large scale, fossil-fuelled power plants.