• Energy Research
• other engineering and technologies close
• JP close
• IRDB close

Cavity growth occurring with crack extension and coal consumption during UCG processes directly influences the gasification efficiency and the estimated subsidence and gas leakage to the surface. This report presents an evaluation of the gas energy recovery, coal consumption, and gasification cavity estimation using a proposed stoichiometric method to analyze the coal gasification reaction process. We defined the evaluation parameters of rate of energy recovery and investigated the effects of different parameters using UCG trials conducted with coal blocks and coal seams, adopting different Linking-hole methods and operational parameters. Analyses of results obtained from laboratory experiments and small-scale field trials using V-shaped and L-shaped linking holes, and Coaxial-hole UCG models show that the gasification of Linking-hole models yielded average calorific values of product gas as high as 10.26, 11.11 MJ/m3 (lab.), and 14.39 MJ/m3 (field.). In contrast, the Coaxial-hole models under experimental conditions yielded average calorific values of product gas as: 7.38, 4.70 MJ/m3 (lab.) and 6.66 MJ/m3 (field.). The cavity volume obtained with Coaxial models was about half of the volume obtained from Linking-hole models. Results obtained for these UCG systems show that the feed gas and linking-hole types can influence coal consumption and product gas energy. Fissure ratios were also investigated. Results confirmed major factors underpinning gasification efficiency. Linking-hole types strongly influenced the development of the oxidization surface and fracture cracks for subsequent combustion in the gasification zone. Estimated gas energy recovery results support experimental observations within an acceptable error range of about 10%. Moreover, this stoichiometric approach is simple and useful for evaluating the underground cavity during UCG. Based on these results, we proposed a definition of the energy recovery rate, combined with the obtained volumes of gasification cavities that provide a definition of energy recovery and UCG effects. UCGにおいては，炭層内のき裂進展に伴う燃焼空洞の拡大と石炭の消費が重要であり，これがガス化効率や安全性 (地盤沈下，ガス漏洩等) に大きく影響する。本研究では，ガス化効率，回収エネルギーとガス化空洞の評価方法として，化学量論および化学平衡に基づく評価手法を検討した。生成ガス組成と求めたガス化反応式から，石炭の消費量，ガス生産量等を推定する方法である。また，エネルギー回収率を定義し，UCG室内モデル実験及び露天炭鉱の炭層で行った小規模現場実験の結果を評価し，リンキングの方式や注入ガス等のパラメータがガス化効率やガス化空洞の成長に与える影響を検討した。リンキングの方式として，L字，V字，同軸型のUCG実験を行い，ガス化効率の違いと，その原因を明らかにした。すなわち，リンキング型と同軸型モデルを比較すると，リンキング型UCGモデルの方が発熱量が高く，平均発熱量では，前者が10.26/11.11 MJ/m3 (室内) ，14.39 MJ/m3 (現場) であった。一方，同軸型モデル試験では，7.38/4.70 MJ/m3 (室内) と6.66 MJ/m3 (現場) と低い値であった。実験後の空洞体積の直接評価結果でも，リンキング型の方がガス化領域が拡大していることを確認した。リンキング方式の方が，炭層内にき裂を連続的に進展させやすいためと考えられる。また，エネルギー回収率の評価では，実験前後の供試体質量差から求めたエネルギー回収率と比較検討を行った。その結果，両者の誤差は約10％で，検討した手法によりエネルギー回収率や燃焼ガス化領域の石炭消費量を推定できることがわかった。以上の結果より，検討した化学量論法よる回収エネルギー評価手法は簡便で，実用的であることが明らかになった。 Special Edition for Coal Energy Technology; Development and Utilization of Coal Energy

Abstract Numerical simulations of combined natural convection–conduction in a droplet of n-dodecane suspended from a thermocouple were carried out, taking into consideration evaporation, and the effect of thermocouple diameter on the evaporation characteristics was investigated. The calculated temperature history of the droplet is in good agreement with experimental results; both show that the rate of heating decreases with increasing thermocouple diameter. The maximum error in temperature due to the thermocouple increases linearly with increasing thermocouple diameter. Thus, in investigations involving a droplet suspended from a thermocouple, it is preferable to use a thermocouple with the smallest possible diameter.

It is of importance to develop the proper decontamination technique for decommissioning of nuclear plant. In this paper, in order to investigate the feasibility of plasma process operated at atmospheric pressure, cold experiments to remove the oxide film deposited on the AISI 304 surface under the BWR condition were carried out. After 4 minutes plasma irradiation, surface changed significantly to be converted into metal fluorides which can be scraped off easily. The removal rate due to fluorination reaction on surface depends strongly on the number density of fluorine atoms in plasma. In our experimental conditions, the maximum removal rate 0.22g-m-2 min-1 was obtained. From these results it is concluded that plasma decontamination method can be feasible.

Abstract Improvement for electrochemical luminescence (ECL) property of MgIn 2 O 4 is attempted by partial exchange of Mg 2+ ion in MgIn 2 O 4 to Ca 2+ ion. Mg 1− x Ca x In 2 O 4 solid solution was obtained in the region 0 x 1− x Ca x In 2 O 4 :Er 3+ increased with the increase in the ratio of Ca 2+ ion, and showed a peak at x =0.25 and then decreased steeply. ECL efficiency for other rare-earth ion-(RE:Sm, Eu, Ho) doped Mg 1− x Ca x In 2 O 4 also increased comparing with those for MgIn 2 O 4 :RE. This Ca 2+ addition effect on the ECL efficiency seems to be caused by the improvement of the efficiency for the impact activation.

AbstractReview: 55 refs.

Abstract This paper describes the improvements and verification of computational modeling for hexcan wall failures assumed to occur under core disruptive accident conditions of fast reactors. A series of out-of-pile experiments named SIMBATH has been analyzed by using the SIMMER-II code. The SIMBATH experiments used a thermite mixture to simulate fuel. The test geometry of SIMBATH ranged from single pin to 37-pin bundles. In this study, phenomena of hexcan wall failure found in a SIMBATH test were analyzed by SIMMER-II with model improvements. Although the original model of SIMMER-II did not calculate any hexcan wall failure, several model improvements made it possible to reproduce the hexcan wall melt-through with respect to the formation of an escape path for material movement as observed in the experiment. In this paper the model improvements and their significance are discussed for further model development of structure failure under the attack of molten fuel materials.

A simple expression for the apparent reaction rate of large wood char gasification with steam is proposed. Large char samples were gasified under steam atmosphere using a thermo-balance reactor. The apparent reaction rate was expressed as the product of the intrinsic rate and the effective factor. The effective factor was modified to include the effect of change in char diameter and intrinsic reaction rate during the reaction. Assuming uniform conversion ratio throughout a particle, the simplified reaction scheme was divided into three stages. In the initial stage, the local conversion ratio increases without particle shrinkage. In the middle stage, the particle shrinks following the shrinking core model without change in the local conversion ratio. In the final stage, the local conversion ratio increases without particle shrinkage. The validity of the modified effective value was confirmed by comparison with experimental results.