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Plastic film mulching (FM) became a general practice to enhance crop productivity and its net primary production (NPP), but it can increase greenhouse gas (GHG) emissions. The proper addition of organic amendments might effectively decrease the impact of FM on global warming. To evaluate the feasibility of biomass addition on decreasing this negative influence, cover crop biomass as a green manure was incorporated with different recycling levels (0-100% of aboveground biomass) under FM and no-mulching. The net global warming potential (GWP) which integrated with soil C stock change and GHG (N2O and CH4) fluxes with CO2-equivalent was evaluated during maize cultivation. Under the same biomass incorporation, FM significantly enhanced the grain productivity and NPP of maize by 22-61 and 18-58% over no-mulching, respectively. In contrast, FM also highly increased the respired C loss, which was 11-95% higher than NPP increase, over no-mulching. Irrespective with biomass recycling ratio and mulching system, negative NECB which indicates the decrease of soil C stock was observed, mainly due to big harvest removal. FM decreased more soil C stock by 57-158% over no-mulching, but its C stock was clearly increased with increasing biomass addition. FM significantly increased total N2O and CH4 fluxes by 4-61 and 140-600% over no-mulching, respectively. Soil C stock changes mainly decided net GWP scale, but N2O and CH4 fluxes negligibly influenced. As a result, FM highly increased net GWP over no-mulching, while this net GWP was clearly decreased with increasing biomass application. However, cover cropping, and its biomass recycling was not enough to compensate the negative impact of FM on global warming. Therefore, more biomass incorporation might be essential to compensate this negative effect of FM.

The current status and challenges associated with the production and utilization of cellulosic ethanol in Korea are reviewed in this paper. Cellulosic ethanol has emerged as a promising option for mitigating Korea's CO(2) emissions and enhancing its energy security. Korea's limited biomass resources is the most critical barrier to achieving its implementation targets for cellulosic ethanol. Efforts to identify new suitable biomass resources for cellulosic ethanol production are ongoing and intensive. Aquatic biomasses including macroalgae and plantation wastes collected in the Southeast Asia region have been found to have great potential as feedstocks for the production of cellulosic ethanol. R&D explorations into the development of technologies that can convert biomass materials to ethanol more efficiently also are underway. It is expected that cellulosic ethanol will be in supply from 2020 and that, by 2030, its use will have effectively reduced Korea's total gasoline consumption by 10%.

This paper presents experimental results of the impact of CO(2) co-feed on a gasification/pyrolysis process for various feedstocks (biomass, coal, and municipal solid waste (MSW)). Various feedstocks were thermo-gravimetrically characterized under various atmospheric conditions and heating rates. A substantial amount of char burn out was identified in the presence of CO(2) via a series of thermo-gravimetric analysis tests, which enabled high conversion of final mass (approximately 99%) to be achieved. The impact of CO(2) co-feed on the volatilization regime during the pyrolysis/gasification process was not apparent at a heating rate of 10-40 degrees C min(-1). However, the impact of CO(2) on the volatilization regime at a fast heating rate (950 degrees C min(-1)) was substantial. For example, significant enhancement in the generation of CO, by a factor of approximately 2, was observed in the presence of CO(2). The generation of major chemical species, such as CH(4) and C(2)H(4), were enhanced, but this was not as apparent as in the case with CO. In addition, introducing CO(2) to the pyrolysis/gasification process enabled the amount of condensable liquid hydrocarbons, such as tar (approximately 30-40%) to be significantly reduced in the presence of CO(2), in that injecting CO(2) into the pyrolysis/gasification process expedites cracking the volatilized chemical species. Experimental work confirmed that biomass and MSW could be feasible and desirable feedstocks for the pyrolysis/gasification process as these feedstocks can be easily treated compared to coal. To extend this understanding to a more practical level, various feedstocks were tested in a tubular reactor and drop tube reactor under various experimental conditions.

Abstract Bamboo has been considered a potential feedstock of energy for the future. It can be subjected to the pyrolysis for biofuels production. The thermogravimetric analysis (TGA) combined with differential thermogravimetric analysis (DTG) for bamboo was carried out prior to pyrolysis. The thermal degradation of bamboo was mainly between 230 and 420 °C. The conventional pyrolysis of bamboo was investigated in a bubbling fluidized-bed reactor using silica sand. The product distribution and composition of pyrolysis bio-oil were dependent on biomass component and operating conditions such as pyrolysis temperature, fluidization velocity, and particle size of biomass. The fractional catalytic pyrolysis of bamboo was also studied to upgrade the pyrolysis vapor, using HZSM-5 and red mud. The highest yield of bio-oil was 54.03 wt% compared to 49.14 wt% and 50.34 wt% of HZSM-5 and red mud catalyst, respectively. In the red mud catalytic pyrolysis, the oxygen content was rejected from pyrolysis vapor mostly via decarboxylation to produce more CO2 than CO; in contrast, for the HZSM-5 catalytic pyrolysis, the production of CO through decarbonylation was more favored than CO2. The main composition of catalytic pyrolysis bio-oil was 4-vinylphenol, which was employed as a raw material source to synthesize valuable material for energy storage.

Abstract A change in the thermal environment of an urban area affects health, living conditions, and energy consumption. In urban planning, urban parks are one of the methods for improving the thermal environment and saving cooling energy. Urban park construction can mitigate temperature, but it also causes urban development by increasing local attractiveness. To achieve efficient energy saving through parks in urban planning, the purpose of this study is to investigate the relationship between building energy consumption and urban characteristics both before and after the construction of an urban park. This study targeted Seoul's Gyeongui line forest, which was recently converted into a linear park on the former railway as an urban regeneration project. We analyzed the relationship between energy consumption and urban characteristics using a regression model, focusing on the changes before and after the construction. In this study, urban characteristics include environment, building physical characteristics, and economic variables. The results show that the construction of the urban park reduced not only temperature but also building energy consumption. The energy reduction effect of the park was limited to a marginal distance. Meanwhile, the urban park construction caused land prices to rise and prompted new development, and this changed the urban characteristics of the area and affected energy consumption. Despite changes in urban characteristics, urban park planning is an effective methods of reducing the energy consumption involved in cooling urban areas. We recommend comprehensive consideration of the urban factors when making park policy to reduce urban temperature and energy consumption.

The offshore wells are subject to hostile environments of such areas as the North Sea, GOM and the high arctic. The strong loop ocean currents and induced eddies can pose significant problems for deep-water well. Broadly divided ocean currents, surface currents, bottom currents and vertical currents, interact with the deep water well structures as one of environmental forces. One of the engineering challenges in deep water drilling is temperature gradient. In the past the temperature in the wellbore was ignored and an isothermal system was assumed because no practical means existed to determine the well bore temperature profile. But the fact is that the negative thermal gradient exists between surface to seafloor and it becomes positive below the seafloor. The extreme values could be as low as 40°F and as high as 150∼200°F. In addition to low temperature condition, the significant heat exchange also occurs for high temperature and geothermal reservoirs. The universal matrix form of implicit finite differential equations is introduced to predict the temperature profile of the fluid in the well and near-wellbore formation. This paper is to combine various factors together to derive a solver for the transient temperature modeling during the dirculation of riserless drilling, which can be the basis to describe the near-wellbore well stability under geo-thermal stress and predict the annular pressure during HPHT injection or production, which can also be used to including but not limited to the dynamic temperature profile and bottom-hole temperature, improving cementing program design, casing thermal stresses to be determined.

Sustainable aviation fuels (SAFs) can contribute reduce greenhouse gas emissions compared to conventional fuel. With the increasing SAFs demand, various generations of resources have been shifted from the 1st generation (oil crops), the 2nd generation (agricultural waste), to the 3rd generation (microalgae). Microalgae are the most suitable feedstock for jet biofuel production than other resources because of their productivity and capability to capture carbon dioxide. However, microalgae-based biofuel has a limitation of high freezing point. Recently, a jet biofuel derived from Euglena wax ester has been paying attention due to its low freezing point. Challenges still remain to enhance production yields in both upstream and downstream processes. Studies on downstream processes as well as techno-economic analysis on biofuel production using Euglena are highly limited to date. Economic aspects for the biofuel production will be ensured via valorization of industrial byproducts such as food wastes.

Abstract This paper is concerned with the neutronics analysis of extremely simplified recycling technologies of spent fuels in a small breed-and-burn fast reactor (B&BR). The discharged fuels of the first generation B&BR, which achieved an average burnup of 160 GWd/MTHM, were used to construct a second generation B&BR core. Two types of high proliferation resistant recycling technologies, melt refining and the newly suggested super-simplified melt and treatment, were applied to process and treat the discharged fuels. Because the burnup profile of discharged fuels varies largely depending on its position in the core, the recycling of the discharged fuels was also carried out by grouping them into recycling regions including 1, 3, and 6 recycling regions. In this study, the core performance of the 2nd generation B&BR loaded with the recycled fuel, which was produced by different recycling technologies and recycling regions, was analyzed and compared. An optimum fuel loading scheme was also adopted to maximize the performance of the 2nd generation B&BR in terms of the burnup reactivity change, core lifetime, and power profiles.

The deposition of ash - combustion residues - on superheaters and heat exchanger surfaces reduce their efficiency; this phenomenon was investigated for a large-scale waste-to-energy incineration facility. Over a period of six months, ash samples were collected from the plant, which included the bottom ash and deposits from the superheater, as well as flyash from the convective heat exchanger, the economiser and fabric filters. These were analysed for particle size, unburned carbon, elemental composition and surface morphology. Element partitioning was evident in the different combustion residues, as volatile metals, such as cadmium, antimony and arsenic, were found to be depleted in the bottom ash by the high combustion temperatures (1000+°C) and concentrated/enriched in the fabric filter ash (transferred by evaporation). Non-volatile elements by contrast were distributed equally in all locations (transported by particle entrainment). The heat exchanger deposits and fabric filter ash had elevated levels of alkali metals. 82% of flyash particles from the fabric filter were in the submicron range.