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AbstractA novel multifunctional conjugated polymer (RCP‐1) composed of an electron‐donating backbone (carbazole) and an electron‐accepting side chain (cyanoacetic acid) connected through conjugated vinylene and terthiophene has been synthesized and tested as a photosensitizer in two major molecule‐based solar cells, namely dye sensitized solar cells (DSSCs) and organic photovoltaic cells (OPVs). Promising initial results on overall power conversion efficiencies of 4.11% and 1.04% are obtained from the basic structure of DSSCs and OPVs based on RCP‐1, respectively. The well‐defined donor (D)‐acceptor (A) structure of RCP‐1 has made it possible, for the first time, to reach over 4% of power conversion efficiency in DSSCs with an organic polymer sensitizer and good operation stability.

One of main concepts involved in regional small nuclear reactors is unmanned remote control. Internet-based virtual private networks provide environments for the remote monitoring and control of geographically-dispersed systems, and with the advances in communication technologies, the potential of networks for real time control and automation becomes enormous. However, networked control has some problems. The most critical is delay in signal transmission, which degrades system stability and performance. Therefore, a networked control system should be designed to account for delay. This paper proposes some design approaches for a delay-tolerant system that can guarantee predetermined stability margins and performance. To accomplish this, the reactor plant is modeled with consideration of uncertainties. With this model, three kinds of controllers are developed using different methods. The designed systems are compared with respect to stability and performance, and a second-order controller designed using the table lookup method was found to give the most satisfactory results.

Abstract Energy harvesting in natural environment has attracted a great deal of attention to generate stable and continuous electrical energy. In this work, we proposed an advanced pyroelectric energy harvesting system by using form-stable phase change material (PCM) composites. The PCM composite connected pyro-electrode generated electrical polarization due to the change of external environment. Polyethylene glycol (PEG) and 1-tetradecanol (1-TD) composites with different phase transition field induced the temperature difference during light-on/-off process. Poly(vinylidene difluoride) (PVDF) was utilized for pyroelectric energy harvesting. The PVDF based pyro-electrode was applied changing the conditions of solar light irradiation and heat air flow. The PCM composites controlled the temperature fluctuation effectively and generated stable output electrical voltage and current. Numerical simulation was carried out to provided in-depth insight into the underlying physics of the system. We envisage that the developed thermal energy harvesting system can pave a way towards high-throughput and sustainable energy harvesting.

Abstract In this work, earth-abundant CZTSSe thin film solar cells were fabricated by sulfo-selenization of the Mo/Zn/Cu/Sn/Cu metallic precursors. The influences of morphological and compositional properties of the absorbers on performance of solar cells were investigated by tuning Cu content in the films. The Raman analysis showed that absorbers consist of a kesterite CZTSSe phase with ZnSe as a minor secondary phase. X-ray photoelectron spectroscopy (XPS) analyses revealed that the surfaces are Cu depleted and Zn enriched compared with the bulk composition of the absorbers. The results indicate that during sulfo-selenization the Cu diffused into the film and the Zn towards the film surface. The performance of the solar cells initially improved with the increasing of the Cu content and then decreased. By tuning the Cu content in the absorbers, the minority-carrier life time improved from 0.8 to 1.6 ns. The power conversion efficiency increased from 5.1 to 8.03% with fine controlling of Cu composition of the CZTSSe absorbers. The diode-ideality factors are higher than 2, suggesting an increased interfacial recombination in the devices. The high ideality-factors A and low minority carrier life times may originate from surface and bulk related defects, which in turn limits the Voc and the achievable high conversion efficiency for the CZTSSe thin film solar cells.

Several methods were known to observe the cloud height. Since the meteorological administration mainly has been using human eye method, an automatic cloud height observer is proposed to reduce human errors.The proposed cloud observer system is for the cloud automatic observation system which has been operating at weathers stations in Korea since 1993. The high hand camera is adapted to get high resolution images without a capture board that has the low resolution. And the man-made passive filter for extracting sky reign is replaced by the active filter using image processing. The famous BRISK matching is selected instead of the block mating to get more precise disparity form a pair of stereo image.The Cloud cover announced by the Korean Meteorological Agency is the eye observation result nowadays, even though an intelligent cloud observation system was supplied. The reason is the impermissible error in the observed data of the automatic observation system. The current system is applied a man-made passive filter has to be changed periodically due to the boundary transition, but the proposed system is maintenance-free, since the active filter using edge detection algorithm automatically adjusts itself. The measuring of disparity which is important to analyze spatial information, has improved up to the resolution of observing height is 100m by getting image data directly form the high resolution camera, the old resolution from the capture board. Also, the disparity analyzing method is changed to the BRISK matching algorithm instead of the block mating algorism to get more deliberate disparity analysis since the dimension of the block is too big relatively compare to the cloud in the stereo all sky image. The test results are acceptable range which is human observation value ± 10% since the resolution of observing height is 100m at lower cloud in the sky. The proposed system is conducting the comparison research to compare with the result of reading satellite images and ceilometer. 

The combustion possibility of Indonesia KBB coal as a pulverized fuel for a thermal power plant was studied with a thermogravimetric analysis (TGA), drop tube furnace (DTF) and ignition temperature (IT) tester. TGA results showed that combustion patterns of coal samples were divided into devolatilization and oxidation reactions, and the fixed carbon contained with minor content in high moisture KBB coal (HM KBB) was quickly burned at a lower temperature than that of bituminous C&A coal (Design C&A). The linear regression for the Arrhenius plot to the experimental data is very good, and activation energies for overall combustion of Design C&A and HM KBB are 63.19 and 81.89 kJ/mol, respectively. It was derived that activation energies of dry KBB coal (Dry KBB) produced through drying of HM KBB and its mixture (Dry KBB Mixture) are 79.82 and 61.66 kJ/mol in reciprocal proportion to specific surface area. Test results show that the volatile content contained in coal samples except for HM KBB with the lowest surface area significantly improved the combustion reactivity. The conversion behavior of the coals observed in DTF was similar to that reflected in TGA. DTF studies showed that the combustion of Dry KBB Mixture was also completed at a residence time of around 1 s and set temperature range of 1,200°C similar to commercial coal fired plant. Although Dry KBB has the highest conversion of the four coals, it was not appropriate as a single pulverized fuel of coal fired plant because its initial deformation (IDT) and ignition temperatures of about 1,088 and 198°C, respectively, were too low to cause slagging in boiler, and firing at the pulverizer. The high IDT of Dry KBB Mixture ash with minimum of 1,250°C is not expected to be associated with slagging and fouling in pulverized coal fired systems. The liability of spontaneous combustion of coal samples was increased with increasing the moisture and volatile contents whereas that of Dry KBB was the highest due to the high surface area. It was, therefore, proposed that the combustion of mixtures of Dry KBB with Design C&A was the most appropriate for the prevention of slagging and spontaneous combustion in pulverized coal fired boilers and has excellent combustion efficiency.

This paper presents a model predictive control (MPC)-based algorithm for rollover prevention of an autonomous electric road sweeper (AERS). For AERS, the basic function of autonomous driving is a path- and velocity-tracking control needed to make a vehicle follow given path and velocity profiles. On the other, the AERS adopts an articulated frame steering (AFS) mechanism which can make cornering behavior agile. Moreover, the tread of the AERS is narrow, and the height of the mass center is high. As a result, it is prone to roll over. For this reason, it is necessary to design a controller for path and velocity tracking and rollover prevention in order to improve maneuverability and roll safety of the AERS. A kinematic model was adopted as a vehicle one for the AERS. With the vehicle model, reference states of position and velocity were determined that are needed to make the AERS track the reference path and prevent rollover. With the vehicle model and reference states, an MPC-based motion controller was designed to optimize articulation angle and velocity commands. The load-transfer ratio (LTR) was used to measure a rollover propensity. To evaluate the proposed algorithm, a simulation was conducted for the U-turn scenario. Simulation results show that the proposed algorithm improves path tracking and prevents the rollover of the AERS.

Torrefaction is a thermal treatment process to pre-treat biomass at temperature of under an inert atmosphere. It was known that torrefaction process strongly depended on the decomposition temperature of the lignocellulosic constituents in biomass. In this work, the torrefaction characteristics of baggase has been studied. This study focuses on the relation between the energy yields, heating values, gas emission, volatile and ash constituents with torrefaction temperatures and times. The activation energies of baggase torrefaction has been studied by using TGA (Thermogravimetric Analyzer). From this work, it was seen that ash constituents and heating values were increased with torrefaction temperature, while volatile constituents and energy yields decreased. It was also found that carbon monoxide containing oxygen were decomposed at a lower temperature than those of hydrocarbon compounds, .

This paper presents a CFD analysis of three types of axial-flow magnesium-based automotive cooling fans. The numerical modeling was conducted for geometrically modified fan designs: one with no-beads, the second one with beads at the suction-side of the fan namely reverse-beads fan, and the third one with beads installed at the pressure-side of the fan namely forward-beads fan. The effect of geometric modifications of the fan blades on the volumetric flow rate, fan efficiency, and energy efficiency was investigated using Reynolds-averaged Navier-Stokes (RANS) equations following the multiple reference frame methodology. The fan with no-beads was fabricated using 3D printing technology and tested to measure the flow velocity. Subsequently, the fans with beads along with the no-beads fan designs were numerically analyzed. The volumetric flow rate, fan efficiency, and energy efficiency were quantified as a function of fan rotating speed. The results show that the reverse-beads fan produced a relatively more volumetric flow rate and energy-efficient compared to the forward-beads fan. Moreover, to further improve the performance of the reverse-beads fan, the location and size of the bead structure were varied along the radial direction of the fan blade. The optimized reverse-beads fan significantly improves the fan performance.