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Once previous industrial activity has ceased, brownfields are found in urban and suburban environments and managed in different ways ranging from being left untouched to total reconversion. These situations apply to large surface areas often impacted by residual diffuse pollution. Though significant and preventing any sensitive use, residual contamination does not necessarily require treatment. Moreover, conventional treatments show their technical and economic limits in these situations and gentle remediation options such as phytomanagement might appear more relevant to the management of those sites. Thus, these sites face up two major issues: managing moderate contamination levels and providing an alternative use of economic interest. This work proposes to assess a management strategy associating the phytoremediation of organic pollution along with the production of biomass for energy generation production. A 16-week controlled growth experiment was conducted on a soil substrate moderately impacted by multiple pollution (trace elements, mainly Zn and Pb, and hydrocarbons), by associating rhizodegradation with Medicago sativa or biomass production with Robinia pseudoacacia or Alnus incana in monocultures. The effect of a microbial inoculum amendment on the performances of these treatments was also evaluated. Results showed total hydrocarbons (TH), and to a lesser extent polycyclic aromatic hydrocarbons (PAH), concentrations decreased over time, whatever the plant cover. Good biomass production yields were achieved for both tree species in comparison with the control sample, even though R. pseudoacacia seemed to perform better. Furthermore, the quality of the biomass produced was in conformity with the thresholds set by the legislation concerning its use as a renewable energy source.

Two 4 L tubular microbial fuel cells (MFCs) were installed in a municipal wastewater treatment facility and operated for more than 400 days on primary effluents. Both MFCs removed 65-70% chemical oxygen demand (COD) at a hydraulic retention time (HRT) of 11 h and reduced about 50% suspended solids. The COD removal rates were about 0.4 (total) or 0.2 (soluble) kg m(-3) day(-1). They could handle fluctuation, such as emptying the anode for 1-3 days or different HRTs. The preliminary analysis of energy production and consumption indicated that the two MFCs could theoretically achieve a positive energy balance and energy consumption could be reduced using larger tubing connectors. Through linkage to a denitrifying MFC, the MFC system improved the removal of total nitrogen from 27.1 to 76.2%; however, the energy production substantially decreased because of organic consumption in the denitrifying MFC. Establishing a carbon (electron) balance revealed that sulfate reduction was a major electron scavenger (37-64%) and methane production played a very minor role (1.3-3.3%) in electron distribution. These results demonstrate the technical viability of MFC technology outside the laboratory and its potential advantages in low energy consumption, low sludge production, and energy recovery from wastes.

Meteorological forcing at the air-water interface is the main determinant of the heat balance of most lakes (Edinger et al., 1968; Sweers, 1976). Year-to-year changes in the weather therefore have a major effect on the thermal characteristics of lakes. However, lakes that differ with respect to their morphometry respond differently to these changes (Gorham, 1964), with deeper lakes integrating the effects of meteorological forcing over longer periods of time. Other important factors that can influence the thermal characteristics of lakes include hydraulic residence time, optical properties and landscape setting (e.g. Salonen et al., 1984; Fee et al., 1996; Livingstone et al., 1999). These factors modify the thermal responses of the lake to meteorological forcing (cf. Magnuson et al., 2004; Blenckner, 2005) and regulate the patterns of spatial coherence (Chapter 17) observed in the different regions (Livingstone, 1993; George et al., 2000; Livingstone and Dokulil, 2001; Jarvinen et al., 2002; Blenckner et al., 2004)

Two studies conducted in Guadeloupe (West Indies) and Réunion (Indian Ocean) islands were designed to investigate the benefits of producing sugarcane as an energy crop and to assess the influence of agroclimatic factors on energy efficiency, respectively. In this context, it is essential to know the low heating value of the dry above-ground biomass (LHVd, MJ/kg) and its energy yield (EY, MJ/m2) in order to select the best varieties and set up a payment method for growers. Eighteen Poaceae (sugarcane and Erianthus) cultivars were compared under wet tropical environmental conditions in Guadeloupe. Three sugarcane cultivars were studied in four contrasting environments in Réunion. The partition sampling and biomass measurement procedures were identical at both locations. Low heating value (LHV) predictions were achieved using near-infrared reflectance spectroscopy (NIRS) after specific calibration (Guadeloupe), or arithmetically after lignocellulosic compound prediction (Réunion). In both studies, LHV variability was very low and slightly dependent on the site, cultivar and above-ground biomass components (millable stalks and tops, and green and dead leaves). Considering the overall dry above-ground biomass (DAB, kg/m2), the LHVd was calculated by averaging 159 samples (mean 16.65 MJ/kg) in Guadeloupe and 315 samples (mean 16.45 MJ/kg) for Réunion. An excellent linear relationship between the DAB and its EY, regardless of cultivar, age and environment, was found (n = 474 and R² = 0.99). Sugarcane energy content assessment could thus be simplified by measuring the DAB, while enabling development of a faster method of payment for growers based on the DAB measurement and the correlation between DAB and EY. Finally, the findings of this study should allow growers to rapidly determine the commercial value of their sugarcane crops, and also enable purchasers to assess the amount of recoverable energy. (Résumé d'auteur)

We develop an open-source Python software integrating flexibility needs from Variable Renewable Energies (VREs) in the development of regional energy mixes. It provides a flexible and extensible tool to researchers/engineers, and for education/outreach. It aims at evaluating and optimizing energy deployment strategies with higher shares of VRE, assessing the impact of new technologies and of climate variability and conducting sensitivity studies. Specifically, to limit the algorithm’s complexity, we avoid solving a full-mix cost-minimization problem by taking the mean and variance of the renewable production–demand ratio as proxies to balance services. Second, observations of VRE technologies being typically too short or nonexistent, the hourly demand and production are estimated from climate time series and fitted to available observations. We illustrate e4clim’s potential with an optimal recommissioning-study of the 2015 Italian PV-wind mix testing different climate data sources and strategies and assessing the impact of climate variability and the robustness of the results.

Activated sludge from municipal wastewater treatment processes can be used directly for the production of biodegradable polyesters from the family of polyhydroxyalkanoates (PHAs). However, municipal activated sludge typically cannot accumulate PHAs to very high levels and often low yields of polymer produced on substrate are observed. In the present work, it was found that the presence of calcium promotes selective growth and enrichment of the PHA-storing biomass fraction and significantly improved both PHA contents and yields. Calcium addition resulted in PHA contents of 0.60 ± 0.03 gPHA/gVSS and average PHA yields on substrate of 0.49 ± 0.03 gCODPHA/gCODHAc compared to 0.35 ± 0.01 gPHA/gVSS and 0.19 ± 0.01 gCODPHA/gCODHAc without calcium addition. After 48 h, three times more PHA was produced compared to control experiments without calcium addition. Higher PHA content and selective biomass production is proposed to be a consequence of calcium dependent increased levels of passive acetate uptake. Such more efficient substrate uptake could be related to a formation of calcium acetate complexes. Findings lead to bioprocess methods to stimulate a short-term selective growth of PHA-storing microorganisms and this enables improvements to the techno-economic feasibility for municipal waste activated sludge to become a generic resource for industrial scale PHA production.

(1) The amount of plastic discharges in the environment has drastically increased in the last decades negatively affecting aquatic ecosystems, societies, and the world economy. The policies initiated to deal with this problem are insufficient and there is an urgency to initiate local actions based on a deep understanding of the factors involved. (2) This paper investigates the potential of massive open online courses (MOOCs) to spread environmental education. Therefore, the conclusions drawn from the implementation of a MOOC to combat the problem of marine litter in the world are presented. (3) This work describes the activity of 3632 participants from 64 countries taking an active role presenting useful tools, connecting them with the main world associations, and defining applied action plans in their local area. Pre- and post-questionnaires explore behavioral changes regarding the actions of participants to combat marine litter. The role of MOOCs is contrasted with social media, formal education, and informal education. (4) Findings suggest that MOOCs are useful instruments to promote environmental activism, and to develop local solutions to global problems, for example, clean beaches, supplanting plastic bottles, educational initiatives, and prohibition of single-use plastic.