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Abstract Liquefaction of poly-isoprene based rubber (PIR) was performed using ethanol as a solvent for the production of liquid fuel and chemicals. An autoclave batch reactor was used to perform the ethanolysis of PIR at different temperature ranges (250–375 °C), with different ethanol to PIR ratio (0.5:1 to 4:1), and at different reaction times (15–75mins). The experimental results showed that a maximum yield of 86 wt % was achieved at temperature of 325 °C, ethanol to PIR ratio 1/1, and reaction time of 30 min. This liquid oil yield is about 14% higher than the yield obtained from the pyrolysis of PIR at 500 °C and about 10% higher than the yield obtained from hydrothermal liquefaction of PIR at 375 °C. Moreover, the utilization of ethanol in the process was also incorporated and product yields were redefined. Furthermore, ethanol contributed to enhance the quality of liquid-oil, particularly in term of viscosity, acidity, and energy density. Furthermore, the FTIR analysis showed methyl and methylene were most dominating functional groups found in the liquid product and GCMS analysis identified that they were presented by alkenes, aromatics, and alkyls.

PurposeThe purpose of this paper is to outline a comprehensive picture of the coverage of various certification schemes and sustainability principles relating to the entire value‐added chain of biomass and bioenergy and comparing them accordingly.Design/methodology/approachA tri‐dimensional approach (sustainability issues; technical biomass conversion routes; physical trade flows) was developed for testing the coverage of various sustainability dimensions in different phases of the value‐added chain with the chosen certification schemes and sustainability principles.FindingsUsing the tri‐dimensional approach, a comparison of the chosen schemes and principles demonstrated that the application of existing schemes and the development of new ones have placed a major emphasis on the primary production of biomass. Economic and social dimensions related to biofuels and bioenergy processing and trade were either emphasised less or they were covered inadequately. In view of this, the schemes sometimes seem to ignore that the utilisation of renewable energy as such guarantee no positive or neutral climate impact and may not be economically sustainable, especially when bioenergy can often be more expensive than energy generated from fossil energy sources.Originality/valueThe analysis showed that the tri‐dimensional model is an applicable framework that could facilitate policy makers to formulate policies that comprehensively take into consideration the various sustainability dimensions throughout the entire value‐added chain, now and in the future. It can be applied to the future outlining and completion of certification schemes and sustainability principles for biomass and bioenergy, as well as in the testing of their applicability in the implementation.

Abstract As the part of a study to develop buparvaquone (BPQ) formulations for the treatment of cutaneous leishmaniasis, the topical delivery of BPQ and one of its prodrugs from a range of formulations was evaluated. In previous studies, BPQ and its prodrugs were shown to be potent antileishmanials in-vitro, with ED50 values in the nanomolar range. 3-Phosphono-oxymethyl-buparvaquone (3-POM-BPQ) was the most potent antileishmanial and was chosen, together with the parent drug, for further investigation. The ability of the parent and prodrug formulations to cross human and murine skin was tested in-vitro using the Franz diffusion cells. Formulations intended for topical application containing either BPQ or 3-POM-BPQ were developed using excipients that were either acceptable for topical use (GRAS or FDA inactive ingredients) or currently going through the regulatory process. BPQ was shown to penetrate both human epidermal membranes and full thickness BALB/c skin from a range of formulations (gels, emulsions). Similarly, 3-POM-BPQ penetrated full-thickness BALB/c skin from several gel formulations. In-vitro binding studies showed that BPQ bound melanin in a dose-dependent manner and preferably bound to delipidized skin over untreated BALB/c skin (on a weight to weight basis). The results confirm that BPQ and its prodrug 3-POM-BPQ can penetrate the skin from several formulations, making them potentially interesting candidates for further investigation of topical formulations using in-vivo models of cutaneous leishmaniasis.

The paper aims to analyse the relationship between energy prices (biodiesel, crude oil) and food commodities - vegetable oils used also as feedstock for biodiesel production. The econometric technique of price transmission, such as unit root test, cointegration test and vector error correction model, is applied to assess the interdependencies between energy prices and vegetable oil prices in Germany. Results suggest close price linkages between prices of vegetable oils and biodiesel and confirm that the vegetable oil prices drive the price dynamics of biodiesel. However, the simultaneous relationship is only revealed between biodiesel and soybean oil prices. The increase in crude oil prices is found to lead to an upward trend in the vegetable oils used for biodiesel production, thus influencing biodiesel prices as well.

With increasing concern over global climate change and rapid rise in energy consumption on the data-driven market, data centres are an important renewable energy target. As cooling contributes a substantial portion of the energy use of data centres, minimising the cooling energy demand in data centres is one of the main objectives for improving renewable energy. This paper investigates overall energy consumption and the energy efficiency of the cooling system for a data centre in Finland as a case study. The temporal energy consumption characteristics, cooling infrastructure and operation of the data centre are analysed. The main problems associated with cooling energy efficiency and the factors that may contribute toward higher efficiency are identified and further suggestions are put forward. Results are presented of an extensive evaluation of the energy performance of the study data centre with a view to energy recovery. The conclusion we can draw is that even though the analysed data centre demonstrat...

Most of the existed works on the radio resource allocation (RRA) problem commonly assume the channel-state information (CSI) can be perfectly obtained by the transmission source. However, such assumption is not practical in the realistic wireless systems. In this work, we consider the practical implementation issues of resource allocation in orthogonal frequency division multiple access (OFDMA) two-way relay networks: the inaccuracy of channel-state information (CSI) available to the source. Instead, only the estimated channel status is known by the source. In this context, a joint optimization of subcarrier pairing and allocation, relay selection, and transmit power allocation is formulated in OFDMA two-way amplify-and-forward relay networks. Moreover, the objective of this work is to minimize the energy consumption of the overall system. Further, to ensure the quality of service (QoS) or data rate requirement, the energy consumption must be minimized without compromising the QoS. Therefore, by applying convex optimization techniques, energy-efficient algorithms are developed with the objective to minimize the total transmit power with guaranteeing the required data rates. Through simulation studies, energy consumption performance of the systems under the proposed schemes is investigated. It can be observed that our proposed scheme can improve the energy consumption performance of the considered system.

Large-scale compressed air energy storage (CAES) is conventionally used in power systems. However, application of CAESs at the distribution level is limited because of differences in design and efficiency. On the other hand, application of electrical batteries suited for distribution networks (DNs) faces also challenges from high investment cost and significant degradation. In this regard, this paper presents the participation of an active distribution system equipped with a small-scale CAES (SCAES) in the day-ahead wholesale market. To make CAES applicable to DNs, thermal-electrical setting design of the SCAES coupled with a packed-bed heat exchanger is adopted in the operation of the grid, where SCAES performs as an energy storage for DNs to surpass existing deficiencies of battery banks. The electrical/thermal conversion rate has been modeled for the SCAES operation. Moreover, the operation strategy of the SCAES is optimally coordinated with an electric vehicle charging station (EVCS) as an alternative energy storage technology in deregulated DNs. To make EVCS simulation more realistic, Gaussian Copula probability distribution function is used to model the behavior of the EVCS. The results obtained from different case studies confirm the value of SCAES as a reliable energy storage technology for DNs.

Energy ecosystems are under a significant transition. Local flexibility marketplaces (LFM) and platforms are argued to have significant potential in contributing to such a transition. The purpose of this study was to answer the following research question: how do market conditions and stakeholders shape emerging LFM platform governance choices? We approached this objective with an exploratory single-case study by conducting ten semi-structured interviews with key stakeholders in the Finnish energy ecosystem. The results of the content and pattern analyses revealed the key challenges to LFM implementation such as the current regulatory treatment of flexibility, high costs of gadget installations, and ensuring sufficient liquidity in the market. In addition, we also demonstrated that despite such barriers, the Finnish ecosystem is largely pragmatic about LFMs’ in its midst. All in all, we contributed to the non-technological streams of LFM literature by developing an exhaustive framework with four distinctive dimensions (i.e., ecosystem readiness, value-creation logic, platform architecture and governance, platform competitiveness) for LFM development, which helps academics, practitioners, and policy-makers to understand how novel platforms emerge and develop.