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Continuous phosphorus discharges in bodies of water, generated by human activities, such as agriculture, domestic effluences or wastewater from industrial processes, produce contaminated water and eutrophication. For this reason, efficient and low-cost systems that can remove phosphorus from contaminated water are necessary. In addition, it is important to generate renewable energy such as the energy produced in biomass power plants, taking advantage of the available biomass waste in each place. When producing this renewable energy, the resulting ash is a residue that can be used for phosphorus removal by adsorption processes. Moreover, according to the concept of the circular economy, the ash waste generated in this bio energy process should be reduced as much as possible. One of the advantages of this research being that surplus phosphorus-laden ash can be reused as fertilizer in agricultural fields. Considering this, the efficiency of reed ash (RA) (Phragmites australis) has been analysed in batch experiments, as well as the effect of several parameters on the removal of phosphate, such as contact time, phosphate-ash ratio, ash dose and temperature. Significant results obtained show that RA can be used to improve water quality.

Abstract Worldwide the search for new raw materials that are suitable for the production of energy pellets is increasing. Each new raw material undergoes evaluation through various analytical processes and quality assessments before being considered for use as energy pellet. In recent times, the raw materials such as agricultural, forestry, and food waste, as well as the surpluses originating from the agri-food production have become very popular for the production of energy pellets. In this study, we evaluated the feasibility of using lignocellulosic raw materials such as chamomile waste, birch sawdust, pea waste, and soybean waste for the production of pellets. In this study, we focused on the production of thermal energy from pellets by assessing the pellets in accordance with the required standards. The results have shown that lignocellulosic raw materials can be used to produce good quality energy pellets. The proportion of individual raw materials determines the individual strength characteristics of pellets and the suitability of pellets to produce thermal energy.

Abstract The innovation of this research was a holistic approach to the problem of linking the biometric characteristics of six energy plants species and the distribution of moisture along the shoot‘ height and determination of linear models of particle sizes in relation to the moisture. The median biometric parameters values for growth phases I and II were as follows: shoot weight: 63 g and 65 g; stalk weight: 45.1 g and 43.8 g; plant length: 1273 mm and 2157 mm; shoot centre of gravity: 698 mm and 968 mm; slenderness ratio 147 and 215, respectively. For big bluestem and Spartina pectinata the largest values were for slenderness ratio and for phase II amounted to 403 and 410, respectively but most other parameters were the smallest values. Regarding the shoots’ growth, the greatest influence was on the stalks by increasing their lengths more than their diameters. The highest difference in the plant length between harvest terms was observed for Spartina pectinata which increased from 793 mm to 2257 mm (by 185%). The lengths of the Jerusalem artichoke, miscanthus and big bluestem plants also significantly increased: from 1345 mm to 2920 mm (117%), 1214 mm to 2065 mm (70%) and 1064 mm to 1779 mm (67%), respectively. Positive correlation coefficient values between parameters (shoot weight, leaf weight, stalk weight and plant length) indicate that to characterize of plant shoots the shoot mass and plant slenderness could be used. The Rosin-Rammler function fit the chopped plan material size distribution data with an R 2 = 0.909–0.991. All the biomass particle sizes belonged to the “very poorly sorted” category (2.00 mm ≤ σ ig ≤ 4.00 mm), and the particle size distributions were “fine skewed” (0.1 ≤ GS is ≤ 0.3) and “mesokurtic” (0.90 ≤ K gs ≤ 1.11). For grasses relation of particle sizes vs. moisture for phase II (August for Spartina and big bluestem or October for miscanthus) was inverted to phase I (June) with slope coefficients −0.11 and 0.09, respectively. For leaf plants direction of the relation was preserved, wherein for phase II (all plants harvested in October) the growth dynamic was lower than for phase I and slope coefficients of the lines were 0.17 and 0.04, respectively. Moisture content of leafy plants was high, and its distribution along the shoots’ heights was different than that for grasses. Varied values of particle size and weight of plant components, together with the change in moisture along the height of the plants, will impact the diversity of the dynamic loads of elements and working units of forage harvesters and can be useful to explain these results.

Skull measurements Sorex araneus were collected between 1953 and 2004 in Białowieża National Park, preserved in alcohol and stored in the zoological collection of the Mammal Research Institute, Polish Academy of Sciences, in Białowieża. The skull height, length and width (mm) of 502 S. araneus were measured using X-ray images of the alcohol-preserved specimens, as described by Lázaro et al. (2017). Climate parameters in Białowieża between 1952 and 2004 Mean temperatures (degrees Celsius), rainfall (mm), and the number of days with snow cover are routine measurements from the meteorological station in Białowieża (52.7070 N, 23.8479 E). We computed the soil moisture deficit from monthly temperatures and precipitation using the Watbug program (Willmott 1977). Lazáro, J., Dechmann, D.K.N., LaPoint, S., Wikelski, M., & Hertel, M. (2017). Profound reversible seasonal changes of individual skull size in a mammal. Current Biology, 27, R1089-R1107. Willmott, C. J. (1977). WATBUG: a FORTRAN IV algorithm for calculating the climatic water budget. CW Thornthwaite Associates Laboratory of Climatology, Publications in Climatology, 30, 1-55. We assesed the impact of the changes in climate on the overall skull size (the proxy of the overall body size) and the seasonal changes of skull height (Dehnel’s phenomenon) in skulls of the common shrew, Sorex araneus, collected over 50 years in the Białowieża Forest, E Poland. Overall skull size decreased, along with increasing temperatures and decreasing soil moisture, which determined the availability of the shrews’ main food source, earthworms. The magnitude of Dehnel’s phenomenon increased over time, indicating an increasing selection pressure on animals in winter. Two files include the data on 1) the size of the skulls of Sorex araneus collected in the Białowieża Forest between 1953 and 2004; and 2) the meteorological data from Białowieża, from 1952 to 2004.

Globally, sustainable procurement is seen as a crucial component of public sector sustainability initiatives. This research investigates the internal and external barriers to the implementation of sustainable procurement in China’s public sector. Primary data for this research were gathered using survey techniques from 287 respondents who were procurement officials at higher education institutions that are part of the public sector. Twelve hypotheses were developed based on the conceptual model and literature review and evaluated using SEM-AMOS in order to look at the correlations between the variables. The study’s findings demonstrate that employee competency, employee motivation, training programs, financial aspects, management commitment, government rules and regulations, unavailability of green products, supplier capacity, and third-party pressure statistically influence the sustainability of public procurement. At the same time, green practices, the ineffectiveness of green products, and prices of green items had statistically no significant influence on sustainability in public procurement. This is a crucial effort to identify the factors that influence sustainable purchasing in China’s public colleges. This study draws interest from stakeholders and adds to the scant body of knowledge on sustainability in developing nations. In addition, this research is crucial for creating a roadmap for China’s long-term sustainable development in the area of procurement.

The study proposes a comprehensive framework to support the development of green hydrogen production, including the establishment of legal and regulatory frameworks, investment incentives, and public-private partnerships. Using official and public data from government agencies, the potential of renewable energy sources is studied, and some reasonable assumptions are made so that a full study and evaluation of hydrogen production in the country can be done. The information here proves beyond a doubt that renewable energy makes a big difference in making green hydrogen. This makes the country a leader in the field of making green hydrogen. Based on what it found, this research suggests a way for the country to have a green hydrogen economy by 2050. It is done in three steps: using green hydrogen as a fuel for industry, using green hydrogen in fuel cells, and selling hydrogen. On the other hand, the research found that making green hydrogen that can be used in Iraq and other developing countries is hard. There are technological, economic, and social problems, as well as policy consequences, that need to be solved.

The article presents results of thermodynamic analysis using a zero-dimensional mathematical models of a negative CO2 emission power plant. The developed cycle of a negative CO2 emission power plant allows the production of electricity using gasified sewage sludge as a main fuel. The negative emission can be achieved by the use this type of fuel which is already a “zero-emissive” energy source. Together with carbon capture installation, there is a possibility to decrease CO2 emission below the “zero” level. Developed models of a novel gas cycle which use selected codes allow the prediction of basic parameters of thermodynamic cycles such as output power, efficiency, combustion composition, exhaust temperature, etc. The paper presents results of thermodynamic analysis of two novel cycles, called PDF0 and PFD1, by using different thermodynamic codes. A comparison of results obtained by three different codes offered the chance to verify results because the experimental data are currently not available. The comparison of predictions between three different software in the literature is something new, according to studies made by authors. For gross efficiency (54.74%, 55.18%, and 52.00%), there is a similar relationship for turbine power output (155.9 kW, 157.19 kW, and 148.16 kW). Additionally, the chemical energy rate of the fuel is taken into account, which ultimately results in higher efficiencies for flue gases with increased steam production. A similar trend is assessed for increased CO2 in the flue gas. The developed precise models are particularly important for a carbon capture and storage (CCS) energy system, where relatively new devices mutually cooperate and their thermodynamic parameters affect those devices. Proposed software employs extended a gas–steam turbine cycle to determine the effect of cycle into environment. First of all, it should be stated that there is a slight influence of the software used on the results obtained, but the basic tendencies are the same, which makes it possible to analyze various types of thermodynamic cycles. Secondly, the possibility of a negative CO2 emission power plant and the positive environmental impact of the proposed solution has been demonstrated, which is also a novelty in the area of thermodynamic cycles.

AbstractUnderstanding observed patterns of connectivity requires an understanding of the evolutionary processes that determine genetic structure among populations, with the most common models being associated with isolation by distance, allopatry or vicariance. Pinnipeds are annual breeders with the capacity for extensive range overlap during seasonal migrations, establishing the potential for the evolution of isolation by distance. Here, we assess the pattern of differentiation among six breeding colonies of the southern elephant seal, Mirounga leonina, based on mtDNA and 15 neutral microsatellite DNA markers, and consider measures of their demography and connectivity. We show that all breeding colonies are genetically divergent and that connectivity in this highly mobile pinniped is not strongly associated with geographic distance, but more likely linked to Holocene climate change and demographic processes. Estimates of divergence times between populations were all after the last glacial maximum, and there was evidence for directional migration in a clockwise pattern (with the prevailing current) around the Antarctic. We discuss the mechanisms by which climate change may have contributed to the contemporary genetic structure of southern elephant seal populations and the broader implications.