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Harmful Algal Blooms (HAB) are complex to manage due to their intermittent nature and their severe impact on the economy and human health. The conditions which promote HAB have not yet been fully explained, though climate change and anthropogenic intervention are pointed as significant factors. The rise of water temperature, the opening of new sea canals and the introduction of ship ballast waters all contribute to the dispersion and establishment of toxin-producing invasive species that promote the settling of emergent toxins in the food-chain. Tetrodotoxin, ciguatoxin, palytoxin and cyclic imines are commonly reported in warm waters but have also caused poisoning incidents in temperate zones. There is evidence that monitoring for these toxins exclusively in bivalves is simplistic and underestimates the risk to public health, since new vectors have been reported for these toxins and as well for regulated toxins such as PSTs and DSTs. In order to avoid public health impacts, there is a need for adequate monitoring programs, a need for establishing appropriate legislation, and a need for optimizing effective methods of analysis. In this review, we will compile evidence concerning emergent marine toxins and provide data that may indicate the need to restructure the current monitoring programs of HAB.

Nowadays, the use of a drug to modify a person's behavior with criminal intentions has become a growing public concern. In fact, stealthy drink spiking with certain drugs can cause the incapacitation of a potential victim of assault and in extreme cases can even lead to death. Belonging to the group of drugs used to commit drug-facilitated crimes is glibenclamide, which not only exhibits high sedation secondary effects but when subject to an overdose intake can lead to intense hypoglycemic episodes that could end with death. Suicide attempts and homicides through overdose with glibenclamide have already been reported. In this work and for the first time, it was developed a new methodology for detection of glibenclamide in spiked liquid samples (teas) by fluorometry (λ(ex)=300 nm; λ(em)=404 nm). The novel methodology was also implemented in a miniaturized and portable automatic flow system based in the concept of multipumping with an in-line pre-separation unit. The separation of the drug from the liquid samples was achieved through adsorption of the drug into activated charcoal packed within a mini column followed by elution with a solution composed by ethanol, hydrochloric acid and the surfactant CTAB (70%, 1.0 mol L(-1), 0.01 mol L(-1), respectively). The results allowed to obtain a linear working range for glibenclamide concentrations of up to 50 mg L(-1) (r=0.9999) and the detection limit was about 0.81 mg L(-1) of glibenclamide.

Metal accumulation by Juncus maritimus and the effect this plant might have on the physico-chemical composition of sediments, from Douro river estuary (NW Portugal), were investigated through one year of plant's life. The contents of Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn were determined (by atomic absorption spectrophotometry) in sediments, rhizosediments (those among plant roots and rhizomes) and different tissues of J. maritimus. Two estuarine sites with different characteristics were studied, one a sandy sediment with relatively low organic matter content, the other a muddy site. The role of the plant seemed to be markedly dependent on the sediment composition. At the sandy site, significant variations throughout the year (a decrease from winter to summer and an increase in autumn) either in rhizosediment and sediment or in J. maritimus roots were only observed in Cd and Cu levels. These variations were the same in both compartments, probably caused by tidal water movements and the activity of the plant. At the muddy site, variations throughout the year were observed for all studied elements but Pb. Changes in the Cd and Zn contents of roots were opposite to those in the rhizosediment (uptake of Cd and Zn by J. maritimus roots in summer may have caused a decrease in rhizosediment levels). Fe and Mn showed similar patterns of variation in both roots and rhizosediment (contents significantly increasing in summer). Higher contents of Fe and Mn in roots in summer could be related to changes in mass, higher availability of the elements, or accumulation at the surface of the root in (hydr)oxides forms. For the remaining elements no significant correlations between rhizosediment and roots variations were observed, indicating that their uptake and release by roots were not based on single exchanges with the sediment. J. maritimus showed capacity to accumulate Cu, Zn and particularly Cd, thus appearing to be useful for the phytostabilization of these metals.

Biogas is a valuable renewable energy source that can help mitigate greenhouse emissions. The dry reforming of methane (DRM) offers an alternative hydrogen production route with the advantage of using two main greenhouse gases, CO2 and CH4. However, its real application is limited mainly due to catalyst deactivation by coke formation and the reverse water gas shift (RWGS) reaction that can occur in parallel. Additionally, the typical dry reforming temperature range is 700–950 °C, often leading to catalyst sintering. A low-temperature DRM process could be in principle achieved using a membrane reactor (MR) to shift the dry reforming equilibrium forward and inhibit the RWGS reaction. In this work, biogas reforming was investigated through the simulation of MRs with thin (3.4 µm) and thick (50 µm) Pd-Ag membranes. The effects of the feed temperature (from 450 to 550 °C), pressure (in the range of 2–20 bar), and biogas composition (CH4/CO2 molar ratios from 1/1 to 7/3) were studied for the thin membrane through the calculation and comparison of several process indicators, namely CH4 and CO2 conversions, H2 yield, H2/CO ratio and H2 recovery. Estimation of the CO-inhibiting effect on the H2 molar flux through the membrane was assessed for a thick membrane. Simulations for a thin Pd-Ag MR show that (i) CO2 and CH4 conversions and H2 yield increase with the feed temperature; (ii) H2 yield and average rate of coke formation increase for higher pressures; and (iii) increasing CH4/CO2 feed molar ratio leads to higher H2/CO ratios, but lower H2 yields. Moreover, simulations for a thick Pd-Ag MR showed that the average H2 molar flux decreases due to the CO inhibiting effect (ca. 15%) in the temperature range considered. In conclusion, this work showed that for the considered simulation conditions, the use of an MR leads to the inhibition of the RWGS reaction and improves H2 yield, but coke formation and CO inhibition on H2 permeation may pose limitations on its practical feasibility, for which proper strategies must be explored.

AbstractElectrocution on power lines is an important human‐related cause of bird mortality and an important conservation issue worldwide. Besides impacts on bird populations, electrocutions cause power outages, resulting in damage to power line network integrity. However, there is a general lack of knowledge on the risk of bird electrocution, especially in developing countries. Generating information over large scales without resorting to local mortality data can be useful for the development of regional management strategies, particularly in countries where electrocution is poorly documented. Here, we developed a framework to model the risk of bird electrocution as an interaction between the species‐specific exposure to power lines (pole density within a species distribution range) and susceptibility (morphological and behavioral traits associated with electrocution hazards). We applied this framework to Brazil, identifying 283 species that face a risk of electrocution, of which 38 were classified as higher risk, mostly raptors (76%). The Pantanal (a large wetland biome) concentrates the greatest cumulative susceptibility due to the high number of species vulnerable to electrocution (i.e. large species using power lines for perching or nesting), while the Atlantic Forest region has a higher risk for electrocution, due to the spatial overlap between the presence of vulnerable species and high exposure to power lines. Furthermore, our study identified spatial patterns of bird electrocution, highlighting priority areas for electrocution susceptibility and electrocution risk to be further investigated, and where measures to mitigate bird electrocutions should be applied on new and existing power lines. Our framework allows a preliminary assessment aimed at identifying areas of higher risk of electrocution, to highlight species vulnerable to this threat and to improve power line routing. This approach can be replicated to other understudied areas of the world where the same information is available.

Reducing office buildings’ energy consumption can contribute significantly towards carbon reduction commitments since it represents ∼40% of total energy consumption. Major components of this are lighting, electrical equipment, heating, and central cooling systems. Solid evidence demonstrates that individual occupants’ behaviors impact these energy consumption components. In this work, we propose the methodology of using virtual choreographies to identify and prioritize behavior-change interventions for office users based on the potential impact of specific behaviors on energy consumption. We studied the energy-related office behaviors of individuals by combining three sources of data: direct observations, electricity meters, and computer logs. Data show that there are behaviors with significant consumption impact but with little potential for behavioral change, while other behaviors have substantial potential for lowering energy consumption via behavioral change.

AbstractParapatry is a biogeographical term used to refer to organisms whose ranges do not overlap, but are immediately adjacent to each other; they only co‐occur – if at all – in a narrow contact zone. Often there are no environmental barriers in the contact zones, hence competitive interaction is usually advocated as the factor that modulates species distribution ranges. Even though the effects of climate change on species distribution have been widely studied, few studies have explored these effects on the biogeographical relationships between closely related, parapatric, species. We modelled environmental favourability for three parapatric hare species in Europe – Lepus granatensis, L. europaeus and L. timidus – using ecogeographical variables and projected the models into the future according to the IPCC A2 emissions scenario. Favourabilities for present and future scenarios were combined using fuzzy logic with the following aims: (i) to determine the biogeographical relationships between hare species in parapatry, that is L. granatensis/L. europaeus and L. europaeus/L. timidus and (ii) to assess the effects of climate change on each species as well as on their interspecific interactions. In their contact area L. granatensis achieved higher favourability values than L. europaeus, suggesting that if both species have a similar population status, the former species may have some advantages over the latter if competitive relationships are established. Climate change had the most striking effect on the distribution of L. timidus, especially when interspecific interactions with L. europaeus were taken into account, which may compromise the co‐existence of L. timidus. The results of this study are relevant not only for understanding the distribution patterns of the hares studied and the effects of climate change on these patterns, but also for improving the general application of species distribution models to the prediction of the effects of climate change on biodiversity.

This work intended to explore some motivations that influence people’s eating habits towards sustainability. This was an observational, cross-sectional study, carried out by questionnaire survey on a non-probabilistic sample of 10,067 participants from 13 countries (Argentina, Brazil, Croatia, Greece, Hungary, Latvia, Lithuania, Poland, Portugal, Serbia, Slovenia, Romania and United States). Results indicated that people prefer fresh local foods from the season, being important because it allows transportation and storage to be reduced, which in many cases implies refrigeration systems and consequent energy expenditure. Although people avoid food waste at home, the awareness for the waste at restaurants still needs to be improved. Consumers seem to prefer foods that have been produced and packed in sustainable ways but still give importance to the package—understandable for food products. The results also indicated significant differences in the food choice motivations between groups for all sociodemographic variables tested (age, sex, marital status, education, professional area, living environment and country), but the association was high only for variable country. Additionally, a tree classification analysis allowed to identify the relative importance of the influential variables on the sustainable food choices, with country being the most important, followed by age and sex. Additionally, discriminant function analysis allowed establishing a model for the relation between country and six variables accounting for preservation of biodiversity, respect for life, save natural resources, save energy, reduce industrial pollution and minimal packaging. Although with some limitations, this study brings valuable insight into some aspects linked with sustainable food choices on a number of countries and how people shape their food choices according to some sustainability issues.