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Mining and mineral processing industry adversely affects ecosystems and communities in nearby areas, including high freshwater consumption and scarcity. That is why the emerging global trend is to use sea water in flotation to recover valuable minerals from finely disseminated base metals ores. Recent studies investigate sea water flotation of copper, molybdenum, nickel sulphides and pyrite, while flotation of sphalerite, the main valuable mineral for zinc production, remains uncovered. This paper examines the feasibility of sphalerite flotation by conventional collectors in artificial sea water using a bubble-particles technique and frothless flotation tests. Potassium isopropyl xanthate (PIPX) and sodium isopropyl dithiophosphate (SIDTP) were used as collectors, and copper sulphate was introduced as the activator, while zinc sulphate and sodium sulphide were used as depressants. We examined the most common size fractions of sphalerite: medium (−74 + 44 μm) and fines (−44 μm). The findings showed the feasibility of sphalerite flotation in artificial sea water. We also established correlations between the rate of bubble-particle attachment and the sphalerite flotation recovery resulting in the growth of flotation recovery with the increase of the bubble-particle attachment rate. The results can be used as guidelines in choosing flotation reagents for sphalerite flotation in sea water. Another practical application of the results is the potential for sustainable development of the industrial sector, ecosystems and societies due to the replacement of fresh water by sea water, although further technological and environmental studies are required.

AbstractNowadays, researchers are focusing on the methods of using recycled industrial/agricultural wastes as raw materials, which are not only economically but also environmentally useful. In the recent years, many scholars have conducted research on the rational use of rice husks (RHs) and found that RHs are rich in inorganic/organic components and used in combination with the certain building materials to produce new green composite building materials. This paper studies the method of using RH processed products and the sodium silicate solution (liquid glass) made from RH ash to produce cheap wood substitute composite materials, which can be improved the insulation performance of the wall greatly. Obtained results are determined by comparing with the properties of standard polymer composite materials such as particleboards, chipboards, and medium‐density fiberboards (MDF). The significance of the work is pointing out by solving the problem of recycling large‐tonnage agricultural waste and reproduce products with the consumer's value.

Abstract This study presents and evaluates the feasibility of a novel hybridization of modified Kalina cycle, reverse osmosis desalination, and low-temperature water electrolysis utilizing geothermal energy to yield power, distilled water, and hydrogen, respectively. The scientific impact of the current work has been improved considering the features of Sabalan flash-binary geothermal wells in Iran as a real model through a case study. In addition to designing a novel setup, the smart use of multi-heat recovery technique, modifying the base cycle, and utilizing a part of generated distilled water to produce hydrogen by the electrolyzer are the other structural originalities, distinguishing the current work from the previous studies. The suggested system is scrutinized via a parametric study and optimized based on a genetic algorithm. The parametric study demonstrated that the highest sensitivity of varying the performance criteria of the whole system is attributed to the change in flash tank pressure. Moreover, the multi-objective optimization led to achieving the exergy efficiency and trigeneration gain output ratio as 51.3% and 1.7 for the system, respectively. Furthermore, the system was able to produce 4795 kW of power, 5.3 kg/h of hydrogen, and 19.9 kg/s of distilled water.

Innovative control method is prosed for the RED WoLF hybrid storage system. The technology is aimed for residential dwellings and allows to reduce the load from the electrical grid during time with high CO emissions. The RED WoLF system consists of a battery, water cylinder, PV array and storage heaters. This technology allows the grid energy to be stored at the “greenest” time, in order to accommodate needs of dwellings with the aid of AI. The original RED WoLF algorithm is considerably improved, following modified progressive threshold approach up to additional 14% savings of CO could be obtained. Intriguingly, savings are only slightly lower than global possible mathematical minimum, for the system barred of predictions errors. However, the computation time of the proposed control method is lower by a few orders of magnitudes, with comparison to standard optimisation techniques. Furthermore, the investigation on 11 months period was performed in order find out if there is significant difference between following a time of use tariff or an environmental signal. Results, suggest that the differences are minor in both cases following any signal improves the used energy quality. Although, the price signal has been affected slightly more to the choice of a target. Finally, the average system composition with 2 kWh battery and 4 kW PV array provides reduction by 55%–60% of both CO emissions and the bill. Such achievement could potentially lead to smooth substitution of carbon intensive residential systems with gas and oil heaters.

Closed-loop supply chain networks are gaining research popularity due to environmental, economic and social concerns. Such networks are primarily designed to overcome carbon footprints and to retrieve end of life products from customers. This study considers a multi echelon closed-loop supply chain in the presence of machine disruption. A multi-objective model is presented to optimize the total cost, the total time and emissions in a closed-loop supply chain network. The aim is to analyze the trade-off between the objectives of cost, time, and emissions and how these decisions are impacted by the selection of different available machines. A number of solution approaches are tested on a case study from the tire industry. The results suggest the improved performance of the hybrid heuristic and the importance of controlling disruption in a closed-loop supply chain network. Furthermore, there is a trade-off between the different objective functions which can help the decision maker to choose a particular solution according to the preference of an organization. Finally, conclusion and future research avenues are provided.

Purpose: The aim of this work is the operational electrophysical method of the control for contamination and purification of soil from oil products and the identification of changes in the soil properties in electrochemical processing to determine rational modes of processing.Methods: Investigations are performed on the laboratory setup including the two -electrode scheme of electric treatment of the artificially polluted soil .The setup is equipped with a system of micro sensors of specific electrical resistance. Traditional laboratory tests are used to determine the physical and mechanical properties of soils. The possibility of control for soil purification by electrochemical method using a system of continuous operational geophysical monitoring is considered.Results: Changes in the physical properties of contaminated soils are experimentally confirmed when exposed to the electric current. A physical model is created for coagulation of oil products in pores during the electrical processing. It increases the amount of sand and clay components with changes in the electrical resistance of soil. The physical processes in the clean and polluted soil are compared. It is shown that when electric current passes through contaminated soils, oil products in pores transfer to a solid, less toxic state, which leads to a change in the specific electrical soil resistance throughout the zone processed. This pattern should be used to control soil decontamination.

The object of the study is the water supply and sanitation system of an industrial enterprise. Currently, many enterprises do not use the treated industrial waste water in the water supply cycle. Therefore, the use of treated wastewater is of practical importance. The scheme of thermal treatment of waste water for obtaining pure condensate by evaporation is proposed. The main results of the study are the technical solution for the development of the enterprise's wastewater treatment complex. Pure condensate is obtained in an instant boiling evaporator. The research method is based on the calculation of energy costs in wastewater treatment for different types of waste water. The results of the study allow us to determine the optimal set of energy equipment for obtaining pure condensate and its further use. The specific practical significance lies in the development of a technical solution that helps the treatment of wastewater and the reduction of emissions into the water basin.

The aim of the study - identification of factors that ensure the vital activity of indigenous small-numbered peoples of the North in the Arctic, as well as the analysis of their impact on the preservation and development of the ethnic group. Identifying problems and assessing the prospects for the development of indigenous people consists of 3 stages: analysis of foreign and domestic sources, the results of scientific research teams; systematization of statistical data, including information on the dynamics of the development of indigenous people (number, employment in traditional activities); the impact assessing of legal, economic and social factors on the preservation and development of indigenous people. A comprehensive analysis of a wide range of legal, economic and social problems of ensuring the traditional life of indigenous people within the Arctic zone of the Russian Federation (AZRF) has shown the need to improve legislative, financial and managerial actions to preserve them as a specific community, adapted to the extremely severe conditions of permanent residence beyond the Arctic Circle and as a unique phenogenotype, whose activity is closely conjugated with the environmental state of the macroregion and in fact is entirely dependent on it. The exclusive role of indigenous peoples in preserving the natural complexes of the Arctic in the 21st century for future generations was emphasized. Under the conditions of proliferation of technogenic and anthropogenic burden on the natural complexes of the macroregion, associated with the intensive development of fuel and power resources, deposits of rare and precious metals, development of coastal transport infrastructure and a multiple increase in the population in the Russian Arctic with a creation of "stronghold areas" the threat of the indigenous peoples' disappearance appeared (Enets - about 200 people remain and less than 100 people - the Votes). Under the conditions of a large-scale, integral impact of man-made, anthropogenic and climatic factors on indigenous communities in the Arctic, their life environment and traditional management the need for urgent adoption of a complex of specific and targeted legal, economic and social measures aimed at ensuring and preserving their livelihoods is obvious.

Abstract Mitigating the effects of environmental deterioration requires a focus on not just CO2 emissions from energy consumption, but also environmental pollution from industry sectors. To reach this goal, recent studies have extended ecological footprint (EF) analysis to identify the ecological drivers of various key industry sectors. The role of the phosphorus (P) industry on the EF within the environmental Kuznets curve (EKC) framework for China is the emphasis of this study. Autoregressive distributive lag (ARDL) as well as the impulse response function and robustness analysis were used to consider a time from 1985 to 2018. The study verifies the EKC hypothesis for China in both the long and the short run, and indispensable determinants are proposed to be included to assure the model’s fitness and robustness when conducting EF analysis of industry sectors. Energy consumption–based carbon emissions have been verified as the dominant contributor to EF, but P use and urbanization have a significant lagged positive influence on EF in the short run. P exports, in particular, have been highlighted as a critical driver of the EF of China’s P industry. The conducted frequency domain causality test reinforced the above findings and demonstrated bidirectional causality at different frequencies. This work suggests that formulating plausible P export policies to alleviate the conflict between the output of China’s P industry and the environmental sustainability of this industry are necessary. In this context, “multidisciplinary, multidimensional, and practical solutions” are most desirable for sustainable P management.

Pharmaceutical and personal care products (PPCPs) are discharged into receiving water bodies mainly from sewage treatment plants. Due to the inefficient removal in conventional wastewater treatment facilities, PPCPs have become a major concern to aquatic ecosystems, water quality, and public health worldwide since they cause harmful effects on aquatic life and human even at low doses. Among the PPCPs, carbamazepine (CBZ) is one of the most commonly prescribed anticonvulsant drugs and consumed more than 1,000 tons per year. Due to its structural complexity, CBZ is known as recalcitrant compound highly stable during wastewater treatment. Consequently, it has become one of the most frequently detected pharmaceuticals in waste water, surface water, and even drinking water. In this study, Korean indigenous microalgae strains were tested as eco-friendly and cost-effective solutions for CBZ removal. Based on the preliminary biological CBZ degradation tests, Tetradesmus obliquus KNUA061 demonstrating the best CBZ removal rate was selected for further experiments. In order to increase strain KNUA061's CBZ removal efficiency, NaOCl, which is widely accepted in the water purification process, was used as an additional stimulus to induce stress conditions. At around 20 μg L−1 CBZ, addition of 1.0 mg NaOCl resulted in approximately 20% of removal rate increase without suppressing cells growth. Roughly 90% of CBZ remained its original form and the composition of the transformed secondary metabolites was less than 10% during the biodegradation process by the microalga. Based on the results of the antioxidant enzyme activities, degree of lipid oxidation, and amino acid contents, it was concluded that the redox-defence system in microalgal cells may have been activated by the NaOCl treatment. Biomass analysis results showed that higher heating value (HHV) of strain KNUA061 biomass was higher than those of lignocellulosic energy crops suggesting that it could be utilized as a possible renewable energy source. Even though its biodiesel properties were slightly below the international standards due to the high PUFA contents, the biodiesel produced from T. obliquus KNUA061 could be used as a blending resource for transportation fuels. It was also determined that the microalgal biomass has acceptable feasibility as a sustainable dietary supplement feedstock due to its high essential amino acid contents.