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In industrialized countries, large amounts of mineral wastes are produced. They are re-used in various ways, particularly in road and earth constructions, substituting primary resources such as gravel. However, they may also contain pollutants, such as heavy metals, which may be leached to the groundwater. The toxic impacts of these emissions are so far often neglected within Life Cycle Assessments (LCA) of products or waste treatment services and thus, potentially large environmental impacts are currently missed. This study aims at closing this gap by assessing the ecotoxic impacts of heavy metal leaching from industrial mineral wastes in road and earth constructions. The flows of metals such as Sb, As, Pb, Cd, Cr, Cu, Mo, Ni, V and Zn originating from three typical constructions to the environment are quantified, their fate in the environment is assessed and potential ecotoxic effects evaluated. For our reference country, Germany, the industrial wastes that are applied as Granular Secondary Construction Material (GSCM) carry more than 45,000 t of diverse heavy metals per year. Depending on the material quality and construction type applied, up to 150 t of heavy metals may leach to the environment within the first 100 years after construction. Heavy metal retardation in subsoil can potentially reduce the fate to groundwater by up to 100%. One major challenge of integrating leaching from constructions into macro-scale LCA frameworks is the high variability in micro-scale technical and geographical factors, such as material qualities, construction types and soil types. In our work, we consider a broad range of parameter values in the modeling of leaching and fate. This allows distinguishing between the impacts of various road constructions, as well as sites with different soil properties. The findings of this study promote the quantitative consideration of environmental impacts of long-term leaching in Life Cycle Assessment, complementing site-specific risk assessment, for the design of waste management strategies, particularly in the construction sector.

The chemical and petrochemical sector is by far the largest industrial energy user, accounting for 30% of the industry's total final energy use. However, due to its complexity its energy efficiency potential is not well understood. This article analyses the energy efficiency potential on a country level if Best Practice Technologies (BPT) were implemented in chemical processes. Two approaches are applied and an improved dataset referring to Europe has been developed for BPT energy use. This methodology has been applied to 66 products in fifteen countries that represent 70% of chemical and petrochemical sector's energy use worldwide. The results suggest a global energy efficiency potential of 16% for this sector, excluding savings in electricity use and by higher levels of process integration, combined heat and power (CHP) and post-consumer plastic waste treatment. The results are more accurate than previous estimates. The results suggest significant differences between countries, but a cross-check based on two different methods shows that important methodological and data issues remain to be resolved. Further refinement is needed for target setting, monitoring and informing energy and climate negotiation processes. For the short and medium term, a combination of benchmarking and country level analysis is recommended.

Abstract While it is generally accepted that our fossil fuel-dominated energy systems must undergo a sustainable transition, researchers have often neglected the potential impacts of this on water and land systems. However, if unintended environmental impacts from this process are to be avoided, understanding its implications for land use and water demand is of crucial importance. Moreover, developed countries may induce environmental stress beyond their own borders, for instance through extensive imports of bioenergy. In this paper, Germany serves as an example of a developed country with ambitious energy transformation targets. Results show that in particular, the politically-driven aspiration for more organic farming in Germany results in a higher import quota of biomass, especially biofuels. These imports translate into land demand, which will exceed the area available in Germany for bioenergy by a factor of 3–6.5 by 2050. As this will likely bring about land stress in the respective exporting countries, this effect of the German energy transformation ought to be limited as much as possible. In contrast, domestic water demand for the German energy system is expected to decrease by over 80% through 2050 due to declining numbers of fossil-fuelled power plants. However, possible future irrigation needs for bioenergy may reduce or even counterbalance this decreasing effect. In addition, energy policy targets specific to the transport sector show a high sensitivity to biomass imports. In particular, the sector-specific target for greenhouse gas reductions will seemingly promote biomass imports, leading to the above-described challenges in the pursuit of sustainability.

Abstract Behavior change towards sustainable lifestyles such as adoption of renewable energy technologies is a significant element in the fight against anthropogenic climate change. Increasingly, private households can be observed to take up different renewable energy technologies; however, the introduction of these technologies is not accompanied by a broader adoption of pro-environmental behaviors, as recent studies have shown. At the same time, group settings and social capital seem to promote the uptake of wide-ranging sustainability measures. Six case studies were conducted among different sustainable community projects in Germany to shed light on why and how broad sustainability transformation in such settings comes about. Findings suggest that successful implementation of wide-ranging sustainable measures and changes in behaviors in community settings result from motivations that originate from an interplay of social needs, social capital, social norms, and environmental concern. Strong environmental attitudes, not among all, but a critical mass of members and key individuals are necessary. The desire for community and other motives, along with social influence and social norms push individuals with low environmental concern to participate in sustainable endeavors.

Torrefaction is a promising bioenergy pre-treatment technology, with potential to make a major contribution to the commodification of biomass. However, there is limited scientific knowledge on the techno-economic performance of torrefaction. This study therefore improves available knowledge on torrefaction by providing detailed insights into state of the art prospects of the commercial utilisation of torrefaction technology over time. Focussing on and based on the current status of the compact moving bed reactor, we identify process performance characteristics such as thermal efficiency and mass yield and discuss their determining factors through analysis of mass and energy balances. This study has shown that woody biomass can be torrefied with a thermal and mass efficiency of 94% and 48% respectively (on a dry ash free basis). For straw, the corresponding theoretical energetic efficiency is 96% and mass efficiency is 65%. In the long term, the technical performance of torrefaction processes is expected to improve and energy efficiencies are expected to be at least 97% as optimal torgas use and efficient heat transfer are realised. Short term production costs for woody biomass TOPs (torrefied pellets) are estimated to be between 3.3 and 4.8 US$/GJLHV, falling to 2.1–5.1 US$/GJLHV in the long term. At such cost levels, torrefied pellets would become competitive with traditional pellets. For full commercialisation, torrefaction reactors still require to be optimised. Of importance to torrefaction system performance is the achievement of consistent and homogeneous, fully hydrophobic and stable product, capable of utilising different feedstocks, at desired end-use energy densities.

Abstract This study aims to analyze the innovation strategies for the green supply chain management with QFD (quality function deployment) multidimensionally. The novelty of the study is to define the criteria of green supply chain for each stage of QFD and propose a hybrid model by IVIF (interval-valued intuitionistic fuzzy) DEMATEL (decision making trial and evaluation laboratory) and IVIF MOORA (Multi-Objective Optimization by Ratio Analysis) respectively. The results demonstrate that understanding the customer expectations with customer relation management is the most important innovation strategy for the green supply chain management in energy industry with the consecutive stages of QFD whereas benchmarking the competitive market environment has relatively the last seat in the ranking. Hence, it is recommended that energy companies should have an effective customer relationship management. In this context, these companies should make a detailed analysis to learn what their customers directly expect from them. With the help of this issue, these companies should generate their product and services based on these expectations. Additionally, it is also stated that new service and product development is also essential for energy companies to improve their innovativeness. For this purpose, a research and development department should be created, and the qualified people should be employed. Additionally, different opinions should be collected from various parties, such as customers, employees, and suppliers. Since customers who are satisfied will prefer these companies, the energy companies can catch the opportunity to increase their market share.

Wind energy projects provide clean energy so that they should be increased to reach the sustainable development goals of the countries. However, current decision-making process should be improved for the effectiveness of these projects. Thus, critical factors should be considered to understand the significant indicators of the performance of the wind energy projects. This article aims to determine the factors that should be considered when deciding on wind energy investments. In this context, 9 different criteria belonging to 3 dimensions (project, firm, market) are determined based on literature review. Later, an analysis is carried out by using hesitant interval-valued intuitionistic fuzzy (IVIF) Decision Making Trial and Evaluation Laboratory (DEMATEL) to identify the most important factors. Furthermore, 4 different investment strategies in Boston Consultancy Group (BCG) matrix have been determined as alternatives. To determine which of these strategies is suitable for wind energy investments, the hesitant IVIF multi-objective optimization on the basis of ratio analysis (MOORA) method has been considered. Additionally, a comparative evaluation is also performed by using technique for order preference by similarity to ideal solution (TOPSIS) methodology. Similarly, sensitivity analysis is also made by considering 9 different cases. The analysis results of different methodologies are quite similar which shows the coherency and reliability of the findings. It is concluded that firm-based factors play the most significant role. It is also identified that technical development, financial performance and organizational effectiveness are the most significant criteria to make investment decision on wind energy projects. Furthermore, due to the market growth potential, it is recommended that wind energy investors increase their investments and strengthen their position in the market.

Climate change and rising global temperatures pose significant challenges for natural resource management. While developed economies have made progress in addressing these issues, emerging economies are still striving to achieve carbon neutrality, sustainable resource use, and environmental sustainability. This research aims to identify the factors driving carbon emissions in emerging economies over the past three decades. The study establishes a long-run relationship among the factors under investigation by employing various panel diagnostic methods. Non-parametric approaches are used to account for the non-symmetric distribution of panel data. The findings reveal that natural resource components have asymmetric impacts on carbon emissions, with oil rents reducing emissions and mineral rents increasing them. Economic growth and agricultural value added are identified as significant contributors to carbon emissions in the region. On the other hand, renewable energy consumption plays a crucial role in achieving carbon neutrality targets. Gross capital formation exhibits a mixed influence on carbon emissions, being positive and significant in lower quantiles and significantly negative in upper quantiles. These estimates are robust and align with existing literature. The study recommends sustainable resource abstraction and utilization, renewable energy production and consumption improvements, and enhanced capital formation. By providing empirical evidence and policy recommendations, this research contributes to understanding the relationship between these factors and their impact on carbon emissions, facilitating effective strategies for sustainable development and environmental preservation. Xinyang Normal University

Abstract The safe decommissioning as well as decontamination of the radioactive waste resulting from the nuclear accident in Fukushima Daiichi represents a huge task for the next decade. At present, research and development on long-term safe storage containers has become an urgent task with international cooperation in Japan. One challenge is the generation of hydrogen and oxygen in significant amounts by means of radiolysis inside the containers, as the nuclear waste contains a large portion of sea water. The generation of radiolysis gases may lead to a significant pressure build-up inside the containers and to the formation of flammable gases with the risk of ignition and the loss of integrity. In the framework of the project “R&D on technology for reducing concentration of flammable gases generated in long-term waste storage containers” funded by the Japanese Ministry of Education, Culture, Sports, Science and Technology of Japan (MEXT), the potential application of catalytic recombiner devices inside the storage containers is investigated. In this context, a suitable catalyst based on the so-called intelligent automotive catalyst for use in a recombiner is under consideration. The catalyst is originally developed and mass-produced for automotive exhaust gas purification, and is characterized by having a self-healing function of precious metals (Pd, Pt and Rh) dissolved as a solid solution in the perovskite type oxides. The basic features of this catalyst have been tested in an experimental program. The test series in the REKO-4 facility has revealed the basic characteristics of the catalyst required for designing the recombiner system.