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In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

AbstractClimate change poses new and unique challenges that threaten lives and livelihoods. Given the increasing risks and looming uncertainty of climate change, increasing attention has been directed towards adaptation, or the strategies that enable humanity to persist and thrive through climate change the best it can. Though climate change is a global problem often discussed at the national scale, urban areas are increasingly seen as having a distinct role, and distinctive motivation and capacity, for adaptation. The 12 articles in this special issue explore ways of understanding and addressing climate change impacts on urban areas. Together they reveal young but rapidly growing scholarship on how to measure, and then overcome, challenges of climate change. Two key themes emerge in this issue: 1) that we must identify and then overcome current barriers to urban adaptation and 2) frameworks/metrics are necessary to identify and track adaptation progress in urban settings. Both of these themes point to the power of indicators and other quantitative information to inform priorities and illuminate the pathway forward for adaptation. As climate change is an entirely new challenge, careful measurement that enables investment by private and public parties is necessary to provide efficient outcomes that benefit the greatest number of people.

Recycled polylactic acid (PLAr) was reinforced with treated nanocellulosic hemp fibers for biocomposite fabrication. Cellulosic fibers were extracted from hemp fibers chemically and treated enzymatically. Treated nanocellulosic fibers (NCF) were analyzed by Fourier-transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy. Biocomposite fabrication was done with PLAr and three concentrations of treated NCF (0.1%, 0.25%, and 1% (v/v)) and then studied for thermal stability and mechanical properties. Increased thermal stability was observed with increasing NCF concentrations. The highest value for Young’s modulus was for PLAr + 0.25% (v/v) NCF (250.28 ± 5.47 MPa), which was significantly increased compared to PLAr (p = 0.022). There was a significant decrease in the tensile stress at break point for PLAr + 0.25% (v/v) NCF and PLAr + 1% (v/v) NCF as compared to control (p = 0.006 and 0.002, respectively). No significant difference was observed between treatments for tensile stress at yield.

Abstract The combination of biomass gasification with fuel cells, especially high temperature Solid Oxide Fuel Cells (SOFCs) promises sustainable and highly efficient (decentralized and modular) energy conversion systems. This review encompasses the components of biomass integrated gasification–SOFC technology including biomass characteristics, the thermochemical conversion in gasifiers and the factors affecting the gasification process, the cleaning technologies for raw producer gas and its conditioning and finally the integration of gasifier with SOFCs. The influence of impurities present in biomass producer gas such as particulates, tar, H 2 S, HCl and alkali compounds based on recent experimental studies and their tolerance limits towards SOFCs are presented. Even though analysis based on the probable tolerance limits of impurities towards SOFCs and a comprehensive overview of the cleaning technologies for producer gas impurities indicate that producer gas cleaning at various temperatures using current technologies to meet SOFC requirements is possible, more experimental studies are still needed to acquire the detailed information on the tolerance limits of impurities for SOFCs. The recent theoretical modeling and experimental studies of biomass integrated gasification–SOFC systems are also presented.

This article makes the central argument that basic democratic values such as justice, autonomy and participation run the risk of being neglected when designing ‘nudges’ (i.e., indirect suggestions to influence individual behaviour) for sustainable behaviour change in the context of food governance, potentially complicating a democratisation of the food system. ‘Nudges’ uphold freedom of choice while simultaneously advocating a non-coercive soft force of paternalism to help people realise their preferences, maximise societal well-being and meet macro-sustainability goals. While the promises of the ‘nudge’ approach are widely echoed, nudging is also being contested because of its possible anti-democratic effects, such as individualisation, depoliticization and the emphasis of the status of citizens as ‘consumer-citizens.’ From a food democracy perspective, these dangers may undermine efforts to organise collective political action and impede alternative visions of a future food system. Empirically, the article examines specifically how behavioural-economic approaches imagine transitions to a more sustainable food system. By using the “COOP Supermarket of the Future” as a case study, the following analysis will illustrate how private actors are increasingly involved in steering consumer choice towards socially desirable actions. The analysis suggests that the design of choice environments may under specific circumstances increase the susceptibility of individuals to the influence of corporate preferences and simultaneously decrease the prospects for democratic legitimation and decision-making. The article therefore critically assesses whether reforming the food system by altering consumers’ choice-sets and the attribution of personal responsibility, may in fact point towards implicit anti-democratic tenets underlying the ‘will to nudge’ citizens.

The Houston-Dallas (I-45) corridor is the busiest route among 18 traffic corridors in Texas, USA. The expected population growth and the surge in passenger mobility may result in a significant impact on the regional environment. This study uses a life cycle framework to predict and evaluate the net changes of environmental impact associated with the potential development of a high-speed rail (HSR) System along the I-45 corridor through its life cycle. The environmental impact is estimated in terms of CO2 and greenhouse gas (GHG) emissions per vehicle/passenger-kilometers traveled (V/PKT) using life cycle assessment. The analyses are performed referring to the Ecoinvent 3.4 inventory database through the phases: material extraction and processing, infrastructure construction, vehicle manufacturing, system operation, and end of life. The environmental benefit is evaluated by comparing the potential development of the HSR system with those of the existing transportation systems. The vehicle component, especially operation and maintenance of vehicles, is the primary contributor to the total global warming potential with about 93% of the life cycle GHG emissions. For the infrastructure component, 56.76% of GHG emissions result from the material extraction and processing phase (23.75 kgCO2eq/VKT). Various life cycle emissions of HSR except PM are significantly lower than for passenger cars.

The ‘4 per mille Soils for Food Security and Climate’ was launched at the COP21 with an aspiration to increase global soil organic matter stocks by 4 per 1000 (or 0.4 %) per year as a compensation for the global emissions of greenhouse gases by anthropogenic sources. This paper surveyed the soil organic carbon (SOC) stock estimates and sequestration potentials from 20 regions in the world (New Zealand, Chile, South Africa, Australia, Tanzania, Indonesia, Kenya, Nigeria, India, China Taiwan, South Korea, China Mainland, United States of America, France, Canada, Belgium, England & Wales, Ireland, Scotland, and Russia). We asked whether the 4 per mille initiative is feasible for the region. The outcomes highlight region specific efforts and scopes for soil carbon sequestration. Reported soil C sequestration rates globally show that under best management practices, 4 per mille or even higher sequestration rates can be accomplished. High C sequestration rates (up to 10 per mille) can be achieved for soils with low initial SOC stock (topsoil less than 30 t C ha− 1), and at the first twenty years after implementation of best management practices. In addition, areas which have reached equilibrium will not be able to further increase their sequestration. We found that most studies on SOC sequestration only consider topsoil (up to 0.3 m depth), as it is considered to be most affected by management techniques. The 4 per mille number was based on a blanket calculation of the whole global soil profile C stock, however the potential to increase SOC is mostly on managed agricultural lands. If we consider 4 per mille in the top 1m of global agricultural soils, SOC sequestration is between 2-3 Gt C year− 1, which effectively offset 20–35% of global anthropogenic greenhouse gas emissions. As a strategy for climate change mitigation, soil carbon sequestration buys time over the next ten to twenty years while other effective sequestration and low carbon technologies become viable. The challenge for cropping farmers is to find disruptive technologies that will further improve soil condition and deliver increased soil carbon. Progress in 4 per mille requires collaboration and communication between scientists, farmers, policy makers, and marketeers.